Please use this identifier to cite or link to this item:
http://hdl.handle.net/1942/23751
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Barner-Kowollik, Christopher | - |
dc.contributor.author | Beuermann, Sabine | - |
dc.contributor.author | Buback, Michael | - |
dc.contributor.author | Hutchinson, Robin A. | - |
dc.contributor.author | JUNKERS, Tanja | - |
dc.contributor.author | Kattner, Hendrik | - |
dc.contributor.author | Manders, Bart | - |
dc.contributor.author | Nikitin, Anatoly N. | - |
dc.contributor.author | Russell, Gregory T. | - |
dc.contributor.author | van Herk, Alex M. | - |
dc.date.accessioned | 2017-05-18T12:08:08Z | - |
dc.date.available | 2017-05-18T12:08:08Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | MACROMOLECULAR CHEMISTRY AND PHYSICS, 218(1), p. 1-13 (Art N° UNSP 1600357) | - |
dc.identifier.issn | 1022-1352 | - |
dc.identifier.uri | http://hdl.handle.net/1942/23751 | - |
dc.description.abstract | Propagation rate coefficient values, k(p), reported by several groups for radical polymerization of bulk vinyl acetate are critically evaluated. All data are obtained by the combination of pulsed-laser polymerization and subsequent polymer analysis by size exclusion chromatography, as recommended by the IUPAC Working Party on Modeling of Polymerization Kinetics and Processes. Although a small (approximate to 15%) increase in k(p) is observed as laser pulse repetition rate is increased from low (25-100 Hz) to high (300-500 Hz) values, all of the data fulfill the required consistency criteria and thus are combined into a benchmark set covering the temperature range of 5-70 degrees C. The data are fitted well by an Arrhenius relation resulting in a pre-exponential factor of 1.35 x 10(7) L mol(-1) s(-1) and an activation energy of 20.4 kJ mol(-1), with 95% confidence ellipsoids for the parameters also presented. | - |
dc.description.sponsorship | The financial support of IUPAC via project 2013-045-1-400 is gratefully acknowledged. | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.rights | © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.subject.other | kinetics; pulsed laser polymerization; radical polymerization; vinyl acetate | - |
dc.subject.other | kinetics; pulsed laser polymerization; radical polymerization; vinyl acetate | - |
dc.title | Critically Evaluated Rate Coefficients in Radical Polymerization-8. Propagation Rate Coefficients for Vinyl Acetate in Bulk | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 13 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 1 | - |
dc.identifier.volume | 218 | - |
local.format.pages | 13 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | [Barner-Kowollik, Christopher] KIT, Inst Tech Chem & Polymerchem, Preparat Macromol Chem, Engesserstr 18, D-76131 Karlsruhe, Germany. [Barner-Kowollik, Christopher] KIT, Inst Biol Grenzflachen, Herrmann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany. [Beuermann, Sabine] Tech Univ Clausthal, Inst Tech Chem, Arnold Sommerfeld Str 4, D-38678 Clausthal Zellerfeld, Germany. [Buback, Michael; Kattner, Hendrik] Univ Gottingen, Inst Phys Chem, Tech & Macromol Chem Grp, Tammannstr 6, D-37077 Gottingen, Germany. [Hutchinson, Robin A.] Queens Univ, Dept Chem Engn, Dupuis Hall, Kingston, ON K7L 3N6, Canada. [Junkers, Thomas] Univ Hasselt, Inst Mat Res, Polymer React Design Grp, Martelarenlaan 42, B-3500 Hasselt, Belgium. [Manders, Bart] BASF SE, EDG DD H503, D-67056 Ludwigshafen, Germany. [Nikitin, Anatoly N.] Russian Acad Sci, Branch Fed Sci Res Ctr Crystallog & Photon, Inst Laser & Informat Technol, Svyatoozerskaya 1, Shatura 140700, Moscow Region, Russia. [Russell, Gregory T.] Univ Canterbury, Dept Chem, Private Bag 4800, Christchurch 8140, New Zealand. [van Herk, Alex M.] Eindhoven Univ Technol, Dept Chem & Chem Engn, POB 513, NL-5600 MB Eindhoven, Netherlands. | - |
local.publisher.place | WEINHEIM | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
local.bibliographicCitation.artnr | UNSP 1600357 | - |
dc.identifier.doi | 10.1002/macp.201600357 | - |
dc.identifier.isi | 000393411000011 | - |
item.contributor | Barner-Kowollik, Christopher | - |
item.contributor | Beuermann, Sabine | - |
item.contributor | Buback, Michael | - |
item.contributor | Hutchinson, Robin A. | - |
item.contributor | JUNKERS, Tanja | - |
item.contributor | Kattner, Hendrik | - |
item.contributor | Manders, Bart | - |
item.contributor | Nikitin, Anatoly N. | - |
item.contributor | Russell, Gregory T. | - |
item.contributor | van Herk, Alex M. | - |
item.validation | ecoom 2018 | - |
item.fulltext | With Fulltext | - |
item.accessRights | Restricted Access | - |
item.fullcitation | Barner-Kowollik, Christopher; Beuermann, Sabine; Buback, Michael; Hutchinson, Robin A.; JUNKERS, Tanja; Kattner, Hendrik; Manders, Bart; Nikitin, Anatoly N.; Russell, Gregory T. & van Herk, Alex M. (2017) Critically Evaluated Rate Coefficients in Radical Polymerization-8. Propagation Rate Coefficients for Vinyl Acetate in Bulk. In: MACROMOLECULAR CHEMISTRY AND PHYSICS, 218(1), p. 1-13 (Art N° UNSP 1600357). | - |
crisitem.journal.issn | 1022-1352 | - |
crisitem.journal.eissn | 1521-3935 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
barner-kowollik 1.pdf Restricted Access | Published version | 475.9 kB | Adobe PDF | View/Open Request a copy |
SCOPUSTM
Citations
11
checked on Sep 3, 2020
WEB OF SCIENCETM
Citations
26
checked on Oct 12, 2024
Page view(s)
66
checked on Sep 5, 2022
Download(s)
54
checked on Sep 5, 2022
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.