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http://hdl.handle.net/1942/17758
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DC Field | Value | Language |
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dc.contributor.author | Ling, Yun | - |
dc.contributor.author | DILIEN, Hanne | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | ADRIAENSENS, Peter | - |
dc.contributor.author | VAN DOORSLAER, Sabine | - |
dc.date.accessioned | 2014-11-06T11:24:06Z | - |
dc.date.available | 2014-11-06T11:24:06Z | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | APPLIED MAGNETIC RESONANCE, 45 (9), p. 827-839 | - |
dc.identifier.issn | 0937-9347 | - |
dc.identifier.uri | http://hdl.handle.net/1942/17758 | - |
dc.description.abstract | Poly(3-octylthienylene vinylene) (O-PTV) has a great potential as low-bandgap p-type semiconductor for photovoltaic applications. Here, the positive radical state (positive polaron) is induced chemically in the O-PTV polymer in which the vinylene sites are selectively C-13-labeled. Using multi-frequency continuous wave and pulsed electron paramagnetic resonance, the g tensor and maximum H-1 and C-13 hyperfine couplings are determined. A comparative density functional theory (DFT) analysis of PTV-like oligomers is performed. The experimental parameters suggest a larger localization of the positive polaron than follows from the DFT analysis. The counter anion may play a crucial role in localizing the polaron. | - |
dc.description.sponsorship | University of Antwerp; scientific research community project MULTIMAR (Multidisciplinary Magnetic Resonance) of the Research Foundation Flanders (FWO-Vlaanderen); Hercules Foundation, Flanders [AUHA013] | - |
dc.language.iso | en | - |
dc.publisher | SPRINGER WIEN | - |
dc.rights | © Springer-Verlag Wien 2014 | - |
dc.title | Electronic Structure of the Positive Radical of C-13-Labeled Poly(3-Octylthienylene Vinylene) Polymer | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 839 | - |
dc.identifier.issue | 9 | - |
dc.identifier.spage | 827 | - |
dc.identifier.volume | 45 | - |
local.format.pages | 13 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Ling, Yun; Van Doorslaer, Sabine] Univ Antwerp, BIMEF Lab, Dept Phys, B-2610 Antwerp, Belgium. [Dilien, Hanne; Vanderzande, Dirk; Adriaensens, Peter J.] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium. [Vanderzande, Dirk; Adriaensens, Peter J.] IMEC, IMOMEC Assoc Lab, B-3590 Diepenbeek, Belgium. | - |
local.publisher.place | WIEN | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1007/s00723-014-0561-3 | - |
dc.identifier.isi | 000342413100004 | - |
item.fulltext | With Fulltext | - |
item.accessRights | Restricted Access | - |
item.contributor | Ling, Yun | - |
item.contributor | DILIEN, Hanne | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | ADRIAENSENS, Peter | - |
item.contributor | VAN DOORSLAER, Sabine | - |
item.fullcitation | Ling, Yun; DILIEN, Hanne; VANDERZANDE, Dirk; ADRIAENSENS, Peter & VAN DOORSLAER, Sabine (2014) Electronic Structure of the Positive Radical of C-13-Labeled Poly(3-Octylthienylene Vinylene) Polymer. In: APPLIED MAGNETIC RESONANCE, 45 (9), p. 827-839. | - |
item.validation | ecoom 2015 | - |
crisitem.journal.issn | 0937-9347 | - |
crisitem.journal.eissn | 1613-7507 | - |
Appears in Collections: | Research publications |
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art%3A10.1007%2Fs00723-014-0561-3.pdf Restricted Access | 589.11 kB | Adobe PDF | View/Open Request a copy |
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