Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/12339
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dc.contributor.authorCid, Juan-Jose-
dc.contributor.authorDUCHATEAU, Jan-
dc.contributor.authorVAN SEVEREN, Ineke-
dc.contributor.authorGanivet, Carolina R.-
dc.contributor.authorde la Torre, Gema-
dc.contributor.authorVazquez, Purificacion-
dc.contributor.authorCLEIJ, Thomas-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorTorres, Tomas-
dc.date.accessioned2011-11-10T16:33:43Z-
dc.date.availableNO_RESTRICTION-
dc.date.available2011-11-10T16:33:43Z-
dc.date.issued2011-
dc.identifier.citationJOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 15(7-8). p. 659-666-
dc.identifier.issn1088-4246-
dc.identifier.urihttp://hdl.handle.net/1942/12339-
dc.description.abstractHigh molecular weight poly(p-phenylenenevinylene) PPV copolymers laterally substituted with zinc (II) phthalocyanines (Zn(II) Pc-PPV 1 and 2) have been synthesized by means of post-polymerization functionalization reactions through DCC-mediated esterifications between hydroxy-phthalocyanines 4 and 6 and carboxy-bearer PPV copolymers, comprising 2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylene-vinylene (MDMO-PPV) and 1,4-(2-(5-carboxypentyloxy)-5-methoxyphenylenevinylene (CPM-PPV) units in a 9: 1 (3) and 1: 1 (5) ratio, respectively. The resulting copolymer 1 contains a 7 mol % of Pc molecules, while copolymer 2, which is isolated as the soluble fraction of the reaction with the starting 1: 1 copolymer (namely having around 50% of COOH-containing monomeric units), holds a 9 mol % of zinc(II) phthalocyanines. 1 and 2 were fully characterized by (1)H NMR, UV-vis and FT-IR spectroscopies.-
dc.description.sponsorshipThe authors want to thank for financial support to The Research Foundation - Flanders (FWO)/project No. G009107VDZ, the European Science Foundation (ESF) for the ORGANISOLAR Network Program and for the EUROCORES (ESF) Program SONS2 (CRP SOHYDs), that is also supported by funds from the FWO (G. 068506), the UHasselt (Research Fund) and the EC Sixth Framework Program under Contract ERAS-CT-2003-980409. Financial support from the MICINN and MEC (Spain) (CTQ2008-00418/BQU and PLE2009-0070), Comunidad de Madrid (MADRISOLAR-2, S2009/PPQ/1533) and EU (MRTN-CT-2006-035533 Solar-N-type) is gratefully acknowledged.-
dc.language.isoen-
dc.publisherWORLD SCI PUBL CO INC-
dc.subject.otherconjugated polymers; poly(p-phenylenevinylene); phthalocyanines; covalent functionalization-
dc.subject.otherconjugated polymers; poly(p-phenylenevinylene); phthalocyanines; covalent functionalization-
dc.titleSynthesis and characterization of high molecular weight phthalocyanine-PPV copolymers through post-polymerization functionalization-
dc.typeJournal Contribution-
dc.identifier.epage666-
dc.identifier.issue7-8-
dc.identifier.spage659-
dc.identifier.volume15-
local.format.pages8-
local.bibliographicCitation.jcatA1-
dc.description.notesTorres, T (reprint author),[Cid, JJ; Ganivet, CR; de la Torre, G; Vazquez, P; Torres, T] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain. [Duchateau, J; Van Severen, I; Cleij, T; Vanderzande, D] Univ Hasselt, Inst Mat Res, B-3590 Diepenbeek, Belgium. [Lutsen, L; Vanderzande, D] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. [Torres, T] Fac Ciencias, IMDEA Nanociencia, Madrid 28049, Spain. dirk.vanderzande@uhasselt.be; tomas.torres@uam.es-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1142/S1088424611003562-
dc.identifier.isi000295053100021-
item.validationecoom 2012-
item.fulltextNo Fulltext-
item.accessRightsClosed Access-
item.fullcitationCid, Juan-Jose; DUCHATEAU, Jan; VAN SEVEREN, Ineke; Ganivet, Carolina R.; de la Torre, Gema; Vazquez, Purificacion; CLEIJ, Thomas; LUTSEN, Laurence; VANDERZANDE, Dirk & Torres, Tomas (2011) Synthesis and characterization of high molecular weight phthalocyanine-PPV copolymers through post-polymerization functionalization. In: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 15(7-8). p. 659-666.-
item.contributorLUTSEN, Laurence-
item.contributorVANDERZANDE, Dirk-
item.contributorCLEIJ, Thomas-
item.contributorVAN SEVEREN, Ineke-
item.contributorTorres, Tomas-
item.contributorVazquez, Purificacion-
item.contributorCid, Juan-Jose-
item.contributorDUCHATEAU, Jan-
item.contributorGanivet, Carolina R.-
item.contributorde la Torre, Gema-
crisitem.journal.issn1088-4246-
crisitem.journal.eissn1099-1409-
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