Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/2770
Full metadata record
DC FieldValueLanguage
dc.contributor.authorVANGENEUGDEN, Dirk-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorSalbeck, J-
dc.contributor.authorvan Hal, PA-
dc.contributor.authorJanssen, RAJ-
dc.contributor.authorHummelen, JC-
dc.contributor.authorBrabec, CJ-
dc.contributor.authorShaheen, SE-
dc.contributor.authorSariciftci, NS-
dc.date.accessioned2007-11-16T08:08:20Z-
dc.date.available2007-11-16T08:08:20Z-
dc.date.issued2001-
dc.identifier.citationJOURNAL OF PHYSICAL CHEMISTRY B, 105(45). p. 11106-11113-
dc.identifier.issn1089-5647-
dc.identifier.urihttp://hdl.handle.net/1942/2770-
dc.description.abstractThe synthesis of a poly(1,3-dithienylisothianaphthene) (PDTITN) derivative obtained via oxidative polymerization of 5,6-dichloro-1,2-bis(3'-dodecylthienyl)isothianaphthene is described. PDTITN exhibits a band gap of 1.80-1.85 eV. The redox properties of PDTITN were characterized using cyclic voltammetry and spectroelectrochemisty. Photoexcitation of PDTITN results in photoluminescence (PL) in the near-IR region and the formation of a triplet state. In the presence of a methanofullerene (PCBM) as an electron acceptor, PL and triplet formation of PDTITN are quenched. In photovoltaic devices using blends of the polymer with PCBM, the observed incident-photon-to-collected-electron efficiency (IPCE) up to 24% at 400 nm and the 3 orders of magnitude increase of short circuit current as compared to the polymer alone prove the photoactivity of the PDTITN/PCBM blend in the device.-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.titleSynthesis and characterization of a poly(1,3-dithienylisothianaphthene) derivative for bulk heterojunction photovoltaic cells-
dc.typeJournal Contribution-
dc.identifier.epage11113-
dc.identifier.issue45-
dc.identifier.spage11106-
dc.identifier.volume105-
local.format.pages8-
local.bibliographicCitation.jcatA1-
dc.description.notesEindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands. Univ Groningen, Stratingh Inst, NL-9747 AG Groningen, Netherlands. Univ Groningen, MSC, NL-9747 AG Groningen, Netherlands. Johannes Kepler Univ, Linz Inst Organ Solar Cells, LIOS, A-4040 Linz, Austria. Univ Limburg, Div Chem, Inst Mat Res, Lab Organ & Polymer Chem, B-3590 Diepenbeek, Belgium. Gerhard Mercator Univ, FB 6 Chem Geog Electrochem & Optoelect Mat, D-47048 Duisburg, Germany.Janssen, RAJ, Eindhoven Univ Technol, Lab Macromol & Organ Chem, POB 513, NL-5600 MB Eindhoven, Netherlands.-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1021/jp013073t-
dc.identifier.isi000172206300009-
item.fulltextNo Fulltext-
item.contributorVANGENEUGDEN, Dirk-
item.contributorVANDERZANDE, Dirk-
item.contributorSalbeck, J-
item.contributorvan Hal, PA-
item.contributorJanssen, RAJ-
item.contributorHummelen, JC-
item.contributorBrabec, CJ-
item.contributorShaheen, SE-
item.contributorSariciftci, NS-
item.fullcitationVANGENEUGDEN, Dirk; VANDERZANDE, Dirk; Salbeck, J; van Hal, PA; Janssen, RAJ; Hummelen, JC; Brabec, CJ; Shaheen, SE & Sariciftci, NS (2001) Synthesis and characterization of a poly(1,3-dithienylisothianaphthene) derivative for bulk heterojunction photovoltaic cells. In: JOURNAL OF PHYSICAL CHEMISTRY B, 105(45). p. 11106-11113.-
item.accessRightsClosed Access-
item.validationecoom 2002-
crisitem.journal.issn1089-5647-
Appears in Collections:Research publications
Show simple item record

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.