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Title: | One pot synthesis of higher order quasi-block copolymer libraries via sequential RAFT polymerization in an automated synthesizer | Authors: | HAVEN, Joris Guerrero-Sanchez, Carlos Keddie, Daniel J. Moad, Graeme Thang, San H. Schubert, Ulrich S. |
Issue Date: | 2014 | Publisher: | ROYAL SOC CHEMISTRY | Source: | Polymer Chemistry, 5 (18), p. 5236-5246 | Abstract: | Recently developed sequential reversible addition-fragmentation chain transfer (RAFT) polymerization protocols allow the rapid, fully unattended preparation of quasi-block copolymer libraries that cover a wide range of copolymer compositions in an automated synthesizer. This contribution explores the scope and limitations of this sequential approach for the synthesis of higher order quasi-multiblock copolymers (including copolymer sequences of BAB, CBABC, ABC and ABCD). These syntheses illustrate the utility of this high-throughput approach for the one pot synthesis of functional polymers of increased complexity. Additionally, the use of this experimental technique for method development is highlighted. | Notes: | [Haven, Joris J.; Guerrero-Sanchez, Carlos; Keddie, Daniel J.; Moad, Graeme; Thang, San H.] CSIRO, Clayton, Vic 3169, Australia. [Haven, Joris J.] Univ Hasselt, Inst Mat Res, Polymer React Design Grp, IMOMEC, B-3590 Diepenbeek, Belgium. [Guerrero-Sanchez, Carlos; Schubert, Ulrich S.] Univ Jena, Lab Organ & Macromol Chem IOMC, D-07743 Jena, Germany. [Guerrero-Sanchez, Carlos; Schubert, Ulrich S.] Univ Jena, JCSM, Polymer Libs, D-07743 Jena, Germany. [Keddie, Daniel J.] Univ New England, Chem Sch Sci & Technol, Armidale, NSW 2351, Australia. | Document URI: | http://hdl.handle.net/1942/17800 | ISSN: | 1759-9954 | e-ISSN: | 1759-9962 | DOI: | 10.1039/c4py00496e | ISI #: | 000340767100006 | Rights: | This journal is © The Royal Society of Chemistry 2014. | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2015 |
Appears in Collections: | Research publications |
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