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http://hdl.handle.net/1942/13811
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DC Field | Value | Language |
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dc.contributor.author | Voll, Dominik | - |
dc.contributor.author | JUNKERS, Tanja | - |
dc.contributor.author | Barner-Kowollik, Christopher | - |
dc.date.accessioned | 2012-07-17T14:07:50Z | - |
dc.date.available | 2012-07-17T14:07:50Z | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 50 (14), p. 2739-2757 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.uri | http://hdl.handle.net/1942/13811 | - |
dc.description.abstract | The current article contains a review of the electrospray ionization-mass spectrometry characterization of polymers prepared via thermal- and photoinitiation processes. The used analysis method permits direct access to detailed endgroup information. For a qualitative and quantitative endgroup analysis, sophisticated methods have been developed which provide a detailed image of the incorporation propensity of thermally as well as photolytically generated radicals at the polymer chain termini. Such a post-mortem analysis of polymeric materials specifically allows for the quantification of the ability of radical fragments to initiate polymerization processes. Herein, the most recent progress in the field of mass spectrometric radical reactivity mapping is outlined and open questions as well as future directions are discussed. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 | - |
dc.description.sponsorship | C.B.-K acknowledges financial support for the current project from the German Research Council (DFG) as well as from the Karlsruhe Institute of Technology (KIT) in the context of the Excellence Initiative for leading German universities and the Ministry for Science and Arts of the state of BadenWu¨ rttemberg. T.J. is grateful for funding from the Fonds Wetenschappelijk Onderzoek (FWO) in the framework of the Odysseus scheme. | - |
dc.language.iso | en | - |
dc.publisher | WILEY-BLACKWELL | - |
dc.rights | 2012 Wiley Periodicals, Inc | - |
dc.subject.other | initiators | - |
dc.subject.other | mass spectrometry | - |
dc.subject.other | size exclusion chromatography (SEC) | - |
dc.subject.other | laser-induced polymers | - |
dc.subject.other | photopolymerization | - |
dc.subject.other | radical polymerization | - |
dc.subject.other | thermal initiators | - |
dc.title | A qualitative and quantitative post-mortem analysis: Studying free-radical initiation processes via soft ionization mass spectrometry | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 2757 | - |
dc.identifier.issue | 14 | - |
dc.identifier.spage | 2739 | - |
dc.identifier.volume | 50 | - |
local.format.pages | 19 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Junkers, Thomas] Univ Hasselt, Inst Mat Res IMO, Polymer React Design Grp, BE-3590 Diepenbeek, Belgium. [Voll, Dominik; Barner-Kowollik, Christopher] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. | - |
local.publisher.place | HOBOKEN | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1002/pola.26076 | - |
dc.identifier.isi | 000304813300001 | - |
dc.identifier.eissn | 1099-0518 | - |
local.uhasselt.international | yes | - |
item.fullcitation | Voll, Dominik; JUNKERS, Tanja & Barner-Kowollik, Christopher (2012) A qualitative and quantitative post-mortem analysis: Studying free-radical initiation processes via soft ionization mass spectrometry. In: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 50 (14), p. 2739-2757. | - |
item.fulltext | With Fulltext | - |
item.validation | ecoom 2013 | - |
item.accessRights | Restricted Access | - |
item.contributor | Voll, Dominik | - |
item.contributor | JUNKERS, Tanja | - |
item.contributor | Barner-Kowollik, Christopher | - |
crisitem.journal.issn | 0887-624X | - |
crisitem.journal.eissn | 1099-0518 | - |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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voll1.pdf Restricted Access | Published version | 5.86 MB | Adobe PDF | View/Open Request a copy |
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