Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/14251
Full metadata record
DC FieldValueLanguage
dc.contributor.authorRANIERI, Kayte-
dc.contributor.authorCONRADI, Matthias Horst-
dc.contributor.authorChavant, Pierre-Yves-
dc.contributor.authorBlandin, Veronique-
dc.contributor.authorBarner-Kowollik, Christopher-
dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2012-10-12T09:46:14Z-
dc.date.available2012-10-12T09:46:14Z-
dc.date.issued2012-
dc.identifier.citationAUSTRALIAN JOURNAL OF CHEMISTRY, 65 (8), p. 1110-1116-
dc.identifier.issn0004-9425-
dc.identifier.urihttp://hdl.handle.net/1942/14251-
dc.description.abstractA series of cyclic nitrones have been tested for their spin-trapping activity in the enhanced spin-capturing polymerization of styrene and in nitrone-mediated radical coupling reactions. rac-2-Isopropyl-2,3-dimethyl-1-oxy-2,3-dihydro-imidazol-4-one was found to be the most efficient nitrone. The specific polystyrene macroradical addition rate to this nitrone was determined to be 8.0 x 10(3) L mol(-1) s(-1), which is by a factor of 10 higher than for previously studied compounds. Via enhanced spin-capturing polymerization, polymers in the range of oligomers to 30000 g mol(-1) were obtained. A strong dependence of molecular weight on monomer conversion was observed, which can be explained by the high trapping rate. In nitrone-mediated radical coupling, almost ideal coupling of bromine-functional polymers was obtained and the successful introduction of the residual alkoxyamine functionality confirmed.-
dc.language.isoen-
dc.publisherCSIRO PUBLISHING-
dc.subject.otherChemistry, Multidisciplinary-
dc.titleEnhanced Spin-capturing Polymerization and Radical Coupling Mediated by Cyclic Nitrones-
dc.typeJournal Contribution-
dc.identifier.epage1116-
dc.identifier.issue8-
dc.identifier.spage1110-
dc.identifier.volume65-
local.format.pages7-
local.bibliographicCitation.jcatA1-
dc.description.notes[Barner-Kowollik, Christopher] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. [Ranieri, Kayte; Conradi, Matthias; Junkers, Thomas] Univ Hasselt, Inst Mat Res, Polymer React Design Grp, BE-3590 Diepenbeek, Belgium. [Chavant, Pierre-Yves; Blandin, Veronique] Univ Grenoble 1, Dept Chim Mol, UMR 5250, ICMG,CNRS,FR 2607, F-38041 Grenoble 9, France.-
local.publisher.placeCOLLINGWOOD-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1071/CH12182-
dc.identifier.isi000308500300010-
item.fullcitationRANIERI, Kayte; CONRADI, Matthias Horst; Chavant, Pierre-Yves; Blandin, Veronique; Barner-Kowollik, Christopher & JUNKERS, Tanja (2012) Enhanced Spin-capturing Polymerization and Radical Coupling Mediated by Cyclic Nitrones. In: AUSTRALIAN JOURNAL OF CHEMISTRY, 65 (8), p. 1110-1116.-
item.accessRightsClosed Access-
item.contributorRANIERI, Kayte-
item.contributorCONRADI, Matthias Horst-
item.contributorChavant, Pierre-Yves-
item.contributorBlandin, Veronique-
item.contributorBarner-Kowollik, Christopher-
item.contributorJUNKERS, Tanja-
item.fulltextNo Fulltext-
item.validationecoom 2013-
crisitem.journal.issn0004-9425-
crisitem.journal.eissn1445-0038-
Appears in Collections:Research publications
Show simple item record

SCOPUSTM   
Citations

12
checked on Sep 4, 2020

WEB OF SCIENCETM
Citations

15
checked on Apr 14, 2024

Page view(s)

76
checked on Sep 7, 2022

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.