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Title: | Corrole basicity in the excited states: Insights on structure-property relationships | Authors: | Kruk, Mikalai M. Klenitsky, Dmitry, V Gladkov, Lev L. MAES, Wouter |
Issue Date: | 2020 | Publisher: | WORLD SCI PUBL CO INC | Source: | JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 24 (5-7) , p. 765 -774 | Abstract: | Steady-state fluorescence measurements and quantum-chemical DFT geometry optimizations are applied to extend the structure-property relationships between the free-base corrole macrocycle conformation and its basicity to the lowest excited S-1 and T-1 states. Direct basicity estimation in the lowest excited S-1 state is demonstrated by means of fluorescence quantum yield measurements. The long wavelength T1 tautomer is found to retain its basicity in the S(1 )state, whereas the short wavelength T2 tautomer shows a noticeable decrease in basicity in the S-1 state, which is related to the in-plane tilting of the pyrrole ring to be protonated. The conformational changes upon going from the ground to the lowest excited T-1 state and the influence of the meso-aryl substitution pattern on the overall degree of distortions and tilting of the pyrrole ring to be protonated are also discussed from the point of view of macrocycle basicity. | Notes: | Maes, W (corresponding author), Hasselt Univ, Inst Mat Res IMO IMOMEC, Agoralaan 1, B-3590 Diepenbeek, Belgium.; Kruk, MM (corresponding author), Belarusian State Technol Univ, Phys Dept, Sverdlov Str 13a, Minsk 220006, BELARUS. krukmikalai@yahoo.com; wouter.maes@uhasselt.be |
Other: | Maes, W (corresponding author), Hasselt Univ, Inst Mat Res IMO IMOMEC, Agoralaan 1, B-3590 Diepenbeek, Belgium. Kruk, MM (corresponding author), Belarusian State Technol Univ, Phys Dept, Sverdlov Str 13a, Minsk 220006, BELARUS. krukmikalai@yahoo.com; wouter.maes@uhasselt.be | Keywords: | free-base corroles;NH tautomers;basicity;excited states;fluorescence;macrocycle distortions;pyrrole tilting | Document URI: | http://hdl.handle.net/1942/31795 | ISSN: | 1088-4246 | e-ISSN: | 1099-1409 | DOI: | 10.1142/S1088424619501797 | ISI #: | WOS:000536144800017 | Rights: | 2020 World Scientific Publishing Co Pte Ltd. | Category: | A1 | Type: | Journal Contribution | Validations: | ecoom 2021 |
Appears in Collections: | Research publications |
Files in This Item:
File | Description | Size | Format | |
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Kruk, JPP 2020, 765.pdf Restricted Access | Published version | 687.9 kB | Adobe PDF | View/Open Request a copy |
Maes and Kruk_manrevised.pdf | Peer-reviewed author version | 1.1 MB | Adobe PDF | View/Open |
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