Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/2492
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dc.contributor.authorKESTERS, Els-
dc.contributor.authorde Kok, MM-
dc.contributor.authorCARLEER, Robert-
dc.contributor.authorCZECH, Jan-
dc.contributor.authorADRIAENSENS, Peter-
dc.contributor.authorGELAN, Jan-
dc.contributor.authorVANDERZANDE, Dirk-
dc.date.accessioned2007-11-15T08:08:24Z-
dc.date.available2007-11-15T08:08:24Z-
dc.date.issued2002-
dc.identifier.citationPOLYMER, 43(21). p. 5749-5755-
dc.identifier.issn0032-3861-
dc.identifier.urihttp://hdl.handle.net/1942/2492-
dc.description.abstractThe thermal elimination of the n-octyl-sulphonyl group from poly[1,4 phenylene (1-n-octyl-sulphonyl)-1,2-ethylene] and the phenyl-sulphonyl group from poly[1,4 phenylene (1-phenyl-sulphonyl)-1,2-ethylene] is evaluated by different analytical techniques: thermal gravimetric analysis, direct insert probe mass spectrometry, in situ ultraviolet-visible spectroscopy and in situ Fourier transform infra red spectroscopy. This thermal treatment yields PPV with improved optical properties compared to the conventional PPV concerning UV-absorption and photoluminescence efficiencies. The results obtained are consistent with the formation of a PPV with a more or less restricted conjugation length compared to the PPV material obtained from the conversion of a sulphinyl precursor polymer. (C) 2002 Published by Elsevier Science Ltd.-
dc.language.isoen-
dc.publisherELSEVIER SCI LTD-
dc.subject.otherpoly(para-xylylene); PPV; sulphonyl precursor polymers-
dc.titleThe thermal conversion reaction of sulphonyl substituted poly (para-xylylene): evidence for the formation of PPV structures-
dc.typeJournal Contribution-
dc.identifier.epage5755-
dc.identifier.issue21-
dc.identifier.spage5749-
dc.identifier.volume43-
local.format.pages7-
local.bibliographicCitation.jcatA1-
dc.description.notesLimburgs Univ Ctr, Div Chem, Inst Mat Res, B-3590 Diepenbeek, Belgium. Philips Res, NL-5656 AA Eindhoven, Netherlands.Vanderzande, DJ, Limburgs Univ Ctr, Div Chem, Inst Mat Res, Univ Campus,Gebouw D, B-3590 Diepenbeek, Belgium.-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1016/S0032-3861(02)00414-7-
dc.identifier.isi000178062400019-
item.fulltextNo Fulltext-
item.accessRightsClosed Access-
item.contributorKESTERS, Els-
item.contributorCARLEER, Robert-
item.contributorCZECH, Jan-
item.contributorGELAN, Jan-
item.contributorVANDERZANDE, Dirk-
item.contributorADRIAENSENS, Peter-
item.contributorde Kok, MM-
item.fullcitationKESTERS, Els; de Kok, MM; CARLEER, Robert; CZECH, Jan; ADRIAENSENS, Peter; GELAN, Jan & VANDERZANDE, Dirk (2002) The thermal conversion reaction of sulphonyl substituted poly (para-xylylene): evidence for the formation of PPV structures. In: POLYMER, 43(21). p. 5749-5755.-
item.validationecoom 2003-
crisitem.journal.issn0032-3861-
crisitem.journal.eissn1873-2291-
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