Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/13205
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dc.contributor.authorCOSEMANS, Inge-
dc.contributor.authorWOUTERS, Jimmy-
dc.contributor.authorCLEIJ, Thomas-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorMAES, Wouter-
dc.contributor.authorJUNKERS, Tanja-
dc.contributor.authorVANDERZANDE, Dirk-
dc.date.accessioned2012-02-24T14:30:57Z-
dc.date.available2012-02-24T14:30:57Z-
dc.date.issued2012-
dc.identifier.citationMACROMOLECULAR RAPID COMMUNICATIONS, 33 (3), p. 242-247-
dc.identifier.issn1022-1336-
dc.identifier.urihttp://hdl.handle.net/1942/13205-
dc.description.abstractThe anionic polymerization of PPV via the sulfinyl precursor route is further investigated. When LHMDS is employed as the base to form the actively propagating quinodimethane system and THF as the solvent, anionic polymerizations can be observed. With the use of tert- butyl-substituted anionic initiators, specific functional groups can be built in the polymer chain and the chain length can be efficiently controlled, which is demonstrated here for the first time. With introduction of branched side chains on the aromatic core, soluble conjugated PPV material can be obtained with molecular weights in the range of 500016 000 g mol-1.-
dc.description.sponsorshipThe authors gratefully acknowledge the Institute for the Promotion of Innovation by Science and Technology in Flanders (IWT) for the financial support via the SBO-project 060843 "PolySpec." The Bijzonder OnderzoeksFonds (BOF) of the UHasselt is acknowledged for the PhD grants for J.W. and I. C. T.J. is grateful for funding in the framework of the Odysseus scheme from the Fonds Wetenschapelijk Onderzoek (FWO).-
dc.language.isoen-
dc.publisherWILEY-BLACKWELL-
dc.subject.otherAnionic initiators; anionic polymerization; living polymerization; poly(p-phenylene vinylene); sulfinyl precursor route-
dc.subject.otherPolymer Science; Anionic initiators; anionic polymerization; living polymerization; poly(p-phenylene vinylene); sulfinyl precursor route-
dc.titleLiving Polymerization via Anionic Initiation for the Synthesis of Well-Defined PPV Materials-
dc.typeJournal Contribution-
dc.identifier.epage247-
dc.identifier.issue3-
dc.identifier.spage242-
dc.identifier.volume33-
local.format.pages6-
local.bibliographicCitation.jcatA1-
dc.description.notes[Cosemans, Inge; Wouters, Jimmy; Cleij, Thomas; Maes, Wouter; Junkers, Thomas; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res IMO Organ & Bio Polymer Chem, B-3590 Diepenbeek, Belgium. [Lutsen, Laurence] IMEC Div IMOMEC, B-3590 Diepenbeek, Belgium. dirk.vanderzande@uhasselt.be-
local.publisher.placeMALDEN-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1002/marc.201100758-
dc.identifier.isi000299689600009-
item.fullcitationCOSEMANS, Inge; WOUTERS, Jimmy; CLEIJ, Thomas; LUTSEN, Laurence; MAES, Wouter; JUNKERS, Tanja & VANDERZANDE, Dirk (2012) Living Polymerization via Anionic Initiation for the Synthesis of Well-Defined PPV Materials. In: MACROMOLECULAR RAPID COMMUNICATIONS, 33 (3), p. 242-247.-
item.fulltextWith Fulltext-
item.validationecoom 2013-
item.contributorCOSEMANS, Inge-
item.contributorWOUTERS, Jimmy-
item.contributorCLEIJ, Thomas-
item.contributorLUTSEN, Laurence-
item.contributorMAES, Wouter-
item.contributorJUNKERS, Tanja-
item.contributorVANDERZANDE, Dirk-
item.accessRightsRestricted Access-
crisitem.journal.issn1022-1336-
crisitem.journal.eissn1521-3927-
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