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http://hdl.handle.net/1942/13968
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DC Field | Value | Language |
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dc.contributor.author | Thomas, Joice | - |
dc.contributor.author | Dobrzanska, Liliana | - |
dc.contributor.author | Van Hecke, Kristof | - |
dc.contributor.author | Sonawane, Mahendra P. | - |
dc.contributor.author | Robeyns, Koen | - |
dc.contributor.author | Van Meervelt, Luc | - |
dc.contributor.author | Wozniak, Krzysztof | - |
dc.contributor.author | Smet, Mario | - |
dc.contributor.author | MAES, Wouter | - |
dc.contributor.author | Dehaen, Wim | - |
dc.date.accessioned | 2012-09-07T12:30:39Z | - |
dc.date.available | 2012-09-07T12:30:39Z | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | ORGANIC & BIOMOLECULAR CHEMISTRY, 10 (32), p. 6526-6536 | - |
dc.identifier.issn | 1477-0520 | - |
dc.identifier.uri | http://hdl.handle.net/1942/13968 | - |
dc.description.abstract | Homoselenacalix[4]arenes were synthesized by a [2 + 2] reductive coupling protocol favouring the cyclotetramers. The inner and outer-rim decoration was varied and a bicyclic derivative was prepared by a similar one-pot procedure. Conformational analysis in solution and the solid state showed noticeable differences between the homoselenacalix[4]arenes and the analogous homothiacalix[4]arenes and provided insight into the metal binding potential of the Se-bridged macrocycles. The homoselenacalix[4]arenes were found to bind Ag(I). Complexation was visualized in the solid state and different packing networks were formed depending on the counter ions applied. | - |
dc.description.sponsorship | We thank the FWO (Fund for Scientific Research - Flanders), the KU Leuven and the Ministerie voor Wetenschapsbeleid for continuing financial support. | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject.other | Organic Chemistry | - |
dc.title | Homoselenacalix[4]arenes: synthetic exploration and metallosupramolecular chemistry | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 6536 | - |
dc.identifier.issue | 32 | - |
dc.identifier.spage | 6526 | - |
dc.identifier.volume | 10 | - |
local.format.pages | 11 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | Maes, W (reprint author), Katholieke Univ Leuven, Dept Chem, Celestijnenlaan 200F, B-3001 Louvaine La Neuve, Belgium, [Thomas, Joice; Dobrzanska, Liliana; Van Hecke, Kristof; Sonawane, Mahendra P.; Robeyns, Koen; Van Meervelt, Luc; Smet, Mario; Maes, Wouter; Dehaen, Wim] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium. [Van Hecke, Kristof] Univ Ghent, Dept Inorgan & Phys Chem Grp, B-9000 Ghent, Belgium. [Robeyns, Koen] Univ Catholique Louvain UCL, Inst Condensed Matter & Nanosci IMCN, B-1348 Louvain, Belgium. [Wozniak, Krzysztof] Warsaw Univ, Dept Chem, PL-02093 Warsaw, Poland. [Maes, Wouter] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium. wouter.maes@uhasselt.be; wim.dehaen@chem.kuleuven.be | - |
local.publisher.place | CAMBRIDGE | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1039/c2ob25760b | - |
dc.identifier.isi | 000306854600011 | - |
item.contributor | Thomas, Joice | - |
item.contributor | Dobrzanska, Liliana | - |
item.contributor | Van Hecke, Kristof | - |
item.contributor | Sonawane, Mahendra P. | - |
item.contributor | Robeyns, Koen | - |
item.contributor | Van Meervelt, Luc | - |
item.contributor | Wozniak, Krzysztof | - |
item.contributor | Smet, Mario | - |
item.contributor | MAES, Wouter | - |
item.contributor | Dehaen, Wim | - |
item.validation | ecoom 2013 | - |
item.accessRights | Open Access | - |
item.fullcitation | Thomas, Joice; Dobrzanska, Liliana; Van Hecke, Kristof; Sonawane, Mahendra P.; Robeyns, Koen; Van Meervelt, Luc; Wozniak, Krzysztof; Smet, Mario; MAES, Wouter & Dehaen, Wim (2012) Homoselenacalix[4]arenes: synthetic exploration and metallosupramolecular chemistry. In: ORGANIC & BIOMOLECULAR CHEMISTRY, 10 (32), p. 6526-6536. | - |
item.fulltext | With Fulltext | - |
crisitem.journal.issn | 1477-0520 | - |
crisitem.journal.eissn | 1477-0539 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
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Homoselenacalix[4]arenes synthetic exploration and metallosupramolecular chemistry.pdf | Published version | 1.75 MB | Adobe PDF | View/Open |
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