Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/18763
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dc.contributor.authorCOSEMANS, Inge-
dc.contributor.authorVANDENBERGH, Joke-
dc.contributor.authorD'OLIESLAEGER, Lien-
dc.contributor.authorETHIRAJAN, Anitha-
dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2015-04-23T10:20:35Z-
dc.date.available2015-04-23T10:20:35Z-
dc.date.issued2014-
dc.identifier.citationEUROPEAN POLYMER JOURNAL, 55, p. 114-122-
dc.identifier.issn0014-3057-
dc.identifier.urihttp://hdl.handle.net/1942/18763-
dc.description.abstractThe synthesis of amphiphilic rod-coil block copolymers with a poly(p-phenylene vinylene) (PPV) rod-like block using a Click chemistry approach is investigated and a facile reaction pathway towards poly(p-phenylene vinylene)-block-poly(ethylene glycol) (PPV-b-PEG) block copolymers is presented. To reach this aim, an alkyne-functionalized PPV block (synthesized from anionic sulfinyl precursor route polymerization) was synthesized and subsequently coupled to azide-functionalized poly(ethylene glycol) of different lengths. Self-assembly of these materials in aqueous solution demonstrate successful micelle formation with core-shell morphology and different sizes for these PPV-b-PEG block copolymers as is confirmed by TEM and DLS measurements respectively. (C) 2014 Elsevier Ltd. All rights reserved.-
dc.description.sponsorshipThe BOF (Bijzonder Onderzoeksfonds) of the UHasselt is acknowledged for the PhD grant for I.C.T.J. is grateful for funding in the framework of the Odysseus scheme from the Fonds Wetenschappelijk Onderzoek (FWO). A.E. is a FWO postdoctoral research fellow. Additionally, support from the European Science Foundation - "Precision Polymer Materials (P2 M)" program as well as the Belgian Science Policy (Belspo) in the framework of the Interuniversity Attraction Poles Program IAP-PAI P7/05 "Functional Supramolecular Systems" is gratefully acknowledged.-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.rights© 2014 Elsevier Ltd. All rights reserved.-
dc.subject.otherPoly(p-phenylene vinylene) (PPV); Anionic polymerization; CuAAC conjugation; Block copolymers-
dc.subject.otherPoly(p-phenylene vinylene) (PPV); anionic polymerization; CuAAC conjugation; block copolymers-
dc.titleSynthesis of PPV-b-PEG block copolymers via CuAAC conjugation-
dc.typeJournal Contribution-
dc.identifier.epage122-
dc.identifier.spage114-
dc.identifier.volume55-
local.format.pages9-
local.bibliographicCitation.jcatA1-
dc.description.notes[Cosemans, Inge; Vandenbergh, Joke; Junkers, Thomas] Hasselt Univ, Inst Mat Res, Polymer React Design Grp, B-3590 Diepenbeek, Belgium. [D'Olieslaeger, Lien; Ethirajan, Anitha; Vanderzande, Dirk] Hasselt Univ, Inst Mat Res, BE-3590 Diepenbeek, Belgium. [Lutsen, Laurence; Vanderzande, Dirk; Junkers, Thomas] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium.-
local.publisher.placeOXFORD-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1016/j.eurpolymj.2014.03.016-
dc.identifier.isi000337199500013-
item.validationecoom 2015-
item.contributorCOSEMANS, Inge-
item.contributorVANDENBERGH, Joke-
item.contributorD'OLIESLAEGER, Lien-
item.contributorETHIRAJAN, Anitha-
item.contributorLUTSEN, Laurence-
item.contributorVANDERZANDE, Dirk-
item.contributorJUNKERS, Tanja-
item.accessRightsRestricted Access-
item.fullcitationCOSEMANS, Inge; VANDENBERGH, Joke; D'OLIESLAEGER, Lien; ETHIRAJAN, Anitha; LUTSEN, Laurence; VANDERZANDE, Dirk & JUNKERS, Tanja (2014) Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation. In: EUROPEAN POLYMER JOURNAL, 55, p. 114-122.-
item.fulltextWith Fulltext-
crisitem.journal.issn0014-3057-
crisitem.journal.eissn1873-1945-
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