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http://hdl.handle.net/1942/14773
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DC Field | Value | Language |
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dc.contributor.author | MARIN, Lidia | - |
dc.contributor.author | Zhang, Yuexing | - |
dc.contributor.author | Robeyns, Koen | - |
dc.contributor.author | Champagne, Benoit | - |
dc.contributor.author | ADRIAENSENS, Peter | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | BEVK, David | - |
dc.contributor.author | MAES, Wouter | - |
dc.date.accessioned | 2013-03-22T08:55:22Z | - |
dc.date.available | 2013-03-22T08:55:22Z | - |
dc.date.issued | 2013 | - |
dc.identifier.citation | TETRAHEDRON LETTERS, 54 (6), p. 526-529 | - |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | http://hdl.handle.net/1942/14773 | - |
dc.description.abstract | In this Letter we report on the reaction of 4H-cyclopenta[2,1-b:3,4-b']dithiophen-4-one with various trivalent organophosphorus derivatives, with an emphasis on the final products depending on the applied reagents. No reaction occurred upon treatment with either triphenyl- or tricyclohexylphosphine, whereas addition of triethyl phosphite or tri(n-butyl)phosphine resulted in pinacol rearrangement. Structure elucidation of the isolated 5H-spiro(benzo[1,2-b:6,5-b']dithiophene-4,4'-cyclopenta[2,1-6:3,4-b']dithiophen)-5-one was achieved by combined NMR experiments, theoretical chemical shift and geometry calculations, and single crystal X-ray analysis. (C) 2012 Elsevier Ltd. All rights reserved. | - |
dc.language.iso | en | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject.other | Chemistry, Organic | - |
dc.subject.other | 4H-Cyclopenta[2,1-b:3,4-b ']dithiophene; Pinacol rearrangement; Trivalent organophosphorus reagents; Chemical shift calculations; X-ray diffraction | - |
dc.title | Trivalent organophosphorus reagent induced pinacol rearrangement of 4H-cyclopenta[2,1-b:3,4-b ']dithiophen-4-one | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 529 | - |
dc.identifier.issue | 6 | - |
dc.identifier.spage | 526 | - |
dc.identifier.volume | 54 | - |
local.format.pages | 4 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Marin, Lidia; Adriaensens, Peter; Vanderzande, Dirk; Bevk, David; Maes, Wouter] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium. [Zhang, Yuexing; Champagne, Benoit] Univ Namur, Chim Theor Lab, B-5000 Namur, Belgium. [Robeyns, Koen] Catholic Univ Louvain, Inst Condensed Matter & Nanosci Mol Solids & Reac, B-1348 Louvain, Belgium. [Lutsen, Laurence; Vanderzande, Dirk; Bevk, David] IMEC, IMOMEC Ass Lab, B-3590 Diepenbeek, Belgium. | - |
local.publisher.place | OXFORD | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1016/j.tetlet.2012.11.068 | - |
dc.identifier.isi | 000314388300019 | - |
item.accessRights | Restricted Access | - |
item.fulltext | With Fulltext | - |
item.validation | ecoom 2014 | - |
item.contributor | MARIN, Lidia | - |
item.contributor | Zhang, Yuexing | - |
item.contributor | Robeyns, Koen | - |
item.contributor | Champagne, Benoit | - |
item.contributor | ADRIAENSENS, Peter | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | BEVK, David | - |
item.contributor | MAES, Wouter | - |
item.fullcitation | MARIN, Lidia; Zhang, Yuexing; Robeyns, Koen; Champagne, Benoit; ADRIAENSENS, Peter; LUTSEN, Laurence; VANDERZANDE, Dirk; BEVK, David & MAES, Wouter (2013) Trivalent organophosphorus reagent induced pinacol rearrangement of 4H-cyclopenta[2,1-b:3,4-b ']dithiophen-4-one. In: TETRAHEDRON LETTERS, 54 (6), p. 526-529. | - |
crisitem.journal.issn | 0040-4039 | - |
crisitem.journal.eissn | 1873-3581 | - |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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trivalent organophosphorus.pdf Restricted Access | 495.13 kB | Adobe PDF | View/Open Request a copy |
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