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http://hdl.handle.net/1942/30351
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DC Field | Value | Language |
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dc.contributor.author | VAN LANDEGHEM, Melissa | - |
dc.contributor.author | KUDRJASOVA, Julija | - |
dc.contributor.author | MAES, Wouter | - |
dc.contributor.author | Goovaerts, Etienne | - |
dc.contributor.author | VAN DOORSLAER, Sabine | - |
dc.date.accessioned | 2020-01-21T13:25:14Z | - |
dc.date.available | 2020-01-21T13:25:14Z | - |
dc.date.issued | 2019 | - |
dc.date.submitted | 2020-01-21T11:44:56Z | - |
dc.identifier.citation | APPLIED MAGNETIC RESONANCE, 50 (11) , p. 1253 -1265 | - |
dc.identifier.issn | 0937-9347 | - |
dc.identifier.uri | http://hdl.handle.net/1942/30351 | - |
dc.description.abstract | Functionalized 2,5-dithienylthiazolo[5,4-d]thiazole (DTTzTz) derivatives have attracted interest towards application as non-fullerene acceptors in solution-processed organic solar cells. Here, we present a combined high-field electron paramagnetic resonance and density functional theory study of the light-induced negative polaron on the novel acceptor 2,4-diCN-Ph-DTTzTz formed after charge transfer in bulk heterojunction blends with a donor polymer. Despite spectral overlap with the polymer cation, the g-anisotropy of the acceptor radical could be directly confirmed through detection of its unique N-14 hyperfine couplings using electron-electron double resonance (ELDOR)-detected nuclear magnetic resonance (EDNMR) for spectral filtering. The spectral assignment is further underpinned by quantum-chemical calculations, which also provide detailed information about the spin density and charge distribution of the polaron in the DTTzTz acceptor. | - |
dc.language.iso | en | - |
dc.publisher | SPRINGER WIEN | - |
dc.title | EPR Characterization of the Light-Induced Negative Polaron in a Functionalized Dithienylthiazolo[5,4-d]thiazole Acceptor for Organic Photovoltaics | - |
dc.type | Journal Contribution | - |
dc.identifier.epage | 1265 | - |
dc.identifier.issue | 11 | - |
dc.identifier.spage | 1253 | - |
dc.identifier.volume | 50 | - |
local.bibliographicCitation.jcat | A1 | - |
local.publisher.place | SACHSENPLATZ 4-6, PO BOX 89, A-1201 WIEN, AUSTRIA | - |
local.type.refereed | Refereed | - |
local.type.specified | Article | - |
dc.source.type | Article | - |
dc.identifier.doi | 10.1007/s00723-019-01146-4 | - |
dc.identifier.isi | WOS:000491493500002 | - |
dc.identifier.eissn | - | |
local.provider.type | Web of Science | - |
local.uhasselt.uhpub | yes | - |
item.fulltext | With Fulltext | - |
item.contributor | VAN LANDEGHEM, Melissa | - |
item.contributor | KUDRJASOVA, Julija | - |
item.contributor | MAES, Wouter | - |
item.contributor | Goovaerts, Etienne | - |
item.contributor | VAN DOORSLAER, Sabine | - |
item.validation | ecoom 2020 | - |
item.fullcitation | VAN LANDEGHEM, Melissa; KUDRJASOVA, Julija; MAES, Wouter; Goovaerts, Etienne & VAN DOORSLAER, Sabine (2019) EPR Characterization of the Light-Induced Negative Polaron in a Functionalized Dithienylthiazolo[5,4-d]thiazole Acceptor for Organic Photovoltaics. In: APPLIED MAGNETIC RESONANCE, 50 (11) , p. 1253 -1265. | - |
item.accessRights | Open Access | - |
crisitem.journal.issn | 0937-9347 | - |
crisitem.journal.eissn | 1613-7507 | - |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
ApplMagRes_diCN_final.pdf | Peer-reviewed author version | 1.11 MB | Adobe PDF | View/Open |
VanLandeghem2019_Article_EPRCharacterizationOfTheLight-.pdf Restricted Access | Published version | 1.11 MB | Adobe PDF | View/Open Request a copy |
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