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http://hdl.handle.net/1942/13205
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DC Field | Value | Language |
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dc.contributor.author | COSEMANS, Inge | - |
dc.contributor.author | WOUTERS, Jimmy | - |
dc.contributor.author | CLEIJ, Thomas | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | MAES, Wouter | - |
dc.contributor.author | JUNKERS, Tanja | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.date.accessioned | 2012-02-24T14:30:57Z | - |
dc.date.available | 2012-02-24T14:30:57Z | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | MACROMOLECULAR RAPID COMMUNICATIONS, 33 (3), p. 242-247 | - |
dc.identifier.issn | 1022-1336 | - |
dc.identifier.uri | http://hdl.handle.net/1942/13205 | - |
dc.description.abstract | The anionic polymerization of PPV via the sulfinyl precursor route is further investigated. When LHMDS is employed as the base to form the actively propagating quinodimethane system and THF as the solvent, anionic polymerizations can be observed. With the use of tert- butyl-substituted anionic initiators, specific functional groups can be built in the polymer chain and the chain length can be efficiently controlled, which is demonstrated here for the first time. With introduction of branched side chains on the aromatic core, soluble conjugated PPV material can be obtained with molecular weights in the range of 500016 000 g mol-1. | - |
dc.description.sponsorship | The authors gratefully acknowledge the Institute for the Promotion of Innovation by Science and Technology in Flanders (IWT) for the financial support via the SBO-project 060843 "PolySpec." The Bijzonder OnderzoeksFonds (BOF) of the UHasselt is acknowledged for the PhD grants for J.W. and I. C. T.J. is grateful for funding in the framework of the Odysseus scheme from the Fonds Wetenschapelijk Onderzoek (FWO). | - |
dc.language.iso | en | - |
dc.publisher | WILEY-BLACKWELL | - |
dc.subject.other | Anionic initiators; anionic polymerization; living polymerization; poly(p-phenylene vinylene); sulfinyl precursor route | - |
dc.subject.other | Polymer Science; Anionic initiators; anionic polymerization; living polymerization; poly(p-phenylene vinylene); sulfinyl precursor route | - |
dc.title | Living Polymerization via Anionic Initiation for the Synthesis of Well-Defined PPV Materials | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 247 | - |
dc.identifier.issue | 3 | - |
dc.identifier.spage | 242 | - |
dc.identifier.volume | 33 | - |
local.format.pages | 6 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Cosemans, Inge; Wouters, Jimmy; Cleij, Thomas; Maes, Wouter; Junkers, Thomas; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res IMO Organ & Bio Polymer Chem, B-3590 Diepenbeek, Belgium. [Lutsen, Laurence] IMEC Div IMOMEC, B-3590 Diepenbeek, Belgium. dirk.vanderzande@uhasselt.be | - |
local.publisher.place | MALDEN | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1002/marc.201100758 | - |
dc.identifier.isi | 000299689600009 | - |
item.accessRights | Restricted Access | - |
item.fullcitation | COSEMANS, Inge; WOUTERS, Jimmy; CLEIJ, Thomas; LUTSEN, Laurence; MAES, Wouter; JUNKERS, Tanja & VANDERZANDE, Dirk (2012) Living Polymerization via Anionic Initiation for the Synthesis of Well-Defined PPV Materials. In: MACROMOLECULAR RAPID COMMUNICATIONS, 33 (3), p. 242-247. | - |
item.validation | ecoom 2013 | - |
item.contributor | COSEMANS, Inge | - |
item.contributor | WOUTERS, Jimmy | - |
item.contributor | CLEIJ, Thomas | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | MAES, Wouter | - |
item.contributor | JUNKERS, Tanja | - |
item.contributor | VANDERZANDE, Dirk | - |
item.fulltext | With Fulltext | - |
crisitem.journal.issn | 1022-1336 | - |
crisitem.journal.eissn | 1521-3927 | - |
Appears in Collections: | Research publications |
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cosemans1.pdf Restricted Access | Published version | 489.92 kB | Adobe PDF | View/Open Request a copy |
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