Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/13968
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dc.contributor.authorThomas, Joice-
dc.contributor.authorDobrzanska, Liliana-
dc.contributor.authorVan Hecke, Kristof-
dc.contributor.authorSonawane, Mahendra P.-
dc.contributor.authorRobeyns, Koen-
dc.contributor.authorVan Meervelt, Luc-
dc.contributor.authorWozniak, Krzysztof-
dc.contributor.authorSmet, Mario-
dc.contributor.authorMAES, Wouter-
dc.contributor.authorDehaen, Wim-
dc.date.accessioned2012-09-07T12:30:39Z-
dc.date.available2012-09-07T12:30:39Z-
dc.date.issued2012-
dc.identifier.citationORGANIC & BIOMOLECULAR CHEMISTRY, 10 (32), p. 6526-6536-
dc.identifier.issn1477-0520-
dc.identifier.urihttp://hdl.handle.net/1942/13968-
dc.description.abstractHomoselenacalix[4]arenes were synthesized by a [2 + 2] reductive coupling protocol favouring the cyclotetramers. The inner and outer-rim decoration was varied and a bicyclic derivative was prepared by a similar one-pot procedure. Conformational analysis in solution and the solid state showed noticeable differences between the homoselenacalix[4]arenes and the analogous homothiacalix[4]arenes and provided insight into the metal binding potential of the Se-bridged macrocycles. The homoselenacalix[4]arenes were found to bind Ag(I). Complexation was visualized in the solid state and different packing networks were formed depending on the counter ions applied.-
dc.description.sponsorshipWe thank the FWO (Fund for Scientific Research - Flanders), the KU Leuven and the Ministerie voor Wetenschapsbeleid for continuing financial support.-
dc.language.isoen-
dc.publisherROYAL SOC CHEMISTRY-
dc.subject.otherOrganic Chemistry-
dc.titleHomoselenacalix[4]arenes: synthetic exploration and metallosupramolecular chemistry-
dc.typeJournal Contribution-
dc.identifier.epage6536-
dc.identifier.issue32-
dc.identifier.spage6526-
dc.identifier.volume10-
local.format.pages11-
local.bibliographicCitation.jcatA1-
dc.description.notesMaes, W (reprint author), Katholieke Univ Leuven, Dept Chem, Celestijnenlaan 200F, B-3001 Louvaine La Neuve, Belgium, [Thomas, Joice; Dobrzanska, Liliana; Van Hecke, Kristof; Sonawane, Mahendra P.; Robeyns, Koen; Van Meervelt, Luc; Smet, Mario; Maes, Wouter; Dehaen, Wim] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium. [Van Hecke, Kristof] Univ Ghent, Dept Inorgan & Phys Chem Grp, B-9000 Ghent, Belgium. [Robeyns, Koen] Univ Catholique Louvain UCL, Inst Condensed Matter & Nanosci IMCN, B-1348 Louvain, Belgium. [Wozniak, Krzysztof] Warsaw Univ, Dept Chem, PL-02093 Warsaw, Poland. [Maes, Wouter] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium. wouter.maes@uhasselt.be; wim.dehaen@chem.kuleuven.be-
local.publisher.placeCAMBRIDGE-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1039/c2ob25760b-
dc.identifier.isi000306854600011-
item.fulltextWith Fulltext-
item.contributorThomas, Joice-
item.contributorDobrzanska, Liliana-
item.contributorVan Hecke, Kristof-
item.contributorSonawane, Mahendra P.-
item.contributorRobeyns, Koen-
item.contributorVan Meervelt, Luc-
item.contributorWozniak, Krzysztof-
item.contributorSmet, Mario-
item.contributorMAES, Wouter-
item.contributorDehaen, Wim-
item.accessRightsOpen Access-
item.validationecoom 2013-
item.fullcitationThomas, Joice; Dobrzanska, Liliana; Van Hecke, Kristof; Sonawane, Mahendra P.; Robeyns, Koen; Van Meervelt, Luc; Wozniak, Krzysztof; Smet, Mario; MAES, Wouter & Dehaen, Wim (2012) Homoselenacalix[4]arenes: synthetic exploration and metallosupramolecular chemistry. In: ORGANIC & BIOMOLECULAR CHEMISTRY, 10 (32), p. 6526-6536.-
crisitem.journal.issn1477-0520-
crisitem.journal.eissn1477-0539-
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