Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/16728
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dc.contributor.authorKUDRET, Suleyman-
dc.contributor.authorKESTERS, Jurgen-
dc.contributor.authorJanssen, Sander-
dc.contributor.authorVan den Brande, Niko-
dc.contributor.authorDefour, Maxime-
dc.contributor.authorVan Mele, Bruno-
dc.contributor.authorMANCA, Jean-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorMAES, Wouter-
dc.date.accessioned2014-04-29T12:00:25Z-
dc.date.available2014-04-29T12:00:25Z-
dc.date.issued2014-
dc.identifier.citationREACTIVE & FUNCTIONAL POLYMERS, 75, p. 22-30-
dc.identifier.issn1381-5148-
dc.identifier.urihttp://hdl.handle.net/1942/16728-
dc.description.abstractAn optimized synthetic protocol toward highly reactive Rieke zinc is applied for the preparation of a series of x-(2,5-dibromothiophene-3-yl)alkyl acetate monomers and statistical copolythiophenes derived thereof, with 10% of ester-functionalized side chains. The obtained conjugated polymers are attractive electron donor materials for organic solar cells, notably to increase the thermodynamic stability of the bulk heterojunction polymer:fullerene active layer blend, and are fully characterized by a combination of spectroscopic, thermal analysis and electrochemical techniques.-
dc.description.sponsorshipWe thank IMEC and Hasselt University for providing the PhD grant of S.K. We acknowledge the OPV-Life project from the IWT (Agentschap voor Innovate door Wetenschap en Technologie; O&O 080368), the POLYSTAR project from PV ERA-NET, the IWT-SBO project POLYSPEC (Nanostructured POLYmer photovoltaic devices for efficient solar SPECtrum harvesting), and Belspo for supporting the IAP P6/27 and IAP 7/05 networks. We are also thankful to Huguette Penxten for the UV-Vis and CV measurements.-
dc.language.isoen-
dc.rights© 2013 Elsevier Ltd. All rights reserved.-
dc.subject.otherRieke zinc; optimized synthetic protocol; Ester side chains; random copolythiophenes; organic photovoltaics-
dc.titleFacile synthesis of 3-(omega-acetoxyalkyl)thiophenes and derived copolythiophenes using Rieke zinc-
dc.typeJournal Contribution-
dc.identifier.epage30-
dc.identifier.spage22-
dc.identifier.volume75-
local.bibliographicCitation.jcatA1-
dc.description.notesMaes, W (reprint author), Hasselt Univ, Inst Mat Res IMO IMOMEC, Agoralaan 1,Bldg D, B-3590 Diepenbeek, Belgium wouter.maes@uhasselt.be-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1016/j.reactfunctpolym.2013.11.009-
dc.identifier.isi000330918200004-
item.fulltextWith Fulltext-
item.accessRightsRestricted Access-
item.contributorMANCA, Jean-
item.contributorVan Mele, Bruno-
item.contributorVan den Brande, Niko-
item.contributorLUTSEN, Laurence-
item.contributorJanssen, Sander-
item.contributorVANDERZANDE, Dirk-
item.contributorDefour, Maxime-
item.contributorKESTERS, Jurgen-
item.contributorMAES, Wouter-
item.contributorKUDRET, Suleyman-
item.fullcitationKUDRET, Suleyman; KESTERS, Jurgen; Janssen, Sander; Van den Brande, Niko; Defour, Maxime; Van Mele, Bruno; MANCA, Jean; LUTSEN, Laurence; VANDERZANDE, Dirk & MAES, Wouter (2014) Facile synthesis of 3-(omega-acetoxyalkyl)thiophenes and derived copolythiophenes using Rieke zinc. In: REACTIVE & FUNCTIONAL POLYMERS, 75, p. 22-30.-
item.validationecoom 2015-
crisitem.journal.issn1381-5148-
crisitem.journal.eissn1873-166X-
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