Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/10892
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dc.contributor.authorEberle, Felit-
dc.contributor.authorKayser, Michael-
dc.contributor.authorKolb, Dieter M.-
dc.contributor.authorSAITNER, Marc-
dc.contributor.authorBOYEN, Hans-Gerd-
dc.contributor.authorD'OLIESLAEGER, Marc-
dc.contributor.authorMayer, Dieter-
dc.contributor.authorWirth, Alexandra-
dc.date.accessioned2010-04-21T10:46:58Z-
dc.date.availableNO_RESTRICTION-
dc.date.available2010-04-21T10:46:58Z-
dc.date.issued2010-
dc.identifier.citationLANGMUIR, 26 (7). p. 4738-4742-
dc.identifier.issn0743-7463-
dc.identifier.urihttp://hdl.handle.net/1942/10892-
dc.description.abstractResults from electrochemical studies, in situ STM, and ex situ angle-resolved XPS on self-assembled monolayers (SAMs) of thiazole on Au(111) are reported for the first time. Although STM seems to indicate a low density of molecules organized in small ordered domains, a quantitative chemical analysis of the sample surface by XPS clearly points toward the formation of a densely packed molecular layer. The stability of the thiazole SAM against reductive desorption is found to be very comparable with that for thiol-SAMs on gold. This results from the formation of Au-S bonds between the molecules and their support as evidenced by XPS, thereby rebuting speculations that the ring nitrogen is responsible for the attachment of such molecules to gold surfaces. Consequently, the N-atoms terminating the molecular layer are available as active sites for the complexation with Pd ions thereby allowing the deposition of Pd islands with monatomic height on top of the thiazole SAM. The importance of such studies for metal-molecule interconnections is briefly addressed.-
dc.description.sponsorshipThis work was supported by the Deutsche Forschungsgemeinschaft through SFB 569 and by the Odysseus and Interuniversity Attraction Pole programs of the Flemish government. One of us (M.K.) gratefully acknowledges a stipend from BASF. We also thank Dr. G. Gotz for helpful discussions and A. Romanyuk for technical assistance.-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.titleMetallization of Organic Surfaces: Pd on Thiazole-
dc.typeJournal Contribution-
dc.identifier.epage4742-
dc.identifier.issue7-
dc.identifier.spage4738-
dc.identifier.volume26-
local.format.pages5-
local.bibliographicCitation.jcatA1-
dc.description.notes[Eberle, Felit; Kayser, Michael; Kolb, Dieter M.] Univ Ulm, Inst Electrochem, D-89069 Ulm, Germany. [Saitner, Marc; Boyen, Hans-Gerd; D'Oliesliteger, Marc] Univ Hasselt, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Mayer, Dieter; Wirth, Alexandra] BASF, D-67056 Ludwigshafen, Germany. Dieter.Kolb@uni-ulm.de-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1021/la1000232-
dc.identifier.isi000275995100035-
item.fulltextNo Fulltext-
item.validationecoom 2011-
item.contributorSAITNER, Marc-
item.contributorEberle, Felit-
item.contributorMayer, Dieter-
item.contributorKayser, Michael-
item.contributorKolb, Dieter M.-
item.contributorBOYEN, Hans-Gerd-
item.contributorD'OLIESLAEGER, Marc-
item.contributorWirth, Alexandra-
item.fullcitationEberle, Felit; Kayser, Michael; Kolb, Dieter M.; SAITNER, Marc; BOYEN, Hans-Gerd; D'OLIESLAEGER, Marc; Mayer, Dieter & Wirth, Alexandra (2010) Metallization of Organic Surfaces: Pd on Thiazole. In: LANGMUIR, 26 (7). p. 4738-4742.-
item.accessRightsClosed Access-
crisitem.journal.issn0743-7463-
crisitem.journal.eissn****-****-
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