Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/31686
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dc.contributor.authorJOOS, Bjorn-
dc.contributor.authorVOLDERS, Jordi-
dc.contributor.authorda Cruz, RR-
dc.contributor.authorBAETEN, Evelien-
dc.contributor.authorSAFARI, Momo-
dc.contributor.authorVAN BAEL, Marlies-
dc.contributor.authorHARDY, An-
dc.date.accessioned2020-08-12T09:28:19Z-
dc.date.available2020-08-12T09:28:19Z-
dc.date.issued2020-
dc.date.submitted2020-07-28T13:27:34Z-
dc.identifier.citationCHEMISTRY OF MATERIALS, 32 (9) , p. 3783 -3793-
dc.identifier.urihttp://hdl.handle.net/1942/31686-
dc.description.abstractThis work introduces the polymeric eutectogel (P-ETG) solid composite electrolytes (SCEs) developed from the encapsulation of a liquid deep eutectic solvent (DES) electrolyte within a solid amide-based polymer backbone. Compared to their silica-based eutectogel counterparts, the P-ETGs can be efficiently processed by means of UV curing from liquid precursors and possess superior mechanical flexibility. The P-ETGs are characterized by a good electrochemical stability (up to 4.5 V vs Li) and high ionic conductivity up to 0.78 mS cm(-1). The potentiality of P-ETG for application in Li/Li-ion batteries is substantiated by stable cycling results of Li/P-ETG/LiFePO4 cells over 100 cycles at C/5 to 1C rates. The fire-hazards analysis reveals the improved safety of P-ETGs in contrast to the conventional liquid electrolytes (1 M LiPF6 in EC/DEC).-
dc.description.sponsorshipB.J. was a Ph.D. research fellow of the Research Foundation Flanders (FWO Vlaanderen) for the duration of the conducted research and now a researcher at Hasselt University. This project receives the support of the European Union, the European Regional Development Fund ERDF [project 936], Flanders Innovation & Entrepreneurship, and the Province of Limburg. The authors thank A. Kelchtermans for help with the flammability tests, W. Maes for the use of the N2 glovebox and (ATR-)FT-IR setup, and W. Marchal, P. Samyn, and R. Carleer and group members for the many discussions on the (ATR-)FT-IR and TGA measurements.-
dc.language.isoen-
dc.publisherAMER CHEMICAL SOC-
dc.rights© 2020 American Chemical Society-
dc.subject.otherDeep Eutectic Solvents-
dc.subject.otherLi Ion Conductors-
dc.subject.otherN-Methylacetamide-
dc.subject.otherComposite Electrolytes-
dc.subject.otherLithium Salt-
dc.subject.otherLiquid-
dc.subject.otherTemperature-
dc.subject.otherBatteries-
dc.subject.otherIonogels-
dc.subject.otherLitfsi-
dc.titlePolymeric Backbone Eutectogels as a New Generation of Hybrid Solid-State Electrolytes-
dc.typeJournal Contribution-
dc.identifier.epage3793-
dc.identifier.issue9-
dc.identifier.spage3783-
dc.identifier.volume32-
local.bibliographicCitation.jcatA1-
dc.description.notesJoos, B; Hardy, AT (corresponding author), Hasselt Univ, B-3500 Hasselt, Belgium.-
dc.description.notesbjorn.joos@uhasselt.be; an.hardy@uhasselt.be-
dc.description.otherJoos, B; Hardy, AT (corresponding author), Hasselt Univ, B-3500 Hasselt, Belgium. bjorn.joos@uhasselt.be; an.hardy@uhasselt.be-
local.publisher.place1155 16TH ST, NW, WASHINGTON, DC 20036 USA-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.source.typeArticle-
dc.identifier.doi10.1021/acs.chemmater.9b05090-
dc.identifier.isiWOS:000535241800013-
local.provider.typewosris-
local.uhasselt.uhpubyes-
local.description.affiliation[Joos, Bjorn; Volders, Jordi; da Cruz, Ricardo Ribeiro; Safari, Mohammadhosein; Van Bael, Marlies K.; Hardy, An T.] Hasselt Univ, B-3500 Hasselt, Belgium.-
local.description.affiliation[Baeten, Evelien] Zuyd Univ Appl Sci, NL-6419 DJ Heerlen, Netherlands.-
local.uhasselt.internationalyes-
item.contributorJOOS, Bjorn-
item.contributorVOLDERS, Jordi-
item.contributorda Cruz, RR-
item.contributorBAETEN, Evelien-
item.contributorSAFARI, Momo-
item.contributorVAN BAEL, Marlies-
item.contributorHARDY, An-
item.fullcitationJOOS, Bjorn; VOLDERS, Jordi; da Cruz, RR; BAETEN, Evelien; SAFARI, Momo; VAN BAEL, Marlies & HARDY, An (2020) Polymeric Backbone Eutectogels as a New Generation of Hybrid Solid-State Electrolytes. In: CHEMISTRY OF MATERIALS, 32 (9) , p. 3783 -3793.-
item.validationecoom 2021-
item.fulltextWith Fulltext-
item.accessRightsRestricted Access-
crisitem.journal.issn0897-4756-
crisitem.journal.eissn1520-5002-
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