Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/13036
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dc.contributor.authorKruk, Mikalai M.-
dc.contributor.authorStarukhin, S. Alexander-
dc.contributor.authorMAES, Wouter-
dc.date.accessioned2012-01-19T12:13:08Z-
dc.date.available2012-01-19T12:13:08Z-
dc.date.issued2011-
dc.identifier.citationMacroheterocycles, 4(2), p. 69-79-
dc.identifier.issn1998-9539-
dc.identifier.urihttp://hdl.handle.net/1942/13036-
dc.description.abstractAnalysis of the relationship between the molecular structure of porphyrins and the spectral features of their monoand diprotonated forms in solution is presented. The evolution of the concept of the role of acid-base equilibria in the formation of the spectral properties and the excitation energy deactivation pathways in porphyrins are reviewed. The trends observed in the fluorescence and intersystem crossing quantum yields on going from free base porphyrins to their mono- and diprotonated forms are analyzed, and the mechanisms involved are discussed.-
dc.description.sponsorshipThis work was supported by the Foundation for Fundamental Research of the Republic of Belarus (project Ch10R-001) and a FP-7 grant from the EC for Research, Technological Development and Demonstration Activities, "Dendrimers for Photonic Devices" IRSES-PEOPLE-2009-247260-DphotoD, under the "International Research Staff Exchange Scheme". W. Maes also thanks the FWO (Fund for Scientific Research - Flanders), the KU Leuven, Hasselt University and the Ministerie voor Wetenschapsbeleid for continuing financial support.-
dc.language.isoen-
dc.subject.otherPorphyrin; monoprotonated form; excited states; intersystem crossing; internal conversion; fluorescence; heavy atom effect-
dc.titleInfluence of macrocycle protonation on the photophysical properties of porphyrins. A review-
dc.typeJournal Contribution-
dc.identifier.epage79-
dc.identifier.issue2-
dc.identifier.spage69-
dc.identifier.volume4-
local.bibliographicCitation.jcatA1-
local.type.refereedRefereed-
local.type.specifiedReview-
dc.bibliographicCitation.oldjcatA2-
dc.identifier.isi000209017200001-
item.fulltextWith Fulltext-
item.contributorKruk, Mikalai M.-
item.contributorStarukhin, S. Alexander-
item.contributorMAES, Wouter-
item.fullcitationKruk, Mikalai M.; Starukhin, S. Alexander & MAES, Wouter (2011) Influence of macrocycle protonation on the photophysical properties of porphyrins. A review. In: Macroheterocycles, 4(2), p. 69-79.-
item.accessRightsClosed Access-
crisitem.journal.issn1998-9539-
crisitem.journal.eissn1998-9539-
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