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http://hdl.handle.net/1942/15079
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DC Field | Value | Language |
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dc.contributor.author | Bennet, Francesca | - |
dc.contributor.author | Roelle, Thomas | - |
dc.contributor.author | Faecke, Thomas | - |
dc.contributor.author | Weiser, Marc-Stephan | - |
dc.contributor.author | Bruder, Friedrich-Karl | - |
dc.contributor.author | Barner-Kowollik, Christopher | - |
dc.contributor.author | JUNKERS, Tanja | - |
dc.date.accessioned | 2013-04-18T09:41:48Z | - |
dc.date.available | 2013-04-18T09:41:48Z | - |
dc.date.issued | 2013 | - |
dc.identifier.citation | MACROMOLECULAR CHEMISTRY AND PHYSICS, 214 (2), p. 236-245 | - |
dc.identifier.issn | 1022-1352 | - |
dc.identifier.uri | http://hdl.handle.net/1942/15079 | - |
dc.description.abstract | The transfer reactions occurring during polymerization of 2-(phenylcarbamoyloxy)ethyl acrylate (PhCEA) were studied by a detailed product mapping with electrospray ionization mass spectrometry (ESI-MS). Unlike postulated before, PhCEA exhibits the same characteristic transfer reactions as other acrylic monomers at elevated temperatures, resulting in vinyl-terminated and saturated products. Transfer to monomer via abstraction of a hydrogen atom from the ester side chain as suggested before is not observed. When polymerized in a poly(ethylene glycol) (PEG) matrix to increase viscosity, transfer into matrix products are observed in minor amounts, demonstrating that PEG can be employed as a solvent to further increase the overall rate of polymerization without interference from side reactions. | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject.other | acrylate polymerization; electrospray ionization mass spectrometry; transfer to polymer | - |
dc.subject.other | Polymer Science; acrylate polymerization; electrospray ionization mass spectrometry; transfer to polymer | - |
dc.title | Transfer Reactions in Phenyl Carbamate Ethyl Acrylate Polymerizations | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 245 | - |
dc.identifier.issue | 2 | - |
dc.identifier.spage | 236 | - |
dc.identifier.volume | 214 | - |
local.format.pages | 10 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Bennet, Francesca; Barner-Kowollik, Christopher; Junkers, Thomas] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. [Roelle, Thomas; Faecke, Thomas; Weiser, Marc-Stephan; Bruder, Friedrich-Karl] Bayer Mat Sci AG, Leverkusen, Germany. [Junkers, Thomas] Univ Hasselt, Polymer React Design Grp, Inst Mat Res, B-3590 Diepenbeek, Belgium. | - |
local.publisher.place | WEINHEIM | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1002/macp.201200285 | - |
dc.identifier.isi | 000313726500012 | - |
item.accessRights | Restricted Access | - |
item.validation | ecoom 2014 | - |
item.contributor | Bennet, Francesca | - |
item.contributor | Roelle, Thomas | - |
item.contributor | Faecke, Thomas | - |
item.contributor | Weiser, Marc-Stephan | - |
item.contributor | Bruder, Friedrich-Karl | - |
item.contributor | Barner-Kowollik, Christopher | - |
item.contributor | JUNKERS, Tanja | - |
item.fulltext | With Fulltext | - |
item.fullcitation | Bennet, Francesca; Roelle, Thomas; Faecke, Thomas; Weiser, Marc-Stephan; Bruder, Friedrich-Karl; Barner-Kowollik, Christopher & JUNKERS, Tanja (2013) Transfer Reactions in Phenyl Carbamate Ethyl Acrylate Polymerizations. In: MACROMOLECULAR CHEMISTRY AND PHYSICS, 214 (2), p. 236-245. | - |
crisitem.journal.issn | 1022-1352 | - |
crisitem.journal.eissn | 1521-3935 | - |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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transfer reactions.pdf Restricted Access | 739.43 kB | Adobe PDF | View/Open Request a copy |
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