Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/18692
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dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2015-04-13T13:57:36Z-
dc.date.available2015-04-13T13:57:36Z-
dc.date.issued2015-
dc.identifier.citationEUROPEAN POLYMER JOURNAL, 62, p. 273-280-
dc.identifier.issn0014-3057-
dc.identifier.urihttp://hdl.handle.net/1942/18692-
dc.description.abstractPhoto-induced reactions play an important role in precision polymer design. Photoreactions are often cost-effective reactions that proceed under relatively mild reaction conditions. Additionally, photo reactions add spatial and temporal control over reactions, which gives rise to a large number of applications that would otherwise be inaccessible. Among the various photochemistries available, [2+2] cycloadditions are a prominent example for effective conversions. In the field of polymer chemistry, such reactions are often used for crosslinking. If reaction conditions are chosen carefully, they can, however, also be employed for advanced polymer transformations, such as polymer endgroup modification or specific ligation to substrates. Especially when applying flow chemistry approaches, very high reaction efficiencies are gained, bringing [2+2] cycloadditions close in use to other well known click-like techniques such as thiol-ene chemistry. (C) 2014 Elsevier Ltd.-
dc.description.sponsorshipSupport from the European Science Foundation - "Precision Polymer Materials (P2M)" program as well as the Belgian Science Policy (Belspo) in the framework of the Interuniversity Attraction Poles Program TAP-PAI P7/05 "Functional Supramolecular Systems" is gratefully acknowledged.-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.rights© 2014 Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/3.0/).-
dc.subject.otherphotocycloaddition; [2+2]; polymer modification; surface modification; surface patterning-
dc.subject.otherPhotocycloaddition; [2+2]; Polymer modification; Surface modification; Surface patterning-
dc.title[2+2] Photo-cycloadditions for polymer modification and surface decoration-
dc.typeJournal Contribution-
dc.identifier.epage280-
dc.identifier.spage273-
dc.identifier.volume62-
local.format.pages8-
local.bibliographicCitation.jcatA1-
dc.description.notes[Junkers, Thomas] Hasselt Univ, Inst Mat Res, Polymer React Design Grp, B-3500 Hasselt, Belgium. [Junkers, Thomas] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium. thomas.junkers@uhasselt.be-
local.publisher.placeOXFORD-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1016/j.eurpolymj.2014.08.005-
dc.identifier.isi000348486200028-
item.fulltextWith Fulltext-
item.accessRightsOpen Access-
item.contributorJUNKERS, Tanja-
item.fullcitationJUNKERS, Tanja (2015) [2+2] Photo-cycloadditions for polymer modification and surface decoration. In: EUROPEAN POLYMER JOURNAL, 62, p. 273-280.-
item.validationecoom 2016-
crisitem.journal.issn0014-3057-
crisitem.journal.eissn1873-1945-
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