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http://hdl.handle.net/1942/22822
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DC Field | Value | Language |
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dc.contributor.author | RAILIAN, Svitlana | - |
dc.contributor.author | WENN, Benjamin | - |
dc.contributor.author | JUNKERS, Tanja | - |
dc.date.accessioned | 2016-12-01T10:46:55Z | - |
dc.date.available | 2016-12-01T10:46:55Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | JOURNAL OF FLOW CHEMISTRY, 6(3), p. 260-267 | - |
dc.identifier.issn | 2062-249X | - |
dc.identifier.uri | http://hdl.handle.net/1942/22822 | - |
dc.description.abstract | The synthetic scope of photo-induced copper-mediated polymerization (photoCMP) in continuous-flow reactors is further explored. A series of monomers, namely, methyl (MA), ethyl (EA), n-butyl (nBA), 2-hydroxyethyl (HEA), and di(ethylene glycol) ethyl ether (DEGA) acrylate are investigated, all showing high livingness (dispersity in the range of 1.1 and linear first order kinetics) in the polymerizations and high conversions within 20-min reaction time. Next to the commonly used solvent (dimethyl sulfoxide [DMSO]), also a water-ethanol mixture was used as greener alternative, without any loss in reaction control. Upscaling the reactor from 2 to 16 mL allows for production of over 200 g of high-definition material (3000 g/mol, 1.1 dispersity) in overnight operation (18 h), demonstrating that the photoprocess can be run under very stable conditions even for extended reaction times. Via coupling of two reactors, direct chain extension of copolymers in a single reaction step is also demonstrated. | - |
dc.description.sponsorship | The authors are grateful for support by the Belgian Science Policy (BELSPO) via the Interuniversity Attraction Poles Program IAP P7/05 "Functional Supramolecular Systems." T.J. wishes to thank the Fonds Wetenschappelijk Onderzoek (FWO) for a research grant. Further, assistance in laboratory work during the internships of Axel-Laurenz Buckinx and Dries Wyers is kindly acknowledged. | - |
dc.language.iso | en | - |
dc.publisher | AKADEMIAI KIADO RT | - |
dc.rights | © 2016 Akadémiai Kiadó | - |
dc.subject.other | photopolymerization; controlled polymerization; block copolymers; upscaling; flow chemistry | - |
dc.subject.other | photopolymerization; controlled polymerization; block copolymers; upscaling; flow chemistry | - |
dc.title | Photo-Induced Copper-Mediated Acrylate Polymerization in Continuous-Flow Reactors | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 267 | - |
dc.identifier.issue | 3 | - |
dc.identifier.spage | 260 | - |
dc.identifier.volume | 6 | - |
local.format.pages | 8 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Railian, Svitlana; Wenn, Benjamin; Junkers, Thomas] Univ Hasselt, Inst Mat Res IMO, Polymer React Design Grp, Martelarenlaan 42, B-3500 Hasselt, Belgium. [Junkers, Thomas] IMEC Associated Lab IMOMEC, Wetenschapspk 1, B-3590 Diepenbeek, Belgium. | - |
local.publisher.place | BUDAPEST | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.identifier.doi | 10.1556/1846.2016.00018 | - |
dc.identifier.isi | 000386431100016 | - |
item.fullcitation | RAILIAN, Svitlana; WENN, Benjamin & JUNKERS, Tanja (2016) Photo-Induced Copper-Mediated Acrylate Polymerization in Continuous-Flow Reactors. In: JOURNAL OF FLOW CHEMISTRY, 6(3), p. 260-267. | - |
item.validation | ecoom 2017 | - |
item.accessRights | Open Access | - |
item.fulltext | With Fulltext | - |
item.contributor | RAILIAN, Svitlana | - |
item.contributor | WENN, Benjamin | - |
item.contributor | JUNKERS, Tanja | - |
crisitem.journal.issn | 2062-249X | - |
crisitem.journal.eissn | 2063-0212 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
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Photo-Induced.pdf Restricted Access | Published version | 446.31 kB | Adobe PDF | View/Open Request a copy |
photo induced.pdf | Peer-reviewed author version | 508.34 kB | Adobe PDF | View/Open |
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