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Title: | meso-Pyrimidinyl-Substituted A(2)B- and A(3)-Corroles | Authors: | Ngo, Thien H. Nastasi, Francesco Puntoriero, Fausto Campagna, Sebastiano Dehaen, Wim MAES, Wouter |
Issue Date: | 2010 | Publisher: | AMER CHEMICAL SOC | Source: | JOURNAL OF ORGANIC CHEMISTRY, 75(6). p. 2127-2130 | Abstract: | A variety of meso-pyrimidinyl-substituted A(2)B- and A(3)-corroles (A = 4,6-dichloropyrimidin-5-yl) have been synthesized by careful optimization of the macrocyclization conditions. meso-Pyrimidinylcorroles offer the distinct advantage of an unprecedented broad scope of functionalization options. Highly sterically encumbered triarylcorroles were readily prepared via efficient nucleophilic aromatic Substitution and Suzuki cross-coupling procedures. | Notes: | [Ngo, Thien H.; Dehaen, Wim; Maes, Wouter] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium. [Nastasi, Francesco; Puntoriero, Fausto; Campagna, Sebastiano] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy. [Maes, Wouter] Hasselt Univ, Inst Mat Res IMO, Res Grp Organ & Biopolymer Chem, B-3590 Diepenbeek, Belgium. | Document URI: | http://hdl.handle.net/1942/10837 | ISSN: | 0022-3263 | e-ISSN: | 1520-6904 | DOI: | 10.1021/jo902709c | ISI #: | 000275379200048 | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2011 |
Appears in Collections: | Research publications |
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