Please use this identifier to cite or link to this item:
http://hdl.handle.net/1942/13060
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | CHAMBON, Sylvain | - |
dc.contributor.author | MENS, Raoul | - |
dc.contributor.author | VANDEWAL, Koen | - |
dc.contributor.author | Clodic, Ewan | - |
dc.contributor.author | Scharber, Markus | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | GELAN, Jan | - |
dc.contributor.author | MANCA, Jean | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | ADRIAENSENS, Peter | - |
dc.date.accessioned | 2012-01-23T13:20:01Z | - |
dc.date.available | 2012-01-23T13:20:01Z | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | SOLAR ENERGY MATERIALS AND SOLAR CELLS, 96(1), p. 210-217 | - |
dc.identifier.issn | 0927-0248 | - |
dc.identifier.uri | http://hdl.handle.net/1942/13060 | - |
dc.description.abstract | The influence of octanedithiol (ODT) on the film morphology of PCPDTBT:PCBM (1:2) blends processed from solutions in chlorobenzene was studied by chemical shift selective carbon-13 solid-state NMR relaxation experiments. A close contact between PCBM and PCPDTBT is demonstrated for PCPDTBT:PCBM films processed with as well as without ODT, i.e. the dimensions of the substructures in the PCBM rich and polymer rich domains are smaller than 10 nm. The PCBM organization is shown to be reduced towards very small and weakly organized clusters. The main difference of processing the active film in the presence of ODT can be found in the ability of the polymer to improve its chain packing towards a state that closely resembles this of pure PCPDTBT. This difference in physical interaction between the polymer chains can explain the improved power conversion efficiency and the EQE red-shift of solar cells processed with ODT. (C) 2011 Elsevier B.V. All rights reserved. | - |
dc.description.sponsorship | The authors gratefully acknowledge the EU for the FP6-Marie Curie-RTN ‘‘SolarNtype’’ (MRTN-CT-2006-035533), the IWT (Institute for the Promotion of Innovation by Science and Technology in Flanders) for the financial support via the SBO-project 060843 ‘‘PolySpec’’. We also want to thank BELSPO in the frame of network IAP P6/27 and the Fund for Scientific Research-Flanders (FWO projects G.0252.04N and G.0091.07N). Last but not least, we would also like to thank Bart Ruttens and Jan D’Haen for the X-Ray Diffraction experiments. | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.rights | 2011 Elsevier B.V. All rights reserved. | - |
dc.subject.other | NMR relaxation | - |
dc.subject.other | Organic solar cells | - |
dc.subject.other | PCPDTBT | - |
dc.subject.other | Film morphology | - |
dc.subject.other | ODT thiols | - |
dc.title | Influence of octanedithiol on the nanomorphology of PCPDTBT:PCBM blends studied by solid-state NMR | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 217 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 210 | - |
dc.identifier.volume | 96 | - |
local.format.pages | 8 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Chambon, Sylvain; Mens, Raoul; Vandewal, Koen; Gelan, Jan; Manca, Jean; Vanderzande, Dirk; Adriaensens, Peter] Hasselt Univ, Inst Mat Res IMO Div Chem, B-3590 Diepenbeek, Belgium. [Clodic, Ewan; Scharber, Markus] Konarka Austria, A-4040 Linz, Austria. [Lutsen, Laurence; Manca, Jean; Vanderzande, Dirk] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. | - |
local.publisher.place | RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1016/j.solmat.2011.09.061 | - |
dc.identifier.isi | 000298534000029 | - |
local.uhasselt.international | yes | - |
item.fullcitation | CHAMBON, Sylvain; MENS, Raoul; VANDEWAL, Koen; Clodic, Ewan; Scharber, Markus; LUTSEN, Laurence; GELAN, Jan; MANCA, Jean; VANDERZANDE, Dirk & ADRIAENSENS, Peter (2012) Influence of octanedithiol on the nanomorphology of PCPDTBT:PCBM blends studied by solid-state NMR. In: SOLAR ENERGY MATERIALS AND SOLAR CELLS, 96(1), p. 210-217. | - |
item.contributor | CHAMBON, Sylvain | - |
item.contributor | MENS, Raoul | - |
item.contributor | VANDEWAL, Koen | - |
item.contributor | Clodic, Ewan | - |
item.contributor | Scharber, Markus | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | GELAN, Jan | - |
item.contributor | MANCA, Jean | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | ADRIAENSENS, Peter | - |
item.validation | ecoom 2013 | - |
item.accessRights | Restricted Access | - |
item.fulltext | With Fulltext | - |
crisitem.journal.issn | 0927-0248 | - |
crisitem.journal.eissn | 1879-3398 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
chambon1.pdf Restricted Access | Published version | 478.47 kB | Adobe PDF | View/Open Request a copy |
SCOPUSTM
Citations
19
checked on Sep 2, 2020
WEB OF SCIENCETM
Citations
20
checked on May 1, 2024
Page view(s)
68
checked on Jun 13, 2022
Download(s)
52
checked on Jun 13, 2022
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.