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http://hdl.handle.net/1942/11937
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DC Field | Value | Language |
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dc.contributor.author | Wong, Edgar H. H. | - |
dc.contributor.author | Stenzel, Martina H. | - |
dc.contributor.author | JUNKERS, Tanja | - |
dc.contributor.author | Barner-Kowollik, Christopher | - |
dc.date.accessioned | 2011-05-12T14:51:03Z | - |
dc.date.available | NO_RESTRICTION | - |
dc.date.available | 2011-05-12T14:51:03Z | - |
dc.date.issued | 2011 | - |
dc.identifier.citation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 49(10). p. 2118-2126 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.uri | http://hdl.handle.net/1942/11937 | - |
dc.description.abstract | A facile method to generate polymer materials with embedded functional groups at known and precise positions along the polymer backbone is described. In the presented approach, well-defined bifunctional poly(isobornyl acrylate)s preformed via atom transfer radical polymerization (ATRP) containing a, x-bromo end groups are reactivated and subsequently coupled in a stepwise manner via the nitrone-mediated radical coupling (NMRC) technique. The generated polymers contain on average four nitrone moieties at evenly spaced locations. The number of embedded functionalities, and thus, the size of the polymer is limited by disproportionation reactions occurring during the nitroxide termination sequence. Using the nitrone as a functional carrier, secondary functionalities can be incorporated into the polymer with ease. To exemplify such an approach, an alkyne-functionalized nitrone is used to construct a multisegment structure via NMRC reactions followed by postmodification of the obtained polymers with 3-mercaptopropionic acid via UV-induced thiol-yne reactions. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 2118-2126, 2011 | - |
dc.description.sponsorship | C.B.-K. is grateful for continued support from the Karlsruhe Institute of Technology (KIT) in the context of the Excellence Initiative for leading German universities, the German Research Council (DFG) and the Ministry of Arts and Science of the State of Baden-Wurttemberg. T.J. acknowledges funding from the Fonds Wetenschappelijk Onderzoek (FWO, project G.0491.11N). E. H. H. W. and C.B.-K. are thankful for a postgraduate scholarship from UNSW central funding. M. H. S. acknowledges receipt of a Future Fellowship from the Australian Research Council (ARC). | - |
dc.language.iso | en | - |
dc.publisher | WILEY-BLACKWELL | - |
dc.subject.other | ATRP; functionalization of polymers; nitrones; radical coupling reactions; radical spin traps; step-growth polymerization; thiol-yne | - |
dc.subject.other | ATRP; functionalization of polymers; nitrones; radical coupling reactions; radical spin traps; step-growth polymerization; thiol-yne | - |
dc.title | Embedding Multiple Site-Specific Functionalities into Polymer Chains via Nitrone-Mediated Radical Coupling Reactions | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 2126 | - |
dc.identifier.issue | 10 | - |
dc.identifier.spage | 2118 | - |
dc.identifier.volume | 49 | - |
local.format.pages | 9 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Junkers, Thomas] Univ Hasselt, Inst Mat Res, Polymer React Design Grp, B-3590 Diepenbeek, Belgium. [Wong, Edgar H. H.; Barner-Kowollik, Christopher] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. [Wong, Edgar H. H.; Stenzel, Martina H.] Univ New S Wales, CAMD, Sydney, NSW 2052, Australia. thomas.junkers@uhasselt.be; christopher.barner-kowollik@kit.edu | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1002/pola.24639 | - |
dc.identifier.isi | 000289443900002 | - |
item.fulltext | With Fulltext | - |
item.validation | ecoom 2012 | - |
item.accessRights | Restricted Access | - |
item.fullcitation | Wong, Edgar H. H.; Stenzel, Martina H.; JUNKERS, Tanja & Barner-Kowollik, Christopher (2011) Embedding Multiple Site-Specific Functionalities into Polymer Chains via Nitrone-Mediated Radical Coupling Reactions. In: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 49(10). p. 2118-2126. | - |
item.contributor | Wong, Edgar H. H. | - |
item.contributor | Stenzel, Martina H. | - |
item.contributor | JUNKERS, Tanja | - |
item.contributor | Barner-Kowollik, Christopher | - |
crisitem.journal.issn | 0887-624X | - |
crisitem.journal.eissn | 1099-0518 | - |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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junkers 1.pdf Restricted Access | Published version | 487.57 kB | Adobe PDF | View/Open Request a copy |
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