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http://hdl.handle.net/1942/17740
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DC Field | Value | Language |
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dc.contributor.author | YEAP, Weng Siang | - |
dc.contributor.author | BEVK, David | - |
dc.contributor.author | Liu, X. | - |
dc.contributor.author | Krysova, H. | - |
dc.contributor.author | Pasquarelli, A. | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | Kavan, L. | - |
dc.contributor.author | Fahlman, M. | - |
dc.contributor.author | MAES, Wouter | - |
dc.contributor.author | HAENEN, Ken | - |
dc.date.accessioned | 2014-11-05T08:33:16Z | - |
dc.date.available | 2014-11-05T08:33:16Z | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | RSC ADVANCES, 4 (79), p. 42044-42053 | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | http://hdl.handle.net/1942/17740 | - |
dc.description.abstract | Donor-acceptor type light-harvesting molecular wires are covalently attached to a boron-doped diamond surface via a combination of diazonium electrografting and Suzuki cross-coupling. For the Suzuki reaction, various catalytic systems are compared with respect to their imposed surface coverage. Combining 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl (SPhos) and Pd(0), the diamond coverage improves considerably (by 98%) as compared to the standard tetrakis(triphenylphosphine)palladium(0) (Pd(PPh3)(4)) catalyst. As the energy levels between the molecular chromophores and the diamond film align well, the sophisticated functionalized diamond surfaces present a first step towards the development of fully carbon-based devices for light to electricity conversion. | - |
dc.description.sponsorship | Special Research Fund of Hasselt University; Research Foundation Flanders (FWO) [G.0555.10N]; EU FP7 Collaborative Project "MOLESOL" [256617]; Swedish Research Council Linnaeus grant; Grant Agency of the Czech Republic [13-37383S] | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.rights | This journal is © The Royal Society of Chemistry 2014. | - |
dc.subject.other | Chemistry, Multidisciplinary | - |
dc.title | Diamond functionalization with light-harvesting molecular wires: improved surface coverage by optimized Suzuki cross-coupling conditions | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 42053 | - |
dc.identifier.issue | 79 | - |
dc.identifier.spage | 42044 | - |
dc.identifier.volume | 4 | - |
local.format.pages | 10 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Yeap, W. S.; Bevk, D.; Vanderzande, D.; Lutsen, L.; Maes, W.; Haenen, K.] Hasselt Univ, IMO, B-3590 Diepenbeek, Belgium. [Bevk, D.; Vanderzande, D.; Lutsen, L.; Maes, W.; Haenen, K.] IMEC VZW, IMOMEC, B-3590 Diepenbeek, Belgium. [Liu, X.; Fahlman, M.] Linkoping Univ, Dept Phys Chem & Biol, S-58183 Linkoping, Sweden. [Krysova, H.; Kavan, L.] Acad Sci Czech Republic, J Heyrovsk Inst Phys Chem, Vvi, CZ-18223 Prague 8, Czech Republic. [Pasquarelli, A.] Univ Ulm, Inst Electron Devices & Circuits, D-89069 Ulm, Germany. | - |
local.publisher.place | CAMBRIDGE | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1039/c4ra04740k | - |
dc.identifier.isi | 000342161600047 | - |
item.validation | ecoom 2015 | - |
item.fulltext | With Fulltext | - |
item.accessRights | Restricted Access | - |
item.fullcitation | YEAP, Weng Siang; BEVK, David; Liu, X.; Krysova, H.; Pasquarelli, A.; VANDERZANDE, Dirk; LUTSEN, Laurence; Kavan, L.; Fahlman, M.; MAES, Wouter & HAENEN, Ken (2014) Diamond functionalization with light-harvesting molecular wires: improved surface coverage by optimized Suzuki cross-coupling conditions. In: RSC ADVANCES, 4 (79), p. 42044-42053. | - |
item.contributor | YEAP, Weng Siang | - |
item.contributor | BEVK, David | - |
item.contributor | Liu, X. | - |
item.contributor | Krysova, H. | - |
item.contributor | Pasquarelli, A. | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | Kavan, L. | - |
item.contributor | Fahlman, M. | - |
item.contributor | MAES, Wouter | - |
item.contributor | HAENEN, Ken | - |
crisitem.journal.eissn | 2046-2069 | - |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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c4ra04740k.pdf Restricted Access | 1.25 MB | Adobe PDF | View/Open Request a copy |
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