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http://hdl.handle.net/1942/2492
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DC Field | Value | Language |
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dc.contributor.author | KESTERS, Els | - |
dc.contributor.author | de Kok, MM | - |
dc.contributor.author | CARLEER, Robert | - |
dc.contributor.author | CZECH, Jan | - |
dc.contributor.author | ADRIAENSENS, Peter | - |
dc.contributor.author | GELAN, Jan | - |
dc.contributor.author | VANDERZANDE, Dirk | - |
dc.date.accessioned | 2007-11-15T08:08:24Z | - |
dc.date.available | 2007-11-15T08:08:24Z | - |
dc.date.issued | 2002 | - |
dc.identifier.citation | POLYMER, 43(21). p. 5749-5755 | - |
dc.identifier.issn | 0032-3861 | - |
dc.identifier.uri | http://hdl.handle.net/1942/2492 | - |
dc.description.abstract | The thermal elimination of the n-octyl-sulphonyl group from poly[1,4 phenylene (1-n-octyl-sulphonyl)-1,2-ethylene] and the phenyl-sulphonyl group from poly[1,4 phenylene (1-phenyl-sulphonyl)-1,2-ethylene] is evaluated by different analytical techniques: thermal gravimetric analysis, direct insert probe mass spectrometry, in situ ultraviolet-visible spectroscopy and in situ Fourier transform infra red spectroscopy. This thermal treatment yields PPV with improved optical properties compared to the conventional PPV concerning UV-absorption and photoluminescence efficiencies. The results obtained are consistent with the formation of a PPV with a more or less restricted conjugation length compared to the PPV material obtained from the conversion of a sulphinyl precursor polymer. (C) 2002 Published by Elsevier Science Ltd. | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCI LTD | - |
dc.subject.other | poly(para-xylylene); PPV; sulphonyl precursor polymers | - |
dc.title | The thermal conversion reaction of sulphonyl substituted poly (para-xylylene): evidence for the formation of PPV structures | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 5755 | - |
dc.identifier.issue | 21 | - |
dc.identifier.spage | 5749 | - |
dc.identifier.volume | 43 | - |
local.format.pages | 7 | - |
local.bibliographicCitation.jcat | A1 | - |
dc.description.notes | Limburgs Univ Ctr, Div Chem, Inst Mat Res, B-3590 Diepenbeek, Belgium. Philips Res, NL-5656 AA Eindhoven, Netherlands.Vanderzande, DJ, Limburgs Univ Ctr, Div Chem, Inst Mat Res, Univ Campus,Gebouw D, B-3590 Diepenbeek, Belgium. | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.bibliographicCitation.oldjcat | A1 | - |
dc.identifier.doi | 10.1016/S0032-3861(02)00414-7 | - |
dc.identifier.isi | 000178062400019 | - |
item.contributor | KESTERS, Els | - |
item.contributor | de Kok, MM | - |
item.contributor | CARLEER, Robert | - |
item.contributor | CZECH, Jan | - |
item.contributor | ADRIAENSENS, Peter | - |
item.contributor | GELAN, Jan | - |
item.contributor | VANDERZANDE, Dirk | - |
item.accessRights | Closed Access | - |
item.fullcitation | KESTERS, Els; de Kok, MM; CARLEER, Robert; CZECH, Jan; ADRIAENSENS, Peter; GELAN, Jan & VANDERZANDE, Dirk (2002) The thermal conversion reaction of sulphonyl substituted poly (para-xylylene): evidence for the formation of PPV structures. In: POLYMER, 43(21). p. 5749-5755. | - |
item.fulltext | No Fulltext | - |
item.validation | ecoom 2003 | - |
crisitem.journal.issn | 0032-3861 | - |
crisitem.journal.eissn | 1873-2291 | - |
Appears in Collections: | Research publications |
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