Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/23979
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dc.contributor.authorSAFARI, Momo-
dc.contributor.authorKwok, Chun Yuen-
dc.contributor.authorNazar, Linda F.-
dc.date.accessioned2017-07-14T14:41:00Z-
dc.date.available2017-07-14T14:41:00Z-
dc.date.issued2016-
dc.identifier.citationACS CENTRAL SCIENCE, 2(8), p. 560-568-
dc.identifier.issn2374-7943-
dc.identifier.urihttp://hdl.handle.net/1942/23979-
dc.description.abstractA comprehensive experimental and theoretical analysis of the isothermal transport of species for the two model ternary-electrolytes with LiTFSILi2S4/dioxolane (DOL)-dimethoxyethane (DME) and LiTFSI-Li2S6/DOL-DME formulations is presented. An unambiguous picture of the polysulfide’s mobility is set forth after a detailed investigation of the macroscopic transference number and diffusion coefficients. The new findings of incongruent diffusion for Li2S4 species and high significance of cross-term diffusion coefficients reformulate a fledgling view of the prevalent redox-shuttle phenomena. The practical implications of this complex mechanism are discussed in detail.-
dc.description.sponsorshipWe gratefully acknowledge the BASF International Scientific Network for Electrochemistry and Batteries for funding. L.F.N. thanks NSERC for a Canada Research Chair, and support via their Discovery Grants program. CYK also thanks the Government of Ontario for Ontario Graduate Scholarship.-
dc.language.isoen-
dc.rightsACS AuthorChoice - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.-
dc.titleTransport Properties of Polysulfide Species in Lithium-Sulfur Battery Electrolytes: Coupling of Experiment and Theory-
dc.typeJournal Contribution-
dc.identifier.epage568-
dc.identifier.issue8-
dc.identifier.spage560-
dc.identifier.volume2-
local.bibliographicCitation.jcatA1-
local.type.refereedRefereed-
local.type.specifiedArticle-
local.classdsPublValOverrule/author_version_not_expected-
dc.identifier.doi10.1021/acscentsci.6b00169-
dc.identifier.isi000384750300013-
dc.identifier.urlhttps://www.researchgate.net/publication/306461801_Transport_Properties_of_Polysulfide_Species_in_Lithium-Sulfur_Battery_Electrolytes_Coupling_of_Experiment_and_Theory-
item.validationecoom 2017-
item.contributorSAFARI, Momo-
item.contributorKwok, Chun Yuen-
item.contributorNazar, Linda F.-
item.accessRightsOpen Access-
item.fulltextWith Fulltext-
item.fullcitationSAFARI, Momo; Kwok, Chun Yuen & Nazar, Linda F. (2016) Transport Properties of Polysulfide Species in Lithium-Sulfur Battery Electrolytes: Coupling of Experiment and Theory. In: ACS CENTRAL SCIENCE, 2(8), p. 560-568.-
crisitem.journal.issn2374-7943-
crisitem.journal.eissn2374-7951-
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