Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/16870
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dc.contributor.authorGHOOS, Toon-
dc.contributor.authorVan den Brande, Niko-
dc.contributor.authorDefour, Maxime-
dc.contributor.authorBrassinne, Jérémy-
dc.contributor.authorFustin, Charles-André-
dc.contributor.authorGohy, Jean-Francois-
dc.contributor.authorHoeppener, Stephanie-
dc.contributor.authorSchubert, Ulrich S.-
dc.contributor.authorVANORMELINGEN, Wouter-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorVan Mele, Bruno-
dc.contributor.authorMAES, Wouter-
dc.date.accessioned2014-06-03T13:12:59Z-
dc.date.available2014-06-03T13:12:59Z-
dc.date.issued2014-
dc.identifier.citationEUROPEAN POLYMER JOURNAL, 53, p. 206-214-
dc.identifier.issn0014-3057-
dc.identifier.urihttp://hdl.handle.net/1942/16870-
dc.description.abstractAmphiphilic diblock copolythiophenes are synthesized by an efficient two-step synthetic strategy. The block architecture is created via the quasi-living Grignard metathesis reaction, after which ionic imidazolium moieties are introduced by substitution on the bromohexyl side chains of one of the monomer constituents. The compositional influence on the solution behavior and thermal properties of both the precursor and ionic block copolythiophenes is investigated. The novel materials are of particular appeal for integration in organic solar cell stacks, either as active layer or interlayer materials.-
dc.description.sponsorshipThe authors acknowledge BELSPO for supporting the IAP P6/27 and IAP P7/05 networks. The reported activity is partly supported by the European Community FP7 - Large-scale integrating project ORION (Ordered Inorganic-Organic Hybrids Using Ionic Liquids For Emerging Applications, Contract No. CP-IP 229036-2) and by the project ORGANEXT (EMR. INT4-1.2.-2009-04/054), selected in the frame of the operational program INTERREG IV-A Euregio Maas-Rijn. CAF is a Research Associate of the FRS-FNRS. JB thanks FRIA for financial support.-
dc.language.isoen-
dc.rights© 2014 Elsevier Ltd. All rights reserved.-
dc.subject.otherdiblock copolymers; ionic polythiophenes; solution properties; dynamic light scattering; thermal properties; organic photovoltaics-
dc.titleAmphiphilic N-methylimidazole-functionalized diblock copolythiophenes-
dc.typeJournal Contribution-
dc.identifier.epage214-
dc.identifier.spage206-
dc.identifier.volume53-
local.bibliographicCitation.jcatA1-
dc.description.notesMaes, W (reprint author), Hasselt Univ, Inst Mat Res IMO IMOMEC, Agoralaan 1 Bldg D, B-3590 Diepenbeek, Belgium. wouter.maes@uhasselt.be-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1016/j.eurpolymj.2014.01.028-
dc.identifier.isi000334481300019-
item.accessRightsRestricted Access-
item.fullcitationGHOOS, Toon; Van den Brande, Niko; Defour, Maxime; Brassinne, Jérémy; Fustin, Charles-André; Gohy, Jean-Francois; Hoeppener, Stephanie; Schubert, Ulrich S.; VANORMELINGEN, Wouter; LUTSEN, Laurence; VANDERZANDE, Dirk; Van Mele, Bruno & MAES, Wouter (2014) Amphiphilic N-methylimidazole-functionalized diblock copolythiophenes. In: EUROPEAN POLYMER JOURNAL, 53, p. 206-214.-
item.validationecoom 2015-
item.fulltextWith Fulltext-
item.contributorGHOOS, Toon-
item.contributorVan den Brande, Niko-
item.contributorDefour, Maxime-
item.contributorBrassinne, Jérémy-
item.contributorFustin, Charles-André-
item.contributorGohy, Jean-Francois-
item.contributorHoeppener, Stephanie-
item.contributorSchubert, Ulrich S.-
item.contributorVANORMELINGEN, Wouter-
item.contributorLUTSEN, Laurence-
item.contributorVANDERZANDE, Dirk-
item.contributorVan Mele, Bruno-
item.contributorMAES, Wouter-
crisitem.journal.issn0014-3057-
crisitem.journal.eissn1873-1945-
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