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http://hdl.handle.net/1942/23979
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | SAFARI, Momo | - |
dc.contributor.author | Kwok, Chun Yuen | - |
dc.contributor.author | Nazar, Linda F. | - |
dc.date.accessioned | 2017-07-14T14:41:00Z | - |
dc.date.available | 2017-07-14T14:41:00Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | ACS CENTRAL SCIENCE, 2(8), p. 560-568 | - |
dc.identifier.issn | 2374-7943 | - |
dc.identifier.uri | http://hdl.handle.net/1942/23979 | - |
dc.description.abstract | A comprehensive experimental and theoretical analysis of the isothermal transport of species for the two model ternary-electrolytes with LiTFSILi2S4/dioxolane (DOL)-dimethoxyethane (DME) and LiTFSI-Li2S6/DOL-DME formulations is presented. An unambiguous picture of the polysulfide’s mobility is set forth after a detailed investigation of the macroscopic transference number and diffusion coefficients. The new findings of incongruent diffusion for Li2S4 species and high significance of cross-term diffusion coefficients reformulate a fledgling view of the prevalent redox-shuttle phenomena. The practical implications of this complex mechanism are discussed in detail. | - |
dc.description.sponsorship | We gratefully acknowledge the BASF International Scientific Network for Electrochemistry and Batteries for funding. L.F.N. thanks NSERC for a Canada Research Chair, and support via their Discovery Grants program. CYK also thanks the Government of Ontario for Ontario Graduate Scholarship. | - |
dc.language.iso | en | - |
dc.rights | ACS AuthorChoice - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. | - |
dc.title | Transport Properties of Polysulfide Species in Lithium-Sulfur Battery Electrolytes: Coupling of Experiment and Theory | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 568 | - |
dc.identifier.issue | 8 | - |
dc.identifier.spage | 560 | - |
dc.identifier.volume | 2 | - |
local.bibliographicCitation.jcat | A1 | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
local.class | dsPublValOverrule/author_version_not_expected | - |
dc.identifier.doi | 10.1021/acscentsci.6b00169 | - |
dc.identifier.isi | 000384750300013 | - |
dc.identifier.url | https://www.researchgate.net/publication/306461801_Transport_Properties_of_Polysulfide_Species_in_Lithium-Sulfur_Battery_Electrolytes_Coupling_of_Experiment_and_Theory | - |
item.validation | ecoom 2017 | - |
item.contributor | SAFARI, Momo | - |
item.contributor | Kwok, Chun Yuen | - |
item.contributor | Nazar, Linda F. | - |
item.accessRights | Open Access | - |
item.fulltext | With Fulltext | - |
item.fullcitation | SAFARI, Momo; Kwok, Chun Yuen & Nazar, Linda F. (2016) Transport Properties of Polysulfide Species in Lithium-Sulfur Battery Electrolytes: Coupling of Experiment and Theory. In: ACS CENTRAL SCIENCE, 2(8), p. 560-568. | - |
crisitem.journal.issn | 2374-7943 | - |
crisitem.journal.eissn | 2374-7951 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
acscentsci.6b00169.pdf | Published version | 1.88 MB | Adobe PDF | View/Open |
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