Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/19852
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dc.contributor.authorLAUN, Joachim-
dc.contributor.authorVorobii, Mariia-
dc.contributor.authorPereira, Andres de los Santos-
dc.contributor.authorPop-Georgievski, Ognen-
dc.contributor.authorTrouillet, Vanessa-
dc.contributor.authorWelle, Alexander-
dc.contributor.authorBarner-Kowollik, Christopher-
dc.contributor.authorRodriguez-Emmenegger, Cesar-
dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2015-11-30T11:46:46Z-
dc.date.available2015-11-30T11:46:46Z-
dc.date.issued2015-
dc.identifier.citationMACROMOLECULAR RAPID COMMUNICATIONS, 36 (18), p. 1681-1686-
dc.identifier.issn1022-1336-
dc.identifier.urihttp://hdl.handle.net/1942/19852-
dc.description.abstractSurface-initiated photo-induced copper-mediated radical polymerization is employed to graft a wide range of polyacrylate brushes from silicon substrates at extremely low catalyst concentrations. This is the first time that the controlled nature of the reported process is demonstrated via block copolymer formation and re-initiation experiments. In addition to unmatched copper catalyst concentrations in the range of few ppb, film thicknesses up to almost 1 mu m are achieved within only 1 h.-
dc.description.sponsorshipJ.L. and M.V. contributed equally to this work. This work was supported by the Grant Agency of the Czech Republic (GACR) under Contract No. 15-09368Y, and the European Regional Development Funds under the project "BIOCEV-Biotechnology and Biomedicine Centre of the Academy of Sciences and Charles University" (CZ.1.05/1.1.00/02.0109) and ERDF OPPK CZ.2.16/3.1.00/21545. T.J. and J.L. are grateful for funding from the Fonds Wetenschappelijk Onderzoek (FWO) in the form of a project grant and a PhD scholarship. Additional support by the Karlsruhe Nano Micro Facility (KNMF), a Helmholtz Research Infrastructure at the Karlsruhe Institute of Technology (KIT), is acknowledged. C.B.-K. acknowledges continued support via the STN program of the Helmholtz association and the KIT. The authors thank V. Jacobi and Prof. A. Rosenhahn (Ruhr-University Bochum) for their support.-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.subject.othercopper-mediated polymerization; photo-induced polymerization; polymer brushes; reversible deactivation radical polymerization; spatial control-
dc.titleSurface Grafting via Photo-Induced Copper-Mediated Radical Polymerization at Extremely Low Catalyst Concentrations-
dc.typeJournal Contribution-
dc.identifier.epage1686-
dc.identifier.issue18-
dc.identifier.spage1681-
dc.identifier.volume36-
local.format.pages6-
local.bibliographicCitation.jcatA1-
dc.description.notes[Laun, Joachim; Junkers, Thomas] Hasselt Univ, Inst Mat Res, B-3500 Hasselt, Belgium. [Rodriguez-Emmenegger, Cesar] Acad Sci Czech Republic, Inst Macromol Chem, Vvi, CR-16206 Prague, Czech Republic. [Trouillet, Vanessa] Karlsruhe Inst Technol, Inst Appl Mat, D-76344 Eggenstein Leopoldshafen, Germany. [Trouillet, Vanessa; Welle, Alexander] Karlsruhe Inst Technol, Karlsruhe Nano Micro Facil, D-76344 Eggenstein Leopoldshafen, Germany. [Welle, Alexander; Barner-Kowollik, Christopher] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, Preparat Macromol Chem, D-76128 Karlsruhe, Germany. [Welle, Alexander; Barner-Kowollik, Christopher] Karlsruhe Inst Technol, Inst Biol Grenzflachen, D-76344 Eggenstein Leopoldshafen, Germany. [Junkers, Thomas] IMOMEC, IMEC Associated Lab, B-3590 Diepenbeek, Belgium.-
local.publisher.placeWEINHEIM-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1002/marc.201500322-
dc.identifier.isi000362555900009-
item.fulltextWith Fulltext-
item.contributorLAUN, Joachim-
item.contributorVorobii, Mariia-
item.contributorPereira, Andres de los Santos-
item.contributorPop-Georgievski, Ognen-
item.contributorTrouillet, Vanessa-
item.contributorWelle, Alexander-
item.contributorBarner-Kowollik, Christopher-
item.contributorRodriguez-Emmenegger, Cesar-
item.contributorJUNKERS, Tanja-
item.fullcitationLAUN, Joachim; Vorobii, Mariia; Pereira, Andres de los Santos; Pop-Georgievski, Ognen; Trouillet, Vanessa; Welle, Alexander; Barner-Kowollik, Christopher; Rodriguez-Emmenegger, Cesar & JUNKERS, Tanja (2015) Surface Grafting via Photo-Induced Copper-Mediated Radical Polymerization at Extremely Low Catalyst Concentrations. In: MACROMOLECULAR RAPID COMMUNICATIONS, 36 (18), p. 1681-1686.-
item.accessRightsRestricted Access-
item.validationecoom 2016-
crisitem.journal.issn1022-1336-
crisitem.journal.eissn1521-3927-
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