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http://hdl.handle.net/1942/17178
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DC Field | Value | Language |
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dc.contributor.author | YEAP, Weng Siang | - |
dc.contributor.author | MURIB, Mohammed Sharif | - |
dc.contributor.author | Cuypers, Wim | - |
dc.contributor.author | Liu, Xianjie | - |
dc.contributor.author | VAN GRINSVEN, Bart | - |
dc.contributor.author | AMELOOT, Marcel | - |
dc.contributor.author | Fahlman, Mats | - |
dc.contributor.author | WAGNER, Patrick | - |
dc.contributor.author | MAES, Wouter | - |
dc.contributor.author | HAENEN, Ken | - |
dc.date.accessioned | 2014-09-25T08:06:01Z | - |
dc.date.available | 2014-09-25T08:06:01Z | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | CHEMELECTROCHEM, 1 (7), p. 1145-1154 | - |
dc.identifier.issn | 2196-0216 | - |
dc.identifier.uri | http://hdl.handle.net/1942/17178 | - |
dc.description.abstract | A straightforward protocol for the covalent functionalization of boron-doped diamond electrodes with either ferrocene or single-stranded deoxyribonucleic acid (DNA) is reported. The functionalization method is based on a combination of diazonium salt electrografting and click chemistry. An azide-terminated organic layer is first electrografted onto the diamond surface by electrochemical reduction of 4-azidophenyldiazonium chloride. The azidophenyl-modified surface then reacts rapidly and efficiently with molecules bearing a terminal alkyne moiety by means of Cu-1-catalyzed alkyne-azide cycloaddition. Covalent attachment of ferrocene moieties was analyzed by X-ray photoelectron spectroscopy and cyclic voltammetry, whereas impedance spectroscopy was applied for the characterization of the immobilized DNA. | - |
dc.description.sponsorship | This work was financially supported by the Special Research Fund of Hasselt University, the Research Foundation Flanders (FWO) (G.0555.10N and G.0829.09N), and the EU FP7 Collaborative Project MOLESOL (No. 256617). We thank H. Penxten for the CV measurements, B. Ruttens for the SEM images, and P. Robaeys for the four-point probe measurements. | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.rights | © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.subject.other | azides; boron-doped diamond; click chemistry; diazonium electrografting; DNA | - |
dc.subject.other | azides; boron-doped diamond; click chemistry; diazonium electrografting; DNA | - |
dc.title | Boron-Doped Diamond Functionalization by an Electrografting/Alkyne-Azide Click Chemistry Sequence | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 1154 | - |
dc.identifier.issue | 7 | - |
dc.identifier.spage | 1145 | - |
dc.identifier.volume | 1 | - |
local.format.pages | 10 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Yeap, Weng Siang; Murib, Mohammed Sharif; Cuypers, Wim; van Grinsven, Bart; Wagner, Patrick; Maes, Wouter; Haenen, Ken] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium. [Liu, Xianjie; Fahlman, Mats] Linkoping Univ, Dept Phys Chem & Biol, S-58183 Linkoping, Sweden. [van Grinsven, Bart] Maastricht Univ, Maastricht Sci Programme, NL-6200 MD Maastricht, Netherlands. [Ameloot, Marcel] Hasselt Univ, Biomed Res Inst BIOMED, B-3590 Diepenbeek, Belgium. [Wagner, Patrick; Maes, Wouter; Haenen, Ken] IMEC VZW, IMOMEC, B-3590 Diepenbeek, Belgium. wengsiang.yeap@uhasselt.be; ken.haenen@uhasselt.be | - |
local.publisher.place | WEINHEIM | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1002/celc.201402068 | - |
dc.identifier.isi | 000340523000007 | - |
item.validation | ecoom 2015 | - |
item.contributor | YEAP, Weng Siang | - |
item.contributor | MURIB, Mohammed Sharif | - |
item.contributor | Cuypers, Wim | - |
item.contributor | Liu, Xianjie | - |
item.contributor | VAN GRINSVEN, Bart | - |
item.contributor | AMELOOT, Marcel | - |
item.contributor | Fahlman, Mats | - |
item.contributor | WAGNER, Patrick | - |
item.contributor | MAES, Wouter | - |
item.contributor | HAENEN, Ken | - |
item.accessRights | Open Access | - |
item.fullcitation | YEAP, Weng Siang; MURIB, Mohammed Sharif; Cuypers, Wim; Liu, Xianjie; VAN GRINSVEN, Bart; AMELOOT, Marcel; Fahlman, Mats; WAGNER, Patrick; MAES, Wouter & HAENEN, Ken (2014) Boron-Doped Diamond Functionalization by an Electrografting/Alkyne-Azide Click Chemistry Sequence. In: CHEMELECTROCHEM, 1 (7), p. 1145-1154. | - |
item.fulltext | With Fulltext | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Accepted_Complete manuscript Yeap et al _revision.pdf | 1.61 MB | Adobe PDF | View/Open | |
yeapws_chemelectrochem_ClickDiamondDNA.pdf Restricted Access | 1.66 MB | Adobe PDF | View/Open Request a copy |
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