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http://hdl.handle.net/1942/19170
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DC Field | Value | Language |
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dc.contributor.author | CONINGS, Bert | - |
dc.contributor.author | DRIJKONINGEN, Jeroen | - |
dc.contributor.author | Gauquelin, Nicolas | - |
dc.contributor.author | BABAYIGIT, Aslihan | - |
dc.contributor.author | D'HAEN, Jan | - |
dc.contributor.author | D'OLIESLAEGER, Lien | - |
dc.contributor.author | ETHIRAJAN, Anitha | - |
dc.contributor.author | Verbeeck, Jo | - |
dc.contributor.author | MANCA, Jean | - |
dc.contributor.author | Mosconi, Edoardo | - |
dc.contributor.author | De Angelis, Filippo | - |
dc.contributor.author | BOYEN, Hans-Gerd | - |
dc.date.accessioned | 2015-09-16T14:31:08Z | - |
dc.date.available | 2015-09-16T14:31:08Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | ADVANCED ENERGY MATERIALS, 5 (15) | - |
dc.identifier.issn | 1614-6832 | - |
dc.identifier.uri | http://hdl.handle.net/1942/19170 | - |
dc.description.abstract | Organolead halide perovskites currently are the new front-runners as light absorbers in hybrid solar cells, as they combine efficiencies passing already 20% with deposition temperatures below 100 degrees C and cheap solution-based fabrication routes. Long-term stability remains a major obstacle for application on an industrial scale. Here, it is demonstrated that significant decomposition effects already occur during annealing of a methylammonium lead triiode perovskite at 85 degrees C even in inert atmosphere thus violating international standards. The observed behavior supports the view of currently used perovskite materials as soft matter systems with low formation energies, thus representing a major bottleneck for their application, especially in countries with high average temperatures. This result can trigger a broader search for new perovskite families with improved thermal stability. | - |
dc.description.sponsorship | This work was financially supported by the Bijzonder Onderzoeksfonds (BOF, Hasselt University), the Fonds voor Wetenschappelijk Onderzoek (FWO) within the Odysseus program, and the Interreg project Organext. B.C. and A.E. are postdoctoral research fellows of FWO. The authors thank Bart Ruttens for supporting the XRD measurements. J.V. acknowledges funding from the Geconcentreerde Onderzoekacties (GOA) project "Solarpaint" of the University of Antwerp and the FWO project G.0044.13N "Charge ordering." | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.rights | © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.subject.other | atomic force microscopy; perovskite solar cells; stability; transmission electron microscopy; X-ray photoelectron spectroscopy | - |
dc.subject.other | atomic force microscopy; perovskite solar cells; stability; transmission electron microscopy; X-ray photoelectron spectroscopy | - |
dc.title | Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite | - |
dc.type | Journal Contribution | - |
dc.identifier.issue | 15 | - |
dc.identifier.volume | 5 | - |
local.format.pages | 8 | - |
local.format.pages | 8 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Conings, Bert; Drijkoningen, Jeroen; Babayigit, Aslihan; D'Haen, Jan; D'Olieslaeger, Lien; Ethirajan, Anitha; Boyen, Hans-Gerd] Hasselt Univ, Inst Mat Res, B-3590 Diepenbeek, Belgium. [Gauquelin, Nicolas; Verbeeck, Jo] Univ Antwerp, Electron Microscopy Mat Res EMAT, B-2020 Antwerp, Belgium. [Manca, Jean] Hasselt Univ, X LaB, B-3590 Diepenbeek, Belgium. [Mosconi, Edoardo; De Angelis, Filippo] CNR ISTM, Computat Lab Hybrid Organ Photovolta CLHYO, I-06123 Perugia, Italy. | - |
local.publisher.place | WEINHEIM | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1002/aenm.201500477 | - |
dc.identifier.isi | 000359374900005 | - |
item.accessRights | Restricted Access | - |
item.validation | ecoom 2016 | - |
item.fulltext | With Fulltext | - |
item.fullcitation | CONINGS, Bert; DRIJKONINGEN, Jeroen; Gauquelin, Nicolas; BABAYIGIT, Aslihan; D'HAEN, Jan; D'OLIESLAEGER, Lien; ETHIRAJAN, Anitha; Verbeeck, Jo; MANCA, Jean; Mosconi, Edoardo; De Angelis, Filippo & BOYEN, Hans-Gerd (2015) Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite. In: ADVANCED ENERGY MATERIALS, 5 (15). | - |
item.contributor | CONINGS, Bert | - |
item.contributor | DRIJKONINGEN, Jeroen | - |
item.contributor | Gauquelin, Nicolas | - |
item.contributor | BABAYIGIT, Aslihan | - |
item.contributor | D'HAEN, Jan | - |
item.contributor | D'OLIESLAEGER, Lien | - |
item.contributor | ETHIRAJAN, Anitha | - |
item.contributor | Verbeeck, Jo | - |
item.contributor | MANCA, Jean | - |
item.contributor | Mosconi, Edoardo | - |
item.contributor | De Angelis, Filippo | - |
item.contributor | BOYEN, Hans-Gerd | - |
crisitem.journal.issn | 1614-6832 | - |
crisitem.journal.eissn | 1614-6840 | - |
Appears in Collections: | Research publications |
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aenm.201500477.pdf Restricted Access | 1.8 MB | Adobe PDF | View/Open Request a copy |
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