Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/12306
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dc.contributor.authorVANDENBERGH, Joke-
dc.contributor.authorDERGENT, Jeroen-
dc.contributor.authorCONINGS, Bert-
dc.contributor.authorTHALLURI, Krishna-
dc.contributor.authorMAES, Wouter-
dc.contributor.authorCLEIJ, Thomas-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorMANCA, Jean-
dc.contributor.authorVANDERZANDE, Dirk-
dc.date.accessioned2011-11-03T09:47:03Z-
dc.date.availableNO_RESTRICTION-
dc.date.available2011-11-03T09:47:03Z-
dc.date.issued2011-
dc.identifier.citationEUROPEAN POLYMER JOURNAL, 47(9). p. 1827-1835-
dc.identifier.issn0014-3057-
dc.identifier.urihttp://hdl.handle.net/1942/12306-
dc.description.abstractTwo hydrophilic branched oligo(ethylene glycol)-substituted PPV derivatives, poly(2,5-bis(1,3-bis(triethoxymethoxy)propan-2-yloxy)-1,4-phenylene vinylene) (BTEMP-PPV) and poly(2-methoxy-5-(1,3-bis(triethoxymethoxy)propan-2-yloxy)-1,4-phenylene vinylene) (MTEMP-PPV), are presented. Polymerizations have been performed via the dithiocarbamate precursor route, using lithium hexamethyldisilazide (LHMDS) as a base, to obtain high molecular weight precursor polymers. After thermal conversion of the precursor polymers into the fully conjugated systems, the solubility of the polymers has been examined. The polar nonionic side chains of MTEMP-PPV and BTEMP-PPV render the PPV backbone soluble in a variety of solvents, including alcohols and even water, making these polymers suitable candidates to be used in optoelectronic devices that can be processed from environmentally friendly solvent systems. (C) 2011 Elsevier Ltd. All rights reserved.-
dc.description.sponsorshipThe authors gratefully acknowledge the Fund for Scientific Research-Flanders (FWO) and the Belgian Science Policy (BELSPO) in the frame of network IAP P6/27, initiated by the Belgian State Prime Minister's Office, for the financial support. We also thank the Institute for the Promotion of Innovation through Science and Technology in Flanders (IWT) for financial support via the IWT-SBO project 060843 "Polyspec".-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subject.otherWater soluble conjugated polymers; PPV-type polymers; Precursor routes; Semi-conducting polymers-
dc.subject.otherWater soluble conjugated polymers; PPV-type polymers; Precursor routes; Semi-conducting polymers-
dc.titleSynthesis and characterization of water-soluble poly(p-phenylene vinylene) derivatives via the dithiocarbamate precursor route-
dc.typeJournal Contribution-
dc.identifier.epage1835-
dc.identifier.issue9-
dc.identifier.spage1827-
dc.identifier.volume47-
local.format.pages9-
local.bibliographicCitation.jcatA1-
dc.description.notesVanderzande, DJM (reprint author),[Vandenbergh, J; Dergent, J; Conings, B; Krishna, TVVG; Maes, W; Cleij, TJ; Manca, J; Vanderzande, DJM] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Lutsen, L; Manca, J; Vanderzande, DJM] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. [Maes, W] Katholieke Univ Leuven, B-3001 Heverlee, Belgium. dirk.vanderzande@uhasselt.be-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1016/j.eurpolymj.2011.06.014-
dc.identifier.isi000295070800011-
item.fullcitationVANDENBERGH, Joke; DERGENT, Jeroen; CONINGS, Bert; THALLURI, Krishna; MAES, Wouter; CLEIJ, Thomas; LUTSEN, Laurence; MANCA, Jean & VANDERZANDE, Dirk (2011) Synthesis and characterization of water-soluble poly(p-phenylene vinylene) derivatives via the dithiocarbamate precursor route. In: EUROPEAN POLYMER JOURNAL, 47(9). p. 1827-1835.-
item.validationecoom 2012-
item.contributorVANDENBERGH, Joke-
item.contributorDERGENT, Jeroen-
item.contributorCONINGS, Bert-
item.contributorTHALLURI, Krishna-
item.contributorMAES, Wouter-
item.contributorCLEIJ, Thomas-
item.contributorLUTSEN, Laurence-
item.contributorMANCA, Jean-
item.contributorVANDERZANDE, Dirk-
item.fulltextWith Fulltext-
item.accessRightsRestricted Access-
crisitem.journal.issn0014-3057-
crisitem.journal.eissn1873-1945-
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