Please use this identifier to cite or link to this item: http://hdl.handle.net/1942/31845
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dc.contributor.authorVRIJSEN, Jeroen-
dc.contributor.authorThomlinson, Isabel A.-
dc.contributor.authorLevere, Martin E.-
dc.contributor.authorLyall, Catherine L.-
dc.contributor.authorDavidson, Matthew G.-
dc.contributor.authorHintermair, Ulrich-
dc.contributor.authorJUNKERS, Tanja-
dc.date.accessioned2020-08-26T11:55:51Z-
dc.date.available2020-08-26T11:55:51Z-
dc.date.issued2020-
dc.date.submitted2020-08-18T09:56:39Z-
dc.identifier.citationPOLYMER CHEMISTRY, 11 (21) , p. 3546 -3550-
dc.identifier.urihttp://hdl.handle.net/1942/31845-
dc.description.abstractHigh-resolution FlowNMR was coupled to a continuous flow reactor to monitor polymer molecular weight evolution online by diffusion ordered NMR spectroscopy. Polymers were synthesized by reversible addition fragmentation chain transfer polymerization in continuous flow. The setup allows to target various polymer chain lengths in a dynamic manner without requiring additional purification or sample preparation. Obtaining molecular weight information in this manner is shown to be more accurate than classical SEC analysis at comparable measurement times, with relative errors around 5%.-
dc.description.sponsorshipThe authors are grateful to the Fonds Wetenschappelijk Onderzoek (FWO) for providing a SB scholarship for JHV, the Royal Society for a University Research Fellowship to UH (UF160458), and EPSRC for funding the Dynamic Reaction Monitoring Facility at the University of Bath (EP/P001475/1) and for the EPSRC Centre for Doctoral Training in Sustainable Chemical Technologies (EP/L016354/1, PhD studentship for IAT). We thank Joris Haven (Monash University), Maciek Kopec and John Lowe (University of Bath) for stimulating discussions.-
dc.language.isoen-
dc.publisherROYAL SOC CHEMISTRY-
dc.rightsOpen Access Article. Published on 06 May 2020. Downloaded on 8/26/2020 12:53:20 PM. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.-
dc.subject.otherSize-Exclusion Chromatography-
dc.subject.otherRing-Opening Polymerization-
dc.subject.otherEvaluated Rate Coefficients-
dc.subject.otherMolar Masses-
dc.subject.otherDosy-
dc.subject.otherTermination-
dc.subject.otherPolymers-
dc.subject.otherAcrylate-
dc.subject.otherErrors-
dc.subject.otherRaft-
dc.titleOnline tracing of molecular weight evolution during radical polymerization via high-resolution FlowNMR spectroscopy-
dc.typeJournal Contribution-
dc.identifier.epage3550-
dc.identifier.issue21-
dc.identifier.spage3546-
dc.identifier.volume11-
local.format.pages5-
local.bibliographicCitation.jcatA1-
dc.description.notesJunkers, T (corresponding author), Hasselt Univ, Martelarenlaan 42, B-3500 Hasselt, Belgium.; Junkers, T (corresponding author), Monash Univ, Sch Chem, Polymer React Design Grp, 19 Rainforest Walk,Bldg 23, Clayton, Vic 3800, Australia.; Hintermair, U (corresponding author), Univ Bath, Ctr Sustainable & Circular Technol, Bath BA2 7AY, Avon, England.; Hintermair, U (corresponding author), Univ Bath, Dynam React Monitoring Facil, Bath BA2 7AY, Avon, England.-
dc.description.notesu.hintermair@bath.ac.uk; tanja.junkers@monash.edu-
dc.description.otherJunkers, T (corresponding author), Hasselt Univ, Martelarenlaan 42, B-3500 Hasselt, Belgium; Monash Univ, Sch Chem, Polymer React Design Grp, 19 Rainforest Walk,Bldg 23, Clayton, Vic 3800, Australia. u.hintermair@bath.ac.uk; tanja.junkers@monash.edu-
local.publisher.placeTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS,-
local.publisher.placeENGLAND-
local.type.refereedRefereed-
local.type.specifiedArticle-
dc.identifier.doi10.1039/d0py00475h-
dc.identifier.isiWOS:000539273600003-
dc.contributor.orcidHintermair, Ulrich/0000-0001-6213-378X-
local.provider.typewosris-
local.uhasselt.uhpubyes-
local.description.affiliation[Vrijsen, Jeroen H.; Junkers, Tanja] Hasselt Univ, Martelarenlaan 42, B-3500 Hasselt, Belgium.-
local.description.affiliation[Vrijsen, Jeroen H.; Junkers, Tanja] Monash Univ, Sch Chem, Polymer React Design Grp, 19 Rainforest Walk,Bldg 23, Clayton, Vic 3800, Australia.-
local.description.affiliation[Thomlinson, Isabel A.; Davidson, Matthew G.; Hintermair, Ulrich] Univ Bath, Ctr Sustainable & Circular Technol, Bath BA2 7AY, Avon, England.-
local.description.affiliation[Levere, Martin E.; Lyall, Catherine L.; Hintermair, Ulrich] Univ Bath, Dynam React Monitoring Facil, Bath BA2 7AY, Avon, England.-
item.validationecoom 2021-
item.contributorVRIJSEN, Jeroen-
item.contributorThomlinson, Isabel A.-
item.contributorLevere, Martin E.-
item.contributorLyall, Catherine L.-
item.contributorDavidson, Matthew G.-
item.contributorHintermair, Ulrich-
item.contributorJUNKERS, Tanja-
item.accessRightsOpen Access-
item.fullcitationVRIJSEN, Jeroen; Thomlinson, Isabel A.; Levere, Martin E.; Lyall, Catherine L.; Davidson, Matthew G.; Hintermair, Ulrich & JUNKERS, Tanja (2020) Online tracing of molecular weight evolution during radical polymerization via high-resolution FlowNMR spectroscopy. In: POLYMER CHEMISTRY, 11 (21) , p. 3546 -3550.-
item.fulltextWith Fulltext-
crisitem.journal.issn1759-9954-
crisitem.journal.eissn1759-9962-
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