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http://hdl.handle.net/1942/10944
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DC Field | Value | Language |
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dc.contributor.author | VAN MIERLOO, Sarah | - |
dc.contributor.author | CHAMBON, Sylvain | - |
dc.contributor.author | BOYUKBAYRAM, Ayse | - |
dc.contributor.author | ADRIAENSENS, Peter | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | CLEIJ, Thomas | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.date.accessioned | 2010-05-21T14:08:54Z | - |
dc.date.available | NO_RESTRICTION | - |
dc.date.available | 2010-05-21T14:08:54Z | - |
dc.date.issued | 2010 | - |
dc.identifier.citation | MAGNETIC RESONANCE IN CHEMISTRY, 48 (5). p. 362-369 | - |
dc.identifier.issn | 0749-1581 | - |
dc.identifier.uri | http://hdl.handle.net/1942/10944 | - |
dc.description.abstract | Novel hexyl-substituted bisthiophene compounds containing a thiazolothiazole(5,4-d) unit have been explored. The molecules are soluble in common organic solvents, which would enhance their chance of possible integration in printable electronics. Synthesis and complete elucidation of the chemical structures by detailed 1D/2D NMR spectroscopy are described. This provides interesting input for chemical shift prediction software, because few experimental data on this type of compounds are available. Furthermore, the potential n-type character of these derivatives is verified using electrochemical measurements. In addition, the low-bandgap character of conjugated polymers containing the thiazolothiazole unit is demonstrated by performing an electropolymerization. Copyright (C) 2010 John Wiley & Sons, Ltd. | - |
dc.description.sponsorship | We gratefully acknowledge the EU for the FP6-Marie Curie-RTN 'SolarNtype' (MRTN-CT-2006-035533), the IWT (Institute for the Promotion of Innovation by Science and Technology in Flanders) for the financial support via the SBO-project 060843 'PolySpec'. We also want to thank BELSPO in the frame of network IAP P6/27 and for a post-doc fellowship (A. E. B.). Furthermore, the support of the Fund for Scientific Research-Flanders (FWO projects G.0161.03N, G.0252.04N and G.0091.07N) is acknowledged. | - |
dc.language.iso | en | - |
dc.publisher | JOHN WILEY & SONS LTD | - |
dc.subject.other | NMR; 1H; 13C; thiazolothiazole derivatives; chemical shift; prediction software; electropolymerization | - |
dc.title | Synthesis, H-1 and C-13 NMR assignment and electrochemical properties of novel thiophene-thiazolothiazole oligomers and polymers | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 369 | - |
dc.identifier.issue | 5 | - |
dc.identifier.spage | 362 | - |
dc.identifier.volume | 48 | - |
local.format.pages | 8 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Van Mierloo, S.; Chambon, S.; Boyukbayram, A. E.; Adriaensens, P.; Cleij, T. J.; Vanderzande, D.] Hasselt Univ, Inst Mat Res, B-3590 Diepenbeek, Belgium. [Boyukbayram, A. E.] Karabuk Univ, Dept Chem, TR-78050 Karabuk, Turkey. [Lutsen, L.] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. dirk.vanderzande@uhasselt.be | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1002/mrc.2593 | - |
dc.identifier.isi | 000277066800005 | - |
item.fulltext | With Fulltext | - |
item.fullcitation | VAN MIERLOO, Sarah; CHAMBON, Sylvain; BOYUKBAYRAM, Ayse; ADRIAENSENS, Peter; LUTSEN, Laurence; CLEIJ, Thomas & VANDERZANDE, Dirk (2010) Synthesis, H-1 and C-13 NMR assignment and electrochemical properties of novel thiophene-thiazolothiazole oligomers and polymers. In: MAGNETIC RESONANCE IN CHEMISTRY, 48 (5). p. 362-369. | - |
item.accessRights | Restricted Access | - |
item.contributor | VAN MIERLOO, Sarah | - |
item.contributor | CHAMBON, Sylvain | - |
item.contributor | BOYUKBAYRAM, Ayse | - |
item.contributor | ADRIAENSENS, Peter | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | CLEIJ, Thomas | - |
item.contributor | VANDERZANDE, Dirk | - |
item.validation | ecoom 2011 | - |
crisitem.journal.issn | 0749-1581 | - |
crisitem.journal.eissn | 1097-458X | - |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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lutsen.pdf Restricted Access | Published version | 213.86 kB | Adobe PDF | View/Open Request a copy |
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