Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/15079
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dc.contributor.authorBennet, Francesca-
dc.contributor.authorRoelle, Thomas-
dc.contributor.authorFaecke, Thomas-
dc.contributor.authorWeiser, Marc-Stephan-
dc.contributor.authorBruder, Friedrich-Karl-
dc.contributor.authorBarner-Kowollik, Christopher-
dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2013-04-18T09:41:48Z-
dc.date.available2013-04-18T09:41:48Z-
dc.date.issued2013-
dc.identifier.citationMACROMOLECULAR CHEMISTRY AND PHYSICS, 214 (2), p. 236-245-
dc.identifier.issn1022-1352-
dc.identifier.urihttp://hdl.handle.net/1942/15079-
dc.description.abstractThe transfer reactions occurring during polymerization of 2-(phenylcarbamoyloxy)ethyl acrylate (PhCEA) were studied by a detailed product mapping with electrospray ionization mass spectrometry (ESI-MS). Unlike postulated before, PhCEA exhibits the same characteristic transfer reactions as other acrylic monomers at elevated temperatures, resulting in vinyl-terminated and saturated products. Transfer to monomer via abstraction of a hydrogen atom from the ester side chain as suggested before is not observed. When polymerized in a poly(ethylene glycol) (PEG) matrix to increase viscosity, transfer into matrix products are observed in minor amounts, demonstrating that PEG can be employed as a solvent to further increase the overall rate of polymerization without interference from side reactions.-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subject.otheracrylate polymerization; electrospray ionization mass spectrometry; transfer to polymer-
dc.subject.otherPolymer Science; acrylate polymerization; electrospray ionization mass spectrometry; transfer to polymer-
dc.titleTransfer Reactions in Phenyl Carbamate Ethyl Acrylate Polymerizations-
dc.typeJournal Contribution-
dc.identifier.epage245-
dc.identifier.issue2-
dc.identifier.spage236-
dc.identifier.volume214-
local.format.pages10-
local.bibliographicCitation.jcatA1-
dc.description.notes[Bennet, Francesca; Barner-Kowollik, Christopher; Junkers, Thomas] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany. [Roelle, Thomas; Faecke, Thomas; Weiser, Marc-Stephan; Bruder, Friedrich-Karl] Bayer Mat Sci AG, Leverkusen, Germany. [Junkers, Thomas] Univ Hasselt, Polymer React Design Grp, Inst Mat Res, B-3590 Diepenbeek, Belgium.-
local.publisher.placeWEINHEIM-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1002/macp.201200285-
dc.identifier.isi000313726500012-
item.contributorBennet, Francesca-
item.contributorRoelle, Thomas-
item.contributorFaecke, Thomas-
item.contributorWeiser, Marc-Stephan-
item.contributorBruder, Friedrich-Karl-
item.contributorBarner-Kowollik, Christopher-
item.contributorJUNKERS, Tanja-
item.accessRightsRestricted Access-
item.fullcitationBennet, Francesca; Roelle, Thomas; Faecke, Thomas; Weiser, Marc-Stephan; Bruder, Friedrich-Karl; Barner-Kowollik, Christopher & JUNKERS, Tanja (2013) Transfer Reactions in Phenyl Carbamate Ethyl Acrylate Polymerizations. In: MACROMOLECULAR CHEMISTRY AND PHYSICS, 214 (2), p. 236-245.-
item.fulltextWith Fulltext-
item.validationecoom 2014-
crisitem.journal.issn1022-1352-
crisitem.journal.eissn1521-3935-
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