Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/20688
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dc.contributor.authorDerboven, Pieter-
dc.contributor.authorVan Steenberge, Paul H. M.-
dc.contributor.authorVANDENBERGH, Joke-
dc.contributor.authorReyniers, Marie-Francoise-
dc.contributor.authorJUNKERS, Tanja-
dc.contributor.authorD'hooge, Dagmar R.-
dc.contributor.authorMarin, Guy B.-
dc.date.accessioned2016-02-18T09:39:43Z-
dc.date.available2016-02-18T09:39:43Z-
dc.date.issued2015-
dc.identifier.citationMACROMOLECULAR RAPID COMMUNICATIONS, 36 (24), p. 2149-2155-
dc.identifier.issn1022-1336-
dc.identifier.urihttp://hdl.handle.net/1942/20688-
dc.description.abstractThe superior capabilities of structured microreactors over batch reactors are demonstrated for reversible addition-fragmentation chain transfer (RAFT) solution polymerization of n-butyl acrylate with the aid of simulations, explicitly accounting for the chain length distribution of all macrospecies types. Since perfect isothermicity can be established in a microreactor, less side products due to backbiting and beta-scission are formed compared to the batch operation in which ineffective heat removal leads to an undesirable temperature spike. For a given RAFT chain transfer agent (CTA), additional microstructural control results under microflow conditions by optimizing the reaction temperature, lowering the dilution degree, or decreasing the initial molar ratio of monomer to RAFT CTA.-
dc.description.sponsorshipThe authors acknowledge financial support from the Interuniversity Attraction Poles Programme, Belgian State, Belgian Science Policy ((P7/05) Functional Supramolecular Systems (FS2)). P.D., P.H.M.V.S., D.R.D., M.-F.R., and G.B.M. acknowledge financial support from the Long Term Structural Methusalem Funding by the Flemish Government and the Fund for Scientific Research Flanders (FWO; G.0065.13N). P.D. acknowledges financial support from the Institute for the Promotion of Innovation through Science and Technology in Flanders (IWT Vlaanderen). D.R.D. and J.V. acknowledge the FWO through a postdoctoral fellowship. T.J. is grateful for additional funding from FWO in the framework of an Odysseus grant.-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.subject.otheracrylates; branching; microreactors; polymer kinetics; reversible addition–fragmentation chain transfer, RAFT-
dc.subject.otheracrylates; branching; microreactors; polymer kinetics; reversible addition-fragmentation chain transfer; RAFT-
dc.titleImproved Livingness and Control over Branching in RAFT Polymerization of Acrylates: Could Microflow Synthesis Make the Difference?-
dc.typeJournal Contribution-
dc.identifier.epage2155-
dc.identifier.issue24-
dc.identifier.spage2149-
dc.identifier.volume36-
local.format.pages7-
local.bibliographicCitation.jcatA1-
dc.description.notes[Derboven, Pieter; Van Steenberge, Paul H. M.; Reyniers, Marie-Francoise; D'hooge, Dagmar R.; Marin, Guy B.] Univ Ghent, Chem Technol Lab, B-9052 Zwijnaarde, Ghent, Belgium. [Vandenbergh, Joke; Junkers, Thomas] Univ Hasselt, Inst Mat Res IMO Imomec, Polymer React Design Grp, B-3590 Diepenbeek, Belgium. [D'hooge, Dagmar R.] Univ Ghent, Dept Text, B-9052 Zwijnaarde, Ghent, Belgium.-
local.publisher.placeWEINHEIM-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1002/marc.201500357-
dc.identifier.isi000368033500005-
item.validationecoom 2017-
item.fulltextWith Fulltext-
item.accessRightsRestricted Access-
item.fullcitationDerboven, Pieter; Van Steenberge, Paul H. M.; VANDENBERGH, Joke; Reyniers, Marie-Francoise; JUNKERS, Tanja; D'hooge, Dagmar R. & Marin, Guy B. (2015) Improved Livingness and Control over Branching in RAFT Polymerization of Acrylates: Could Microflow Synthesis Make the Difference?. In: MACROMOLECULAR RAPID COMMUNICATIONS, 36 (24), p. 2149-2155.-
item.contributorDerboven, Pieter-
item.contributorVan Steenberge, Paul H. M.-
item.contributorVANDENBERGH, Joke-
item.contributorReyniers, Marie-Francoise-
item.contributorJUNKERS, Tanja-
item.contributorD'hooge, Dagmar R.-
item.contributorMarin, Guy B.-
crisitem.journal.issn1022-1336-
crisitem.journal.eissn1521-3927-
Appears in Collections:Research publications
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