Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/2913
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dc.contributor.authorLUTSEN, Laurence-
dc.contributor.authorvan Breemen, AJ-
dc.contributor.authorKreuder, W-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorGELAN, Jan-
dc.date.accessioned2007-11-20T12:53:01Z-
dc.date.available2007-11-20T12:53:01Z-
dc.date.issued2000-
dc.identifier.citationHELVETICA CHIMICA ACTA, 83(12). p. 3113-3121-
dc.identifier.issn0018-019X-
dc.identifier.urihttp://hdl.handle.net/1942/2913-
dc.description.abstractA new and convenient route to an unsymmetrically substituted sulfinyl monomer of precursor polymer toward poly[2-methyl-5-(3,7-dimethyloctyloxy)-p-phenylenevinyline] (OC1C10) is described. OC1C10 is a commercial polymer used as the active layer in LEDs. Therefore, the optimization of the reaction conditions of the monomer synthesis was of some importance for a possible commercialization of this new process. It was possible to increase the overall yield by a factor of 1.5, as compared to the route previously used to obtain these compounds.-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleHighly selective route to unsymmetrically substituted 1-{2-[(butylsulfanyl)methyl]-5-(chloromethyl)-4-methoxyphenoxy}-3,7-dime thyloctane and isomers toward synthesis of conjugated polymer OC1C10 used in LEDs: Synthesis and optimization-
dc.typeJournal Contribution-
dc.identifier.epage3121-
dc.identifier.issue12-
dc.identifier.spage3113-
dc.identifier.volume83-
local.format.pages9-
local.bibliographicCitation.jcatA1-
dc.description.notesLimburgs Univ Ctr, Mat Res Inst, Div Chem, Lab Organ & Polymer Chem, B-3590 Diepenbeek, Belgium. Covion Organ Semicond GMBH, D-65926 Frankfurt, Germany.Vanderzande, DJM, Limburgs Univ Ctr, Mat Res Inst, Div Chem, Lab Organ & Polymer Chem, Univ Campus, B-3590 Diepenbeek, Belgium.-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.isi000166311000003-
item.fulltextNo Fulltext-
item.fullcitationLUTSEN, Laurence; van Breemen, AJ; Kreuder, W; VANDERZANDE, Dirk & GELAN, Jan (2000) Highly selective route to unsymmetrically substituted 1-{2-[(butylsulfanyl)methyl]-5-(chloromethyl)-4-methoxyphenoxy}-3,7-dime thyloctane and isomers toward synthesis of conjugated polymer OC1C10 used in LEDs: Synthesis and optimization. In: HELVETICA CHIMICA ACTA, 83(12). p. 3113-3121.-
item.accessRightsClosed Access-
item.contributorKreuder, W-
item.contributorvan Breemen, AJ-
item.contributorLUTSEN, Laurence-
item.contributorVANDERZANDE, Dirk-
item.contributorGELAN, Jan-
item.validationecoom 2002-
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