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http://hdl.handle.net/1942/17231
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DC Field | Value | Language |
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dc.contributor.author | CONRADI, Matthias Horst | - |
dc.contributor.author | JUNKERS, Tanja | - |
dc.date.accessioned | 2014-10-08T08:06:24Z | - |
dc.date.available | 2014-10-08T08:06:24Z | - |
dc.date.issued | 2013 | - |
dc.identifier.citation | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 259, p. 41-46 | - |
dc.identifier.issn | 1010-6030 | - |
dc.identifier.uri | http://hdl.handle.net/1942/17231 | - |
dc.description.abstract | The [2 + 2] photocycloaddition between maleimide and various alkenes was optimized in a simple custom-made UV flow reactor. While complete maleimide conversion is only achieved with excesses of at least 10 eq. of alkene and reaction times of 12-24 h in batch, complete reactions with yields in the range >98% could be obtained in 5 min in the flow reactor under strictly equimolar conditions. Functional alkenes carrying allyl, alcohol, amine and ether moieties were successfully conjugated in good yields under optimized reaction conditions. As is demonstrated, the reaction gains in flow most characteristics of a high-efficient reaction, making the process highly valuable for upscaled synthesis of maleimide conjugates. (C) 2013 Elsevier B.V. All rights reserved. | - |
dc.description.sponsorship | UHasselt doctoral funds | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.rights | © 2013 Elsevier B.V. All rights reserved. | - |
dc.subject.other | [2 + 2]-cycloaddition; photochemistry; flow chemistry; functional group tolerance; photo-conjugation | - |
dc.subject.other | [2+2]-Cycloaddition; Photochemistry; Flow chemistry; Functional group tolerance; photo-conjugation | - |
dc.title | Efficient [2+2] photocycloadditions under equimolar conditions by employing a continuous UV-flow reactor | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 46 | - |
dc.identifier.spage | 41 | - |
dc.identifier.volume | 259 | - |
local.format.pages | 6 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Conradi, Matthias; Junkers, Thomas] Univ Hassel, Inst Mat Res, Polymer React Design Grp, IMO, B-3590 Diepenbeek, Belgium. | - |
local.publisher.place | LAUSANNE | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1016/j.jphotochem.2013.02.024 | - |
dc.identifier.isi | 000319089900006 | - |
item.fulltext | With Fulltext | - |
item.fullcitation | CONRADI, Matthias Horst & JUNKERS, Tanja (2013) Efficient [2+2] photocycloadditions under equimolar conditions by employing a continuous UV-flow reactor. In: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 259, p. 41-46. | - |
item.contributor | CONRADI, Matthias Horst | - |
item.contributor | JUNKERS, Tanja | - |
item.validation | ecoom 2014 | - |
item.accessRights | Restricted Access | - |
crisitem.journal.issn | 1010-6030 | - |
crisitem.journal.eissn | 1873-2666 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
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junkers.pdf Restricted Access | 380.37 kB | Adobe PDF | View/Open Request a copy |
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