Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/2919
Title: The synthesis of poly(4,4 '-biphenylene vinylene) and poly(2,6-naphthalene vinylene) via a radical chain polymerisation
Authors: Van der Borght, M
ADRIAENSENS, Peter 
VANDERZANDE, Dirk 
GELAN, Jan 
Issue Date: 2000
Publisher: ELSEVIER SCI LTD
Source: POLYMER, 41(8). p. 2743-2753
Abstract: Chain polymerisations used for the synthesis of poly(arylene vinylene)s have in common that they proceed via a quinoid compound. The formation of this compound is a high-energy step that involves the loss of the aromatic resonance energy of the monomer and hence must be compensated by a driving force. In order to comprehend this driving force monomers with a growing aromatic resonance energy an polymerised via the sulphinyl precursor route described. Next the conversion of the synthesised polymers to their corresponding conjugated polymer is followed with different techniques and the u.v.- vis, absorbance and photoluminescence spectra are determined. (C) 2000 Elsevier Science Ltd. All rights reserved.
Notes: Univ Limburg, Lab Organ & Polymer Chem, Mat Res Inst, Div Chem, B-3590 Diepenbeek, Belgium.Vanderzande, D, Univ Limburg, Lab Organ & Polymer Chem, Mat Res Inst, Div Chem, Univ Campus, B-3590 Diepenbeek, Belgium.
Keywords: poly(arylene vinylene)s; driving force; blue-green photoluminescence
Document URI: http://hdl.handle.net/1942/2919
DOI: 10.1016/S0032-3861(99)00486-3
ISI #: 000084839900004
Category: A1
Type: Journal Contribution
Validations: ecoom 2001
Appears in Collections:Research publications

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