Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/17767
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dc.contributor.authorThomas, Joice-
dc.contributor.authorDobrzanska, Liliana-
dc.contributor.authorSonawane, Mahendra Punjaji-
dc.contributor.authorSmet, Mario-
dc.contributor.authorMAES, Wouter-
dc.contributor.authorDehaen, Wim-
dc.date.accessioned2014-11-06T15:03:36Z-
dc.date.available2014-11-06T15:03:36Z-
dc.date.issued2014-
dc.identifier.citationSUPRAMOLECULAR CHEMISTRY, 26 (7-8), p. 591-596-
dc.identifier.issn1061-0278-
dc.identifier.urihttp://hdl.handle.net/1942/17767-
dc.description.abstractSynthetic procedures towards homodithiacalix[n]arenes are developed, starting from simple and readily available bifunctional aryl building blocks, by a dynamic covalent chemistry approach. Reaction of 1,3-bis(mercaptomethyl)-5-tert-butyl-2-methoxybenzene under basic conditions leads to a mixture of trimeric, tetrameric and pentameric dimethylenedithia-bridged cyclooligomers, whereas reaction of 5-tert-butyl-2-methoxy-1,3-bis(thiocyanatomethyl) benzene under reducing conditions (and subsequent oxidation) affords the homodithiacalix[4]arene macrocycle in a very selective fashion through efficient disulphide exchange chemistry.-
dc.description.sponsorshipWe thank the FWO (Fund for Scientific Research Flanders), the KU Leuven and the Ministerie voor Wetenschapsbeleid for continuing financial support.-
dc.language.isoen-
dc.publisherTAYLOR & FRANCIS LTD-
dc.rights© 2014 Taylor & Francis.-
dc.subject.other(hetera)calixarenes; dimethylenedithia bridges; dynamic covalent chemistry; host–guest chemistry-
dc.subject.other(hetera)calixarenes; dimethylenedithia bridges; dynamic covalent chemistry; host-guest chemistry-
dc.titleSynthetic protocols towards homodithiacalix[n]arenes-
dc.typeJournal Contribution-
dc.identifier.epage596-
dc.identifier.issue7-8-
dc.identifier.spage591-
dc.identifier.volume26-
local.format.pages6-
local.bibliographicCitation.jcatA1-
dc.description.notes[Thomas, Joice; Dobrzanska, Liliana; Sonawane, Mahendra Punjaji; Smet, Mario; Dehaen, Wim] Katholieke Univ Leuven, Dept Chem, B-3001 Leuven, Belgium. [Maes, Wouter] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium.-
local.publisher.placeABINGDON-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1080/10610278.2013.875173-
dc.identifier.isi000337921500019-
item.fulltextWith Fulltext-
item.contributorThomas, Joice-
item.contributorDobrzanska, Liliana-
item.contributorSonawane, Mahendra Punjaji-
item.contributorSmet, Mario-
item.contributorMAES, Wouter-
item.contributorDehaen, Wim-
item.fullcitationThomas, Joice; Dobrzanska, Liliana; Sonawane, Mahendra Punjaji; Smet, Mario; MAES, Wouter & Dehaen, Wim (2014) Synthetic protocols towards homodithiacalix[n]arenes. In: SUPRAMOLECULAR CHEMISTRY, 26 (7-8), p. 591-596.-
item.accessRightsClosed Access-
item.validationecoom 2015-
crisitem.journal.issn1061-0278-
crisitem.journal.eissn1029-0478-
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