Copolymers of 3,4-ethylenedioxythiophene and of pyridine alternated with fluorene or phenylene units: Synthesis, optical properties, and devices

Abstract

We report the synthesis of four conjugated copolymers based on alkylated fluorene or phenylene units which band gap is tuned by the regular insertion of an electron-donating or electron-withdrawing unit, (3,4-ethylenedioxy)thiophene and pyridine, respectively. The (AB)(n) regular sequence is achieved by Suzuki polycondensation reactions. The characterization of the copolymers by size exclusion chromatography reveals chains lengths of about 20-30 repeat units (40-60 rings), leading to a good processability for potential optical applications. The 1:1 ratio between the two units improves the solubility of the material in common organic solvents, allowing for physicochemical characterizations. Raman and FT-IR experiments indicate that the electronic structure of the backbone is rather benzenic in the neutral (undoped) state, as opposed to a quinoic oxidized structure. All copolymers exhibit interesting electro-chromic properties as attested by cyclic voltammetry and UV-vis experiments. They reversibly switch among the entire visible spectra, which is of particular importance for display applications. Moreover, the EDOT-based copolymers strongly absorb in the NIR window (1200 nm up to 3000 nm) with some potential electrochromic applications related to this spectral window. Light-emitting diodes were fabricated using these copolymers as active layer. To improve hole and electron injection, the active layer was sandwiched between a ITO/PEDOT:PSSA/copolymer/Ba/Al. The emitting properties were studied on the base of photoluminescence (PL) and electroluminescence (EL) experiments. The spectral emission varies from blue-green to yellow, depending on the composition of the copolymers.