Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/17740
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dc.contributor.authorYEAP, Weng Siang-
dc.contributor.authorBEVK, David-
dc.contributor.authorLiu, X.-
dc.contributor.authorKrysova, H.-
dc.contributor.authorPasquarelli, A.-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorKavan, L.-
dc.contributor.authorFahlman, M.-
dc.contributor.authorMAES, Wouter-
dc.contributor.authorHAENEN, Ken-
dc.date.accessioned2014-11-05T08:33:16Z-
dc.date.available2014-11-05T08:33:16Z-
dc.date.issued2014-
dc.identifier.citationRSC ADVANCES, 4 (79), p. 42044-42053-
dc.identifier.issn2046-2069-
dc.identifier.urihttp://hdl.handle.net/1942/17740-
dc.description.abstractDonor-acceptor type light-harvesting molecular wires are covalently attached to a boron-doped diamond surface via a combination of diazonium electrografting and Suzuki cross-coupling. For the Suzuki reaction, various catalytic systems are compared with respect to their imposed surface coverage. Combining 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl (SPhos) and Pd(0), the diamond coverage improves considerably (by 98%) as compared to the standard tetrakis(triphenylphosphine)palladium(0) (Pd(PPh3)(4)) catalyst. As the energy levels between the molecular chromophores and the diamond film align well, the sophisticated functionalized diamond surfaces present a first step towards the development of fully carbon-based devices for light to electricity conversion.-
dc.description.sponsorshipSpecial Research Fund of Hasselt University; Research Foundation Flanders (FWO) [G.0555.10N]; EU FP7 Collaborative Project "MOLESOL" [256617]; Swedish Research Council Linnaeus grant; Grant Agency of the Czech Republic [13-37383S]-
dc.language.isoen-
dc.publisherROYAL SOC CHEMISTRY-
dc.rightsThis journal is © The Royal Society of Chemistry 2014.-
dc.subject.otherChemistry, Multidisciplinary-
dc.titleDiamond functionalization with light-harvesting molecular wires: improved surface coverage by optimized Suzuki cross-coupling conditions-
dc.typeJournal Contribution-
dc.identifier.epage42053-
dc.identifier.issue79-
dc.identifier.spage42044-
dc.identifier.volume4-
local.format.pages10-
local.bibliographicCitation.jcatA1-
dc.description.notes[Yeap, W. S.; Bevk, D.; Vanderzande, D.; Lutsen, L.; Maes, W.; Haenen, K.] Hasselt Univ, IMO, B-3590 Diepenbeek, Belgium. [Bevk, D.; Vanderzande, D.; Lutsen, L.; Maes, W.; Haenen, K.] IMEC VZW, IMOMEC, B-3590 Diepenbeek, Belgium. [Liu, X.; Fahlman, M.] Linkoping Univ, Dept Phys Chem & Biol, S-58183 Linkoping, Sweden. [Krysova, H.; Kavan, L.] Acad Sci Czech Republic, J Heyrovsk Inst Phys Chem, Vvi, CZ-18223 Prague 8, Czech Republic. [Pasquarelli, A.] Univ Ulm, Inst Electron Devices & Circuits, D-89069 Ulm, Germany.-
local.publisher.placeCAMBRIDGE-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1039/c4ra04740k-
dc.identifier.isi000342161600047-
item.validationecoom 2015-
item.contributorYEAP, Weng Siang-
item.contributorBEVK, David-
item.contributorLiu, X.-
item.contributorKrysova, H.-
item.contributorPasquarelli, A.-
item.contributorVANDERZANDE, Dirk-
item.contributorLUTSEN, Laurence-
item.contributorKavan, L.-
item.contributorFahlman, M.-
item.contributorMAES, Wouter-
item.contributorHAENEN, Ken-
item.fullcitationYEAP, Weng Siang; BEVK, David; Liu, X.; Krysova, H.; Pasquarelli, A.; VANDERZANDE, Dirk; LUTSEN, Laurence; Kavan, L.; Fahlman, M.; MAES, Wouter & HAENEN, Ken (2014) Diamond functionalization with light-harvesting molecular wires: improved surface coverage by optimized Suzuki cross-coupling conditions. In: RSC ADVANCES, 4 (79), p. 42044-42053.-
item.fulltextWith Fulltext-
item.accessRightsClosed Access-
crisitem.journal.eissn2046-2069-
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