Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/12352
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dc.contributor.authorThomas, Joice-
dc.contributor.authorVan Hecke, Kristof-
dc.contributor.authorRobeyns, Koen-
dc.contributor.authorVan Rossom, Wim-
dc.contributor.authorSonawane, Mahendra P.-
dc.contributor.authorVan Meervelt, Luc-
dc.contributor.authorSmet, Mario-
dc.contributor.authorMAES, Wouter-
dc.contributor.authorDehaen, Wim-
dc.date.accessioned2011-11-14T13:02:36Z-
dc.date.availableNO_RESTRICTION-
dc.date.available2011-11-14T13:02:36Z-
dc.date.issued2011-
dc.identifier.citationCHEMISTRY-A EUROPEAN JOURNAL, 17 (37). p. 10339-10349-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/1942/12352-
dc.description.abstractHomothiacalix[n]arenes have been largely underexposed compared with related (homo)heteracalixarenes, although their inherent structural features are particularly attractive for supramolecular host-guest chemistry. In this contribution, the synthetic macrocyclization protocols that afford homothiacalix[n]arenes have been reinvestigated and optimized, providing straightforward access to the parent homothiacalix[4] arene skeleton. More-over, inner-rim (bis and tetrakis) ester functionalization and dimethylenethia bridge oxidation were successfully performed as well. Solution-phase (variable-temperature) NMR spectroscopy studies and solid-state X-ray structures provided complementary information on the conformational features of the novel macrocycles.-
dc.description.sponsorshipWe thank the FWO (Fund for Scientific Research, Flanders), the KU Leuven, and the Ministerie voor Wetenschapsbeleid for continuing financial support.-
dc.language.isoen-
dc.publisherWILEY-BLACKWELL-
dc.subject.othercalixarenes; conformation analysis; macrocyclic ligands; solid-state structures; supramolecular chemistry-
dc.titleHomothiacalix[4]arenes: Synthetic Exploration and Solid-State Structures-
dc.typeJournal Contribution-
dc.identifier.epage10349-
dc.identifier.issue37-
dc.identifier.spage10339-
dc.identifier.volume17-
local.format.pages11-
local.bibliographicCitation.jcatA1-
dc.description.notes[Thomas, J; Van Hecke, K; Robeyns, K; Van Rossom, W; Sonawane, MP; Van Meervelt, L; Smet, M; Maes, W; Dehaen, W] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium. [Maes, W] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Robeyns, K] Catholic Univ Louvain, Inst Condensed Matter & Nanosci IMCN, B-1348 Louvain, Belgium. wouter.maes@uhasselt.be; wim.dehaen@chem.kuleuven.be-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1002/chem.201101690-
dc.identifier.isi000295457700019-
item.fulltextWith Fulltext-
item.fullcitationThomas, Joice; Van Hecke, Kristof; Robeyns, Koen; Van Rossom, Wim; Sonawane, Mahendra P.; Van Meervelt, Luc; Smet, Mario; MAES, Wouter & Dehaen, Wim (2011) Homothiacalix[4]arenes: Synthetic Exploration and Solid-State Structures. In: CHEMISTRY-A EUROPEAN JOURNAL, 17 (37). p. 10339-10349.-
item.validationecoom 2012-
item.accessRightsRestricted Access-
item.contributorThomas, Joice-
item.contributorVan Hecke, Kristof-
item.contributorRobeyns, Koen-
item.contributorVan Rossom, Wim-
item.contributorSonawane, Mahendra P.-
item.contributorVan Meervelt, Luc-
item.contributorSmet, Mario-
item.contributorMAES, Wouter-
item.contributorDehaen, Wim-
crisitem.journal.issn0947-6539-
crisitem.journal.eissn1521-3765-
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