Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/23751
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dc.contributor.authorBarner-Kowollik, Christopher-
dc.contributor.authorBeuermann, Sabine-
dc.contributor.authorBuback, Michael-
dc.contributor.authorHutchinson, Robin A.-
dc.contributor.authorJUNKERS, Tanja-
dc.contributor.authorKattner, Hendrik-
dc.contributor.authorManders, Bart-
dc.contributor.authorNikitin, Anatoly N.-
dc.contributor.authorRussell, Gregory T.-
dc.contributor.authorvan Herk, Alex M.-
dc.date.accessioned2017-05-18T12:08:08Z-
dc.date.available2017-05-18T12:08:08Z-
dc.date.issued2017-
dc.identifier.citationMACROMOLECULAR CHEMISTRY AND PHYSICS, 218(1), p. 1-13 (Art N° UNSP 1600357)-
dc.identifier.issn1022-1352-
dc.identifier.urihttp://hdl.handle.net/1942/23751-
dc.description.abstractPropagation rate coefficient values, k(p), reported by several groups for radical polymerization of bulk vinyl acetate are critically evaluated. All data are obtained by the combination of pulsed-laser polymerization and subsequent polymer analysis by size exclusion chromatography, as recommended by the IUPAC Working Party on Modeling of Polymerization Kinetics and Processes. Although a small (approximate to 15%) increase in k(p) is observed as laser pulse repetition rate is increased from low (25-100 Hz) to high (300-500 Hz) values, all of the data fulfill the required consistency criteria and thus are combined into a benchmark set covering the temperature range of 5-70 degrees C. The data are fitted well by an Arrhenius relation resulting in a pre-exponential factor of 1.35 x 10(7) L mol(-1) s(-1) and an activation energy of 20.4 kJ mol(-1), with 95% confidence ellipsoids for the parameters also presented.-
dc.description.sponsorshipThe financial support of IUPAC via project 2013-045-1-400 is gratefully acknowledged.-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.rights© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.subject.otherkinetics; pulsed laser polymerization; radical polymerization; vinyl acetate-
dc.subject.otherkinetics; pulsed laser polymerization; radical polymerization; vinyl acetate-
dc.titleCritically Evaluated Rate Coefficients in Radical Polymerization-8. Propagation Rate Coefficients for Vinyl Acetate in Bulk-
dc.typeJournal Contribution-
dc.identifier.epage13-
dc.identifier.issue1-
dc.identifier.spage1-
dc.identifier.volume218-
local.format.pages13-
local.bibliographicCitation.jcatA1-
dc.description.notes[Barner-Kowollik, Christopher] KIT, Inst Tech Chem & Polymerchem, Preparat Macromol Chem, Engesserstr 18, D-76131 Karlsruhe, Germany. [Barner-Kowollik, Christopher] KIT, Inst Biol Grenzflachen, Herrmann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany. [Beuermann, Sabine] Tech Univ Clausthal, Inst Tech Chem, Arnold Sommerfeld Str 4, D-38678 Clausthal Zellerfeld, Germany. [Buback, Michael; Kattner, Hendrik] Univ Gottingen, Inst Phys Chem, Tech & Macromol Chem Grp, Tammannstr 6, D-37077 Gottingen, Germany. [Hutchinson, Robin A.] Queens Univ, Dept Chem Engn, Dupuis Hall, Kingston, ON K7L 3N6, Canada. [Junkers, Thomas] Univ Hasselt, Inst Mat Res, Polymer React Design Grp, Martelarenlaan 42, B-3500 Hasselt, Belgium. [Manders, Bart] BASF SE, EDG DD H503, D-67056 Ludwigshafen, Germany. [Nikitin, Anatoly N.] Russian Acad Sci, Branch Fed Sci Res Ctr Crystallog & Photon, Inst Laser & Informat Technol, Svyatoozerskaya 1, Shatura 140700, Moscow Region, Russia. [Russell, Gregory T.] Univ Canterbury, Dept Chem, Private Bag 4800, Christchurch 8140, New Zealand. [van Herk, Alex M.] Eindhoven Univ Technol, Dept Chem & Chem Engn, POB 513, NL-5600 MB Eindhoven, Netherlands.-
local.publisher.placeWEINHEIM-
local.type.refereedRefereed-
local.type.specifiedArticle-
local.bibliographicCitation.artnrUNSP 1600357-
dc.identifier.doi10.1002/macp.201600357-
dc.identifier.isi000393411000011-
item.fulltextWith Fulltext-
item.contributorBarner-Kowollik, Christopher-
item.contributorBeuermann, Sabine-
item.contributorBuback, Michael-
item.contributorHutchinson, Robin A.-
item.contributorJUNKERS, Tanja-
item.contributorKattner, Hendrik-
item.contributorManders, Bart-
item.contributorNikitin, Anatoly N.-
item.contributorRussell, Gregory T.-
item.contributorvan Herk, Alex M.-
item.fullcitationBarner-Kowollik, Christopher; Beuermann, Sabine; Buback, Michael; Hutchinson, Robin A.; JUNKERS, Tanja; Kattner, Hendrik; Manders, Bart; Nikitin, Anatoly N.; Russell, Gregory T. & van Herk, Alex M. (2017) Critically Evaluated Rate Coefficients in Radical Polymerization-8. Propagation Rate Coefficients for Vinyl Acetate in Bulk. In: MACROMOLECULAR CHEMISTRY AND PHYSICS, 218(1), p. 1-13 (Art N° UNSP 1600357).-
item.accessRightsRestricted Access-
item.validationecoom 2018-
crisitem.journal.issn1022-1352-
crisitem.journal.eissn1521-3935-
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