Please use this identifier to cite or link to this item:
http://hdl.handle.net/1942/19753
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | ZAQUEN, Neomy | - |
dc.contributor.author | BAETEN, Evelien | - |
dc.contributor.author | VANDENBERGH, Joke | - |
dc.contributor.author | LUTSEN, Laurence | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.contributor.author | JUNKERS, Tanja | - |
dc.date.accessioned | 2015-11-09T13:05:14Z | - |
dc.date.available | 2015-11-09T13:05:14Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | CHEMICAL ENGINEERING & TECHNOLOGY, 38 (10), p. 1749-1757 | - |
dc.identifier.issn | 0930-7516 | - |
dc.identifier.uri | http://hdl.handle.net/1942/19753 | - |
dc.description.abstract | Continuous synthesis of multistep polymerizations at microscale is made available by coupling two microstructured chip reactors in a single reactor setup. Conjugated [2-methoxy-5-(3,7-dimethyloctyloxy)]-1,4-phenylenevinylene (MDMO-PPV) is synthesized via the radical sulfinyl precursor route. Reactions are carried out in separate reactors and optimization of the elimination of polymer can be effectively performed in a defined temperature range, allowing for full polymer conversion within minutes and formation of conjugated materials. The combination of both processes in a single coupled reactor setup permits total monomer-to-conjugated-MDMO-PPV conversions while retaining its pristine optical properties. Polymer characteristics are comparatively good and the reduction in yield due to the lower initial monomer concentrations is compensated by the much shorter reaction times required in the flow process. | - |
dc.description.sponsorship | N. Z. is grateful for the funding from the Agency for Innovation by Science and Technology in Flanders (IWT), T. J. acknowledges funding from the Fund for Scientific Research Flanders (FWO) in the framework of the Odysseus scheme. J. V. wishes to thank the FWO for a postdoctoral fellowship grant. The authors also like to acknowledge the IWT/TETRA project INFLOWREACT. | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.rights | © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.subject.other | conjugated polymers; continuous flow microreactors; poly(p-phenylene vinylene); radical polymerization | - |
dc.subject.other | Conjugated polymers; Continuous flow microreactors; Poly(p-phenylene vinylene); Radical polymerization | - |
dc.title | Continuous Synthesis and Thermal Elimination of Sulfinyl-Route Poly(p-Phenylene Vinylene) in Consecutive Flow Reactions | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 1757 | - |
dc.identifier.issue | 10 | - |
dc.identifier.spage | 1749 | - |
dc.identifier.volume | 38 | - |
local.format.pages | 9 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Zaquen, Neomy; Baeten, Evelien; Vandenbergh, Joke; Lutsen, Laurence; Vanderzande, Dirk; Junkers, Thomas] Hasselt Univ, Inst Mat Onderzoek, Polymer React Design PRD Grp, Diepenbeek, Belgium. [Vanderzande, Dirk; Junkers, Thomas] IMEC Associated Lab IMOMEC, Diepenbeek, Belgium. | - |
local.publisher.place | WEINHEIM | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1002/ceat.201400754 | - |
dc.identifier.isi | 000362298000008 | - |
item.contributor | ZAQUEN, Neomy | - |
item.contributor | BAETEN, Evelien | - |
item.contributor | VANDENBERGH, Joke | - |
item.contributor | LUTSEN, Laurence | - |
item.contributor | VANDERZANDE, Dirk | - |
item.contributor | JUNKERS, Tanja | - |
item.validation | ecoom 2016 | - |
item.fulltext | With Fulltext | - |
item.accessRights | Restricted Access | - |
item.fullcitation | ZAQUEN, Neomy; BAETEN, Evelien; VANDENBERGH, Joke; LUTSEN, Laurence; VANDERZANDE, Dirk & JUNKERS, Tanja (2015) Continuous Synthesis and Thermal Elimination of Sulfinyl-Route Poly(p-Phenylene Vinylene) in Consecutive Flow Reactions. In: CHEMICAL ENGINEERING & TECHNOLOGY, 38 (10), p. 1749-1757. | - |
crisitem.journal.issn | 0930-7516 | - |
crisitem.journal.eissn | 1521-4125 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
zaquen 1.pdf Restricted Access | Published version | 296.62 kB | Adobe PDF | View/Open Request a copy |
SCOPUSTM
Citations
6
checked on Sep 2, 2020
WEB OF SCIENCETM
Citations
8
checked on Oct 12, 2024
Page view(s)
66
checked on Jun 13, 2022
Download(s)
54
checked on Jun 13, 2022
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.