Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/14251
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dc.contributor.authorRANIERI, Kayte-
dc.contributor.authorCONRADI, Matthias Horst-
dc.contributor.authorChavant, Pierre-Yves-
dc.contributor.authorBlandin, Veronique-
dc.contributor.authorBarner-Kowollik, Christopher-
dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2012-10-12T09:46:14Z-
dc.date.available2012-10-12T09:46:14Z-
dc.date.issued2012-
dc.identifier.citationAUSTRALIAN JOURNAL OF CHEMISTRY, 65 (8), p. 1110-1116-
dc.identifier.issn0004-9425-
dc.identifier.urihttp://hdl.handle.net/1942/14251-
dc.description.abstractA series of cyclic nitrones have been tested for their spin-trapping activity in the enhanced spin-capturing polymerization of styrene and in nitrone-mediated radical coupling reactions. rac-2-Isopropyl-2,3-dimethyl-1-oxy-2,3-dihydro-imidazol-4-one was found to be the most efficient nitrone. The specific polystyrene macroradical addition rate to this nitrone was determined to be 8.0 x 10(3) L mol(-1) s(-1), which is by a factor of 10 higher than for previously studied compounds. Via enhanced spin-capturing polymerization, polymers in the range of oligomers to 30000 g mol(-1) were obtained. A strong dependence of molecular weight on monomer conversion was observed, which can be explained by the high trapping rate. In nitrone-mediated radical coupling, almost ideal coupling of bromine-functional polymers was obtained and the successful introduction of the residual alkoxyamine functionality confirmed.-
dc.language.isoen-
dc.publisherCSIRO PUBLISHING-
dc.subject.otherChemistry, Multidisciplinary-
dc.titleEnhanced Spin-capturing Polymerization and Radical Coupling Mediated by Cyclic Nitrones-
dc.typeJournal Contribution-
dc.identifier.epage1116-
dc.identifier.issue8-
dc.identifier.spage1110-
dc.identifier.volume65-
local.format.pages7-
local.bibliographicCitation.jcatA1-
dc.description.notes[Barner-Kowollik, Christopher] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. [Ranieri, Kayte; Conradi, Matthias; Junkers, Thomas] Univ Hasselt, Inst Mat Res, Polymer React Design Grp, BE-3590 Diepenbeek, Belgium. [Chavant, Pierre-Yves; Blandin, Veronique] Univ Grenoble 1, Dept Chim Mol, UMR 5250, ICMG,CNRS,FR 2607, F-38041 Grenoble 9, France.-
local.publisher.placeCOLLINGWOOD-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1071/CH12182-
dc.identifier.isi000308500300010-
item.fullcitationRANIERI, Kayte; CONRADI, Matthias Horst; Chavant, Pierre-Yves; Blandin, Veronique; Barner-Kowollik, Christopher & JUNKERS, Tanja (2012) Enhanced Spin-capturing Polymerization and Radical Coupling Mediated by Cyclic Nitrones. In: AUSTRALIAN JOURNAL OF CHEMISTRY, 65 (8), p. 1110-1116.-
item.fulltextNo Fulltext-
item.contributorRANIERI, Kayte-
item.contributorCONRADI, Matthias Horst-
item.contributorChavant, Pierre-Yves-
item.contributorBlandin, Veronique-
item.contributorBarner-Kowollik, Christopher-
item.contributorJUNKERS, Tanja-
item.validationecoom 2013-
item.accessRightsClosed Access-
crisitem.journal.issn0004-9425-
crisitem.journal.eissn1445-0038-
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