Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/29086
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dc.contributor.authorRAMAKERS, Gijs-
dc.contributor.authorRUBENS, Maarten-
dc.contributor.authorKRIVCOV, Alexander-
dc.contributor.authorMöbius, Hildegard-
dc.contributor.authorTrouillet,Vanessa-
dc.contributor.authorWelle,Alexander-
dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2019-09-02T12:44:08Z-
dc.date.available2019-09-02T12:44:08Z-
dc.date.issued2019-
dc.identifier.citationJOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 57 (18), p. 2002-2007-
dc.identifier.issn0887-624X-
dc.identifier.urihttp://hdl.handle.net/1942/29086-
dc.description.abstractThe UV-induced and catalyst-free photoiniferter surface grafting using xanthate RAFT agents is studied. First, a novel silane containing a xanthate RAFT agent moiety is synthesized and successfully grafted onto a silicon wafer as confirmed by secondary ion mass spectrometry (SIMS). Next, using only methyl acrylate, solvent and UV light (365 nm) polymer brushes are grafted rapidly from the surface with film thicknesses up to 25 nm reached within half an hour. The obtained polymer films are thoroughly analyzed by X-ray photoelectron spectroscopy (XPS), ToF-SIMS, and AFM.-
dc.description.sponsorshipThe authors are grateful for funding from the Fonds Wetenschappelijk Onderzoek in the form of a project grant and an FWO-SB grant of M.R. Further support via the Karlsruhe Nano Micro Facility (KNMF) is kindly acknowledged. The K-Alpha+ instrument was financially supported by the Federal Ministry of Economics and Technology on the basis of a decision by the German Bundestag. The authors wish to thank Mrs. Emely Bopp (IFG, KIT) for performing some ToF-SIMS experiments.-
dc.language.isoen-
dc.publisherWILEY-
dc.rights2019 Wiley Periodicals, Inc-
dc.subject.otheriniferter-
dc.subject.otherphotoiniferter-
dc.subject.otherphotopolymerization-
dc.subject.otherpolymer brushes-
dc.subject.otherRAFT-
dc.subject.othersurface functionalization-
dc.subject.othersurface grafting-
dc.subject.otherUV-initiation-
dc.titlePhotoiniferter Surface Grafting of Poly(methyl acrylate) using Xanthates-
dc.typeJournal Contribution-
dc.identifier.epage2007-
dc.identifier.issue18-
dc.identifier.spage2002-
dc.identifier.volume57-
local.bibliographicCitation.jcatA1-
dc.description.notesJunkers, T (reprint author), Hasselt Univ, Inst Mat Res, Martelarenlaan 42, B-3500 Hasselt, Belgium. Monash Univ, Sch Chem, Polymer React Design Grp, Rainforest Walk 19, Clayton, Vic 3800, Australia. tanja.junkers@monash.edu-
local.publisher.place111 RIVER ST, HOBOKEN 07030-5774, NJ-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1002/pola.29405-
dc.identifier.isi000486314800018-
dc.identifier.urlhttps://onlinelibrary.wiley.com/doi/abs/10.1002/pola.29405-
dc.identifier.eissn1099-0518-
local.uhasselt.internationalyes-
item.fulltextWith Fulltext-
item.contributorRAMAKERS, Gijs-
item.contributorRUBENS, Maarten-
item.contributorKRIVCOV, Alexander-
item.contributorMöbius, Hildegard-
item.contributorTrouillet,Vanessa-
item.contributorWelle,Alexander-
item.contributorJUNKERS, Tanja-
item.fullcitationRAMAKERS, Gijs; RUBENS, Maarten; KRIVCOV, Alexander; Möbius, Hildegard; Trouillet,Vanessa; Welle,Alexander & JUNKERS, Tanja (2019) Photoiniferter Surface Grafting of Poly(methyl acrylate) using Xanthates. In: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 57 (18), p. 2002-2007.-
item.accessRightsRestricted Access-
crisitem.journal.issn0887-624X-
crisitem.journal.eissn1099-0518-
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