Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/25696
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dc.contributor.authorJOOS, Bjorn-
dc.contributor.authorVRANKEN, Thomas-
dc.contributor.authorMARCHAL, Wouter-
dc.contributor.authorSAFARI, Momo-
dc.contributor.authorVAN BAEL, Marlies-
dc.contributor.authorHARDY, An-
dc.date.accessioned2018-03-08T09:15:12Z-
dc.date.available2018-03-08T09:15:12Z-
dc.date.issued2018-
dc.identifier.citationCHEMISTRY OF MATERIALS, 30 (3), p. 655-662-
dc.identifier.issn0897-4756-
dc.identifier.urihttp://hdl.handle.net/1942/25696-
dc.description.abstractHere, we introduce deep eutectic solvent (DES)–silica composites as a promising candidate for solid composite electrolytes (SCEs). The proposed DES-based gel electrolytes, further referred to as eutectogels (ETGs), are characterized by high ionic conductivity (1.46 mS cm–1), thermal (up to 130 °C), and electrochemical stability (up to 4.8 V) and are chemically inert to solvents and water. These ETGs can be easily processed and potentially at lower costs compared to ionic-liquid-based composite electrolytes. The good prospects of ETGs for application in Li/Li-ion batteries are demonstrated by stable cycling of Li/ETG/LiFePO4 cells over 100 cycles at C/10.-
dc.description.sponsorshipB. Joos is a Ph.D. research fellow of the Research Foundation Flanders (FWO Vlaanderen). This project receives the support of the European Union, the European Regional Development Fund ERDF [project 936], Flanders Innovation & Entrepreneurship, and the Province of Limburg. The authors would like to thank Gilles Bonneux for the SEM measurements, Fulya Ulu for the TEM measurements, Dries De Sloovere for the FT-IR measurements, and Dr. Robert Carleer and the TANG group members for the many discussions, DSC, ICP-AES measurements, and Kjeldahl titrations. Furthermore, the authors would like to thank Dr. Vera Meynen, Karen Leyssens, and Romy Huysmans for performing and interpreting the nitrogen physisorption measurements.-
dc.language.isoen-
dc.subject.othersolid composite electrolytes; hybrid electrolytes; li-ion batteries; ionic liquids-
dc.titleEutectogels: A New Class of Solid Composite Electrolytes for Li/Li-Ion Batteries-
dc.typeJournal Contribution-
dc.identifier.epage662-
dc.identifier.issue3-
dc.identifier.spage655-
dc.identifier.volume30-
local.bibliographicCitation.jcatA1-
dc.description.notesJoos, B (reprint author), Hasselt Univ, UHasselt, Inst Mat Res IMO, Agoralaan, B-3590 Diepenbeek, Belgium. bjorn.joos@uhasselt.be-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1021/acs.chemmater.7b03736-
dc.identifier.isi000425840500015-
item.fulltextWith Fulltext-
item.contributorJOOS, Bjorn-
item.contributorVRANKEN, Thomas-
item.contributorMARCHAL, Wouter-
item.contributorSAFARI, Momo-
item.contributorVAN BAEL, Marlies-
item.contributorHARDY, An-
item.fullcitationJOOS, Bjorn; VRANKEN, Thomas; MARCHAL, Wouter; SAFARI, Momo; VAN BAEL, Marlies & HARDY, An (2018) Eutectogels: A New Class of Solid Composite Electrolytes for Li/Li-Ion Batteries. In: CHEMISTRY OF MATERIALS, 30 (3), p. 655-662.-
item.accessRightsOpen Access-
item.validationecoom 2019-
crisitem.journal.issn0897-4756-
crisitem.journal.eissn1520-5002-
Appears in Collections:Research publications
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