Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/11844
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dc.contributor.authorDILIEN, Hanne-
dc.contributor.authorPALMAERTS, Arne-
dc.contributor.authorLenes, Martijn-
dc.contributor.authorde Boer, Bert-
dc.contributor.authorBlom, Paul-
dc.contributor.authorCLEIJ, Thomas-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorVANDERZANDE, Dirk-
dc.date.accessioned2011-04-05T11:39:21Z-
dc.date.availableNO_RESTRICTION-
dc.date.available2011-04-05T11:39:21Z-
dc.date.issued2010-
dc.identifier.citationMACROMOLECULES, 43(24). p. 10231-10240-
dc.identifier.issn0024-9297-
dc.identifier.urihttp://hdl.handle.net/1942/11844-
dc.description.abstractThe synthesis of, two new poly(thienylene vinylene) derivatives is described, i e poly(3 octyl-2,5 thienylene vinylene) (O-PTV) and poly(bis[octylpheny1-2,5 thienylene vinylene]) (BOP-PTV) Both polymers have been prepared via the dithiocarbamate (DTC) precursor route The polymerization protocol of the monomer toward the precursor polymer has been optimized by the use of different bases, leading to improved reproducibility of the polymerization step Processability has been guaranteed by the introduction of alkyl side chains Finally the precursor polymers were converted toward conjugated polymers and they were fully characterized by UV/vis, IR, GPC and cyclic voltammetry Bulk heterojunction solar cells with PCBM as acceptor showed promising power conversion efficiencies of 0 80% for BOP PTV and 0 92% for O-PTV-
dc.description.sponsorshipThe authors gratefully acknowledge BEL-SPO in the frame of network IAP P6/17 and the Fund for Scientific Research, Flanders (Belgium) (FWO) for financial support and for granting Ph D fellowships (H D and A P) The FWO is also gratefully acknowledged for the funding of the project G 0091 07 We also thank the European Science Foundation (ESF) for the received support for the activity entitled "New Generation of Organic based Photovoltaic Devices"-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.titleA deeper Insight into the Dithiocarbamate Precursor Route Synthesis of Soluble Poly(thienylene vinylene) Derivatives for Photovoltaic Applications-
dc.typeJournal Contribution-
dc.identifier.epage10240-
dc.identifier.issue24-
dc.identifier.spage10231-
dc.identifier.volume43-
local.format.pages10-
local.bibliographicCitation.jcatA1-
dc.description.notesVanderzande, D (reprint author),[Dilien, Hanne; Palmaerts, Arne; Cleij, Thomas J.; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Lutsen, Laurence; Vanderzande, Dirk] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. [Lenes, Martijin; de Boer, Bert; Blom, Paul] Univ Groningen, NL-9747 AG Groningen, Netherlands.-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1021/ma102101e-
dc.identifier.isi000285429400012-
item.fulltextNo Fulltext-
item.fullcitationDILIEN, Hanne; PALMAERTS, Arne; Lenes, Martijn; de Boer, Bert; Blom, Paul; CLEIJ, Thomas; LUTSEN, Laurence & VANDERZANDE, Dirk (2010) A deeper Insight into the Dithiocarbamate Precursor Route Synthesis of Soluble Poly(thienylene vinylene) Derivatives for Photovoltaic Applications. In: MACROMOLECULES, 43(24). p. 10231-10240.-
item.contributorDILIEN, Hanne-
item.contributorPALMAERTS, Arne-
item.contributorLenes, Martijn-
item.contributorde Boer, Bert-
item.contributorBlom, Paul-
item.contributorCLEIJ, Thomas-
item.contributorLUTSEN, Laurence-
item.contributorVANDERZANDE, Dirk-
item.validationecoom 2012-
item.accessRightsClosed Access-
crisitem.journal.issn0024-9297-
crisitem.journal.eissn1520-5835-
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