Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3016
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dc.contributor.authorHONTIS, Lieve-
dc.contributor.authorVan der Borght, M-
dc.contributor.authorVANDERZANDE, Dirk-
dc.contributor.authorGELAN, Jan-
dc.date.accessioned2007-11-23T13:05:42Z-
dc.date.available2007-11-23T13:05:42Z-
dc.date.issued1999-
dc.identifier.citationPOLYMER, 40(23). p. 6615-6617-
dc.identifier.issn0032-3861-
dc.identifier.urihttp://hdl.handle.net/1942/3016-
dc.description.abstractExperiments have been performed to clarify the polymerisation mechanism of chloromethyl-4-(n-butylsulfinyl)methylbenzene 1a and 4-chloromethyl-4'-(n-butylsuIfinyl)methylbiphenyl Ib in NMP. Addition of TEMPO and water to the polymerisation mixture led to the conclusion that radical as well as anionic mechanisms occur which lead to the formation of a high and a low molecular weight polymer fraction, respectively. (C) 1999 Elsevier Science Ltd. All rights reserved.-
dc.language.isoen-
dc.publisherELSEVIER SCI LTD-
dc.subject.otherpolymerisation mechanism; p-quinodimethane systems; poly(p-arylene vinylene) precursors-
dc.titleRadical as well as anionic polymerisation mechanisms in the synthesis of poly(p-arylene vinylene) precursors-
dc.typeJournal Contribution-
dc.identifier.epage6617-
dc.identifier.issue23-
dc.identifier.spage6615-
dc.identifier.volume40-
local.format.pages3-
dc.description.notesLimburgs Univ Ctr, Lab Organ & Polymer Chem, Div Chem, B-3590 Diepenbeek, Belgium.Vanderzande, D, Limburgs Univ Ctr, Lab Organ & Polymer Chem, Div Chem, Univ Campus, B-3590 Diepenbeek, Belgium.-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.doi10.1016/S0032-3861(99)00242-6-
dc.identifier.isi000082132800041-
item.accessRightsClosed Access-
item.fulltextNo Fulltext-
item.validationecoom 2000-
item.contributorHONTIS, Lieve-
item.contributorVan der Borght, M-
item.contributorVANDERZANDE, Dirk-
item.contributorGELAN, Jan-
item.fullcitationHONTIS, Lieve; Van der Borght, M; VANDERZANDE, Dirk & GELAN, Jan (1999) Radical as well as anionic polymerisation mechanisms in the synthesis of poly(p-arylene vinylene) precursors. In: POLYMER, 40(23). p. 6615-6617.-
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