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http://hdl.handle.net/1942/2899
Title: | Scope and limitations of a new highly selective synthesis of unsymmetrical monomers for the synthesis of precursors toward poly(arylenevinylene)s | Authors: | Van der Borght, M VANDERZANDE, Dirk ADRIAENSENS, Peter GELAN, Jan |
Issue Date: | 2000 | Publisher: | AMER CHEMICAL SOC | Source: | JOURNAL OF ORGANIC CHEMISTRY, 65(2). p. 284-289 | Abstract: | In our laboratory a precursor route to poly(p-phenylenevinylene) derivatives is developed in which unsymmetrically substituted p-xylene derivatives, possessing a benzylic sulfinylalkyl group, are used as monomers. Because of this unsymmetry, we were forced to investigate thoroughly the synthesis of these sulfoxides, as we start from symmetric and readily accessible molecules, namely, bis(halomethyl)-p-xylene derivatives. In a former publication, a new extremely effective route for the production of these unsymmetrically substituted sulfinyl monomers was presented. This paper expands upon these previously reported results. To examine the scope and limitations of this elegant route, this new method was applied to the synthesis of various derivatives not included in the initial work. | Notes: | Univ Limburg, Inst Mat Res, Div Chem, Lab Organ & Polymer Chem, B-3590 Diepenbeek, Belgium.Vanderzande, D, Univ Limburg, Inst Mat Res, Div Chem, Lab Organ & Polymer Chem, Univ Campus, B-3590 Diepenbeek, Belgium. | Document URI: | http://hdl.handle.net/1942/2899 | ISI #: | 000084905400002 | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2001 |
Appears in Collections: | Research publications |
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