Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/29087
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dc.contributor.authorZAQUEN, Neomy-
dc.contributor.authorHAVEN, Joris-
dc.contributor.authorRUBENS, Maarten-
dc.contributor.authorAltintas, Ozcan-
dc.contributor.authorBohländer, Peggy-
dc.contributor.authorOffenloch, Janin T.-
dc.contributor.authorBarner‐Kowollik, Christopher-
dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2019-09-02T12:58:05Z-
dc.date.available2019-09-02T12:58:05Z-
dc.date.issued2019-
dc.identifier.citationCHEMPHOTOCHEM,-
dc.identifier.issn2367-0932-
dc.identifier.urihttp://hdl.handle.net/1942/29087-
dc.description.abstractFlowreactorsbecomemoreand moreautomatedby enablingon-linereactionmonitoringand adjustingthe processparame-ters. On-linemonitoringof chemicalprocessesis a valuabletoolto steerprocesses,leadingto preciseengineeringof macro-molecularmaterials.Detailedinformationaboutspecificprod-uct patterns,end-groupfunctionalityor materialcompositioncan be obtainedby couplinga flowreactorto a massspectrometer(e.g. ESI-MS).In this work,we studythe depro-tectionof maleimidesand its subsequentphotoenolfunctional-izationto synthesizecomplexmacromoleculesusinga photoflow reactorcoupledto an ESI-MS.Usinga trappingagent(TA),furanis efficientlyremovedfromthe maleimideDielsAlderadductwithinjustminutesat 175°C andquantitativelyconvertedinto an unreactivespeciesthat doesnot interferewith furtherreactionsof the maleimide.The photoenolreactionwaslikewiseshownto be highlyeffectiveto proceedinmicroreactors,reachingquantitativeconversionof trifunctionalmoleculesin as little as 2 min-
dc.description.sponsorshipN.Z. acknowledges the European Union Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No 665501 with the research Foundation Flanders (FWO). C.B.-K. acknowledges the Australian Research Council (ARC) for a Laureate Fellowship enabling his photochemical research program, as well as the Queensland University of Technology (QUT) for continued financial support.-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.rights2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhei-
dc.subject.othercontinuous flow reactors-
dc.subject.otherDiels-Alder reactions-
dc.subject.othermass spectrometry-
dc.subject.otheron-line monitoring-
dc.subject.otherphotopolymerisation-
dc.titleExploring the Photochemical Reactivity of Multifunctional Photocaged Dienes in Continuous Flow-
dc.typeJournal Contribution-
dc.identifier.epage1152-
dc.identifier.issue11-
dc.identifier.spage1146-
dc.identifier.volume3-
local.bibliographicCitation.jcatA1-
dc.description.notesJunkers, T (reprint author), Univ Hasselt, OBPC, Agoralaan Bldg D, B-3590 Diepenbeek, Belgium, Monash Univ, Sch Chem, Polymer React Design Grp, 19 Rainforest Walk, Clayton, Vic 3800, Australia, Queensland Univ Technol, Sch Chem Phys & Mech Engn, 2 George St, Brisbane, Qld 4000, Australia, Karlsruhe Inst Technol, Inst Tech & Polymerchem, Macromol Architectures, Engesserstr 18, D-76128 Karlsruhe, Germany. christopher.barnerkowollik@qut.edu.au; tanja.junkers@monash.edu-
local.publisher.placePOSTFACH 101161, 69451 WEINHEIM, GERMANY-
local.type.refereedRefereed-
local.type.specifiedArticle-
local.type.programmeH2020-
local.relation.h2020665501-
dc.identifier.doi10.1002/cptc.201900142-
dc.identifier.isi000481011100001-
dc.identifier.urlhttps://onlinelibrary.wiley.com/doi/abs/10.1002/cptc.201900142-
dc.identifier.eissn2367-0932-
local.provider.typePdf-
local.uhasselt.internationalyes-
item.contributorZAQUEN, Neomy-
item.contributorHAVEN, Joris-
item.contributorRUBENS, Maarten-
item.contributorAltintas, Ozcan-
item.contributorBohländer, Peggy-
item.contributorOffenloch, Janin T.-
item.contributorBarner‐Kowollik, Christopher-
item.contributorJUNKERS, Tanja-
item.accessRightsRestricted Access-
item.fullcitationZAQUEN, Neomy; HAVEN, Joris; RUBENS, Maarten; Altintas, Ozcan; Bohländer, Peggy; Offenloch, Janin T.; Barner‐Kowollik, Christopher & JUNKERS, Tanja (2019) Exploring the Photochemical Reactivity of Multifunctional Photocaged Dienes in Continuous Flow. In: CHEMPHOTOCHEM,.-
item.fulltextWith Fulltext-
crisitem.journal.issn2367-0932-
crisitem.journal.eissn2367-0932-
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