Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/28910
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dc.contributor.authorHAVEN, Joris-
dc.contributor.authorHendrikx, Matthew-
dc.contributor.authorJUNKERS, Tanja-
dc.contributor.authorLeenaers, Pieter J.-
dc.contributor.authorTsompanoglou, Theodora-
dc.contributor.authorBoyer, Cyrille-
dc.contributor.authorXu, Jiangtao-
dc.contributor.authorPostma, Almar-
dc.contributor.authorMoad, Graeme-
dc.date.accessioned2019-08-07T15:18:00Z-
dc.date.available2019-08-07T15:18:00Z-
dc.date.issued2018-
dc.identifier.citationMatyjaszewski, K Gao, H Sumerlin, BS Tsarevsky, NV (Ed.). REVERSIBLE DEACTIVATION RADICAL POLYMERIZATION, VOL 2: MECHANISMS AND SYNTHETIC METHODOLOGIES, AMER CHEMICAL SOC,p. 77-103-
dc.identifier.isbn9780841233232-
dc.identifier.issn0097-6156-
dc.identifier.urihttp://hdl.handle.net/1942/28910-
dc.description.abstractThis paper focuses on one of the next directions in the evolution of reversible addition-fragmentation (RAFT) polymerization, namely, progress towards the synthesis of discrete or uniform, sequence-defined (co)polymers. Following a brief review of RAFT-single unit monomer insertion (RAFT-SUMI), we describe recent developments in the field. We point to difficulties in achieving consecutive RAFT-SUMI and report two strategies for overcoming the issue of initiator-derived by-products. We show that the selection of RAFT agent is critical in selective RAFT-SUMI of N,N-dimethylacrylamide (DMAm) into a trithiocarbonate in aqueous solution. Finally we recount on the use of photoRAFT- or PET-RAFT-SUMI in the high yield synthesis of discrete oligomers comprising two or more consecutive SUMI steps.-
dc.description.sponsorshipResearch on thermally initiated SUMI was conducted by MH, PJL and TT while they were present at CSIRO under the industrial traineeship component of their Masters degrees at Eindhoven University of Technology. Research by BE was carried out as part of his PhD program at Hasselt University while on an exchange visit to CSIRO, which was in part funded under a CSIRO Newton-Turner Award provided to GM. We are grateful to Roger Mulder and Jo Cosgriff for assistance with NMR spectroscopy and to Ben Muir and Shaun Howard for assistance in designing and conducting the high throughput (Chemspeed (R)) experiments. PET-RAFT-SUMI experiments were largely conducted by JX, Changkui Fu and Sivaprakash Shanmugam (84) or Changkui Fu and Zixuan Huang (100) at CAMD UNSW under the supervision of CB as part of an informal collaboration also involving Craig Hawker (University of California Santa Barbara) and GM.-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.relation.ispartofseriesACS Symposium Series-
dc.rights2018 American Chemical Society-
dc.titleElements of RAFT Navigation-
dc.typeProceedings Paper-
local.bibliographicCitation.authorsMatyjaszewski, K Gao, H Sumerlin, BS Tsarevsky, NV-
local.bibliographicCitation.conferencedateAUG 20-24, 2017-
local.bibliographicCitation.conferencenameAmerican-Chemical-Society Symposium on Controlled Radical Polymerization / 254th ACS National Meeting-
local.bibliographicCitation.conferenceplaceWashington, DC-
dc.identifier.epage103-
dc.identifier.spage77-
dc.identifier.volume1284-
local.format.pages27-
local.bibliographicCitation.jcatC1-
dc.description.notes[Haven, Joris J.; Hendrikx, Matthew; Leenaers, Pieter J.; Tsompanoglou, Theodora; Postma, Almar; Moad, Graeme] CSIRO Mfg, Res Way, Clayton, Vic 3168, Australia. [Haven, Joris J.; Junkers, Tanja] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia. [Haven, Joris J.; Junkers, Tanja] Univ Hasselt, Inst Mat Res, B-3590 Diepenbeek, Belgium. [Hendrikx, Matthew; Leenaers, Pieter J.; Tsompanoglou, Theodora] Eindhoven Univ Technol, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands. [Boyer, Cyrille; Xu, Jiangtao] Univ NSW, Ctr Adv Macromol Design, Sch Chem Engn, Sydney, NSW 2052, Australia. [Boyer, Cyrille; Xu, Jiangtao] Univ NSW, Australian Ctr NanoMed, Sch Chem Engn, Sydney, NSW 2052, Australia.-
local.publisher.placeWASHINGTON-
local.type.refereedRefereed-
local.type.specifiedProceedings Paper-
dc.identifier.doi10.1021/bk-2018-1284.ch004-
dc.identifier.isi000456766500004-
local.bibliographicCitation.btitleREVERSIBLE DEACTIVATION RADICAL POLYMERIZATION, VOL 2: MECHANISMS AND SYNTHETIC METHODOLOGIES-
item.contributorHAVEN, Joris-
item.contributorHendrikx, Matthew-
item.contributorJUNKERS, Tanja-
item.contributorLeenaers, Pieter J.-
item.contributorTsompanoglou, Theodora-
item.contributorBoyer, Cyrille-
item.contributorXu, Jiangtao-
item.contributorPostma, Almar-
item.contributorMoad, Graeme-
item.validationecoom 2020-
item.fullcitationHAVEN, Joris; Hendrikx, Matthew; JUNKERS, Tanja; Leenaers, Pieter J.; Tsompanoglou, Theodora; Boyer, Cyrille; Xu, Jiangtao; Postma, Almar & Moad, Graeme (2018) Elements of RAFT Navigation. In: Matyjaszewski, K Gao, H Sumerlin, BS Tsarevsky, NV (Ed.). REVERSIBLE DEACTIVATION RADICAL POLYMERIZATION, VOL 2: MECHANISMS AND SYNTHETIC METHODOLOGIES, AMER CHEMICAL SOC,p. 77-103.-
item.accessRightsRestricted Access-
item.fulltextWith Fulltext-
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