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http://hdl.handle.net/1942/20240
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DC Field | Value | Language |
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dc.contributor.author | TASSI, Marco | - |
dc.contributor.author | ADRIAENSENS, Peter | - |
dc.contributor.author | Bianchi, Luca | - |
dc.contributor.author | Barkakaty, Balaka | - |
dc.contributor.author | CARLEER, Robert | - |
dc.contributor.author | Chen, Jihua | - |
dc.contributor.author | Hensley, Dale K. | - |
dc.contributor.author | Marrocchi, Assunta | - |
dc.contributor.author | Vaccaro, Luigi | - |
dc.contributor.author | Bartollini, Elena | - |
dc.date.accessioned | 2016-01-14T09:18:10Z | - |
dc.date.available | 2016-01-14T09:18:10Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | RSC Advances, 5 (130), p. 107200-107208 | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | http://hdl.handle.net/1942/20240 | - |
dc.description.abstract | In view of searching for efficient polymeric supports for organic bases to be used in environmentally friendly reaction conditions, novel gel-type cross-linked polystyrenes functionalized with diethylamine and 1,5,7-triazabicyclo[4.4.0]dec-5-ene, have been prepared. The structural properties and morphology of these catalysts have been determined by extensive solid state NMR experiments, FTIR spectroscopy and SEM/TEM microscopy. SPACeR-supported bases were found to exhibit high catalytic activity in the epoxide ring opening by phenols. A range of β-substituted alcohols have been readily and regioselectively synthesized. | - |
dc.description.sponsorship | This research has been developed and partially financed within the National project "BIT3G" - Italian Green Chemistry Cluster. We gratefully acknowledge the Universita degli Studi di Perugia for financial support. EM (J.C. and D.K.H.) experiments were conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility. | - |
dc.language.iso | en | - |
dc.publisher | RSC | - |
dc.rights | This journal is © The Royal Society of Chemistry | - |
dc.title | Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 107208 | - |
dc.identifier.issue | 130 | - |
dc.identifier.spage | 107200 | - |
dc.identifier.volume | 5 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | Vaccaro, L (reprint author), Univ Perugia, CEMIN Dipartimento Chim Biol & Biotecnol, Lab Green Synthet Organ Chem, Via Elce di Sotto 8, I-06123 Perugia, Italy. luigi.vaccaro@unipg.it | - |
local.publisher.place | RSC Advances | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
local.relation.ispartofseriesnr | 130 | - |
dc.identifier.doi | 10.1039/C5RA21140A | - |
dc.identifier.isi | 000367271700002 | - |
item.fullcitation | TASSI, Marco; ADRIAENSENS, Peter; Bianchi, Luca; Barkakaty, Balaka; CARLEER, Robert; Chen, Jihua; Hensley, Dale K.; Marrocchi, Assunta; Vaccaro, Luigi & Bartollini, Elena (2015) Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases. In: RSC Advances, 5 (130), p. 107200-107208. | - |
item.validation | ecoom 2017 | - |
item.fulltext | With Fulltext | - |
item.accessRights | Restricted Access | - |
item.contributor | TASSI, Marco | - |
item.contributor | ADRIAENSENS, Peter | - |
item.contributor | Bianchi, Luca | - |
item.contributor | Barkakaty, Balaka | - |
item.contributor | CARLEER, Robert | - |
item.contributor | Chen, Jihua | - |
item.contributor | Hensley, Dale K. | - |
item.contributor | Marrocchi, Assunta | - |
item.contributor | Vaccaro, Luigi | - |
item.contributor | Bartollini, Elena | - |
crisitem.journal.eissn | 2046-2069 | - |
Appears in Collections: | Research publications |
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File | Description | Size | Format | |
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c5ra21140a.pdf Restricted Access | Published version | 841.13 kB | Adobe PDF | View/Open Request a copy |
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