Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/3024
Full metadata record
DC FieldValueLanguage
dc.contributor.authorGUEDENS, Wanda-
dc.contributor.authorYPERMAN, Jan-
dc.contributor.authorMULLENS, Jules-
dc.contributor.authorVAN POUCKE, Lucien-
dc.date.accessioned2007-11-23T13:17:00Z-
dc.date.available2007-11-23T13:17:00Z-
dc.date.issued1999-
dc.identifier.citationJOURNAL OF COORDINATION CHEMISTRY, 47(1). p. 17-29-
dc.identifier.issn0095-8972-
dc.identifier.urihttp://hdl.handle.net/1942/3024-
dc.description.abstractBy means of potenriometric pH measurements, the acidity constants of 1,4-diaminobutane and 1,5-diaminopentane have been determined in 1.0 M KNO3 at 25.0 degrees C. Combined pH/pAg data were used at the same temperature in aqueous 1.0 M KNO3 to study the complexation of Ag(I) with the diamines. Protonated and non-protonated mononuclear and polynuclear complexes were detected. No evidence was found for the existence of hydroxo complexes. The resulting overall stability constants have been compared with previously determined stability constants for Ag(I)-ethylenediamine and Ag(I)-1,3-propylenediamine complexes. Some relationships concerning the length of the CH2 backbone have been identified.-
dc.language.isoen-
dc.publisherGORDON BREACH SCI PUBL LTD-
dc.subject.otheraliphatic diamines; silver; stability constants-
dc.titleSilver(I) complex formation with 1,4-diaminobutane and 1,5-diaminopentane: A potentiometric study in 1.0 m KNO3-
dc.typeJournal Contribution-
dc.identifier.epage29-
dc.identifier.issue1-
dc.identifier.spage17-
dc.identifier.volume47-
local.format.pages13-
dc.description.notesLimburgs Univ Ctr, Dept SBM, B-3590 Diepenbeek, Belgium. Limburgs Univ Ctr, Lab Inorgan & Phys Chem, B-3590 Diepenbeek, Belgium.Van Poucke, LC, Limburgs Univ Ctr, Dept SBM, Univ Campus Gebaw D, B-3590 Diepenbeek, Belgium.-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.bibliographicCitation.oldjcatA1-
dc.identifier.isi000080167300002-
item.fulltextNo Fulltext-
item.accessRightsClosed Access-
item.contributorGUEDENS, Wanda-
item.contributorYPERMAN, Jan-
item.contributorVAN POUCKE, Lucien-
item.contributorMULLENS, Jules-
item.fullcitationGUEDENS, Wanda; YPERMAN, Jan; MULLENS, Jules & VAN POUCKE, Lucien (1999) Silver(I) complex formation with 1,4-diaminobutane and 1,5-diaminopentane: A potentiometric study in 1.0 m KNO3. In: JOURNAL OF COORDINATION CHEMISTRY, 47(1). p. 17-29.-
item.validationecoom 2000-
Appears in Collections:Research publications
Show simple item record

WEB OF SCIENCETM
Citations

1
checked on Jul 1, 2022

Page view(s)

8
checked on Jun 30, 2022

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.